System and process for preparing methyl alcohol through coke-oven gas-assisted coal gasification

A technology for coal gasification and coke oven gas, which is applied in the preparation of hydroxyl compounds, the preparation of organic compounds, and the petroleum industry. Flexibility, reduced equipment investment, and low system flexibility

Inactive Publication Date: 2014-12-10
SOUTH CHINA UNIV OF TECH
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  • Claims
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Problems solved by technology

However, the methanol synthesis gas produced by this process needs to be composed of four strands (coal gasification synthesis gas, dry weight integrated gas, wet weight integrated gas, hydrogen), and the operation flexibility is small, and the system flexibility is low. The comp

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  • System and process for preparing methyl alcohol through coke-oven gas-assisted coal gasification
  • System and process for preparing methyl alcohol through coke-oven gas-assisted coal gasification
  • System and process for preparing methyl alcohol through coke-oven gas-assisted coal gasification

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Embodiment 1

[0037] The specific implementation of the coke oven gas assisted coal gasification methanol production system in this embodiment is as follows:

[0038] The raw coal flow rate entering the process of the present invention is 250t / h. The raw material coke oven gas flow rate is 350t / h. The composition of coke oven gas is shown in Table 1. Coke oven gas-assisted coal-to-methanol process flow diagram see figure 2 :

[0039] Raw coal 200 is made into coal-water slurry 201 by the coal-water slurry preparation unit, and then enters the coal gasification unit 101 for coal gasification reaction together with oxygen 202 to produce coal gasification crude synthesis gas 203; the coal gasification crude synthesis gas 203 enters the synthesis gas purification Unit 103 removes sulfide and carbon dioxide to obtain purified coal gasification synthesis gas 204 and carbon dioxide 205;

[0040] Raw material crude coke oven gas 208 enters coke oven gas purification and separation unit 105, an...

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Abstract

The invention discloses a system and a process for preparing methyl alcohol through coke-oven gas-assisted coal gasification. The system comprises a water-coal-slurry preparation unit, a coal gasification unit, a synthesis gas purification unit, a methyl alcohol synthesis unit, a coke-oven gas purification and separation unit, a triple reforming reaction unit and a gas mixer, wherein the water-coal-slurry preparation unit, the coal gasification unit, the synthesis gas purification unit and the methyl alcohol synthesis unit are sequentially connected with one another. According to the system and the process, effective utilization of coal resources is achieved by complementary utilization of elements of coal and the coke-oven gas and the waste of active elements and energy consumption, caused by a component adjustment operation, can be avoided; and since carbon dioxide and coke-oven gas are used by integration of the triple reforming reaction unit, the operation units are relatively simple, the reaction process is relatively strong in flexibility, and the equipment investment is relatively low.

Description

technical field [0001] The invention belongs to the technical field of energy and chemical industry, and in particular relates to a coke oven gas-assisted coal gasification system and process for methanol production. Background technique [0002] Methanol is an important chemical basic product and an important raw material for the manufacture of various organic products such as formaldehyde, acetic acid, methyl chloride, methylamine and dimethyl sulfate, as well as C1 chemicals such as ethylene and propylene. In 2010, my country's methanol production capacity reached 37.57 million tons, with an output of 15.75 million tons, making it the world's largest producer of methanol. At present, my country mainly uses coal as raw material to produce methanol. [0003] The existing coal-to-methanol process has high energy consumption and CO 2 There are two main problems with large emissions. CO 2 The main reason for the large emissions and low energy efficiency is that the hydroge...

Claims

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Application Information

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IPC IPC(8): C07C31/04C07C29/151C07C29/152
CPCC07C29/1518C07C29/152C10J3/00
Inventor 钱宇杨思宇满奕彭丽娟
Owner SOUTH CHINA UNIV OF TECH
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