Acrylic acid series resin particle, coating combination and optical material

An acrylic resin and optical material technology, applied in the direction of coating, etc., can solve problems such as uneven light diffusion, and achieve the effect of improving surface smoothness and excellent mechanical strength

Active Publication Date: 2014-12-31
SEKISUI PLASTICS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, the coefficient of variation (CV value) of the particle size distribution of the polymer particles contained in the composition for optical materials is limited to 20% or less, and the variation in particle size is small. When forming a light-diffusing layer, the polymer particles are arranged in an aligned state. As a result, gaps are formed between the polymer particles instead, and the light passing through the gaps is not diffused, resulting in a problem that the light diffusivity becomes uneven.

Method used

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  • Acrylic acid series resin particle, coating combination and optical material
  • Acrylic acid series resin particle, coating combination and optical material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1)

[0089] A monomer composition containing 95 parts by weight of methyl methacrylate, 5 parts by weight of ethylene glycol dimethacrylate, and 0.4 parts by weight of benzoyl peroxide, and 200 parts by weight of deionized water were used as the acid-soluble insoluble monomer composition. 6 parts by weight of calcium triphosphate as a dispersion stabilizer composed of a water-soluble inorganic compound, and 0.1 part by weight of sodium lauryl sulfate were supplied to a mixer (trade name "TK ホモミキサー" manufactured by Special Machinery Co., Ltd.), and mixed at 4500 rpm for 10 minutes to obtain a dispersion in which the monomer composition is uniformly dispersed in deionized water.

[0090] The dispersion liquid was supplied into the polymerization reactor, and the monomer composition was subjected to suspension polymerization at 70° C. for 3 hours while stirring to obtain a suspension in which cross-linked polymethyl methacrylate particles were dispersed in water.

[0091] After adding...

Embodiment 2)

[0094] The cross-linked polymethyl methacrylate particles before classification were obtained in the same manner as in Example 1, except that the number of revolutions of the mixer was 7000 rpm.

[0095] Next, the obtained cross-linked polymethyl methacrylate particles were put into a turbo classifier (trade name "Type TC-15" manufactured by Nissin Engineering Co., Ltd.) for classification, and the cross-linked polymethyl methacrylate having a particle size of 15 μm or more was removed. Ester particles and cross-linked polymethyl methacrylate particles having a particle diameter of 1 to 4 μm were obtained to obtain classified cross-linked polymethyl methacrylate particles.

Embodiment 3)

[0097] In place of methyl methacrylate and ethylene glycol dimethacrylate, 35 parts by weight of butyl methacrylate, 35 parts by weight of butyl acrylate and 30 parts by weight of ethylene glycol dimethacrylate were used in the mixer. Except that the number of revolutions was 6500 rpm, the same method as in Example 1 was used to obtain crosslinked acrylic resin particles before classification.

[0098] Next, the obtained cross-linked acrylic resin particles were put into a turbo classifier (trade name "Type TC-15" manufactured by Nisshin Engineering Co., Ltd.) and classified to remove cross-linked polymethyl methacrylate particles having a particle size of 15 μm or more and The crosslinked acrylic resin particles having a particle diameter of 1 to 4 μm were obtained as classified crosslinked acrylic resin particles.

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Abstract

The invention provides an acrylic acid series resin particle capable of forming an optical material with uniform light diffusion property, a coating combination and the optical material. The acrylic acid series resin particle is characterized in that: value alpha, value gamma and value eta meet a predetermined relationship, and CV value is 30-40%, meanwhile value A is less than 0.75, and value B is 1.1-1.6, wherein the value alpha is cumulative 10% particle size by volume basis/ cumulative 10% particle size by count basis, the value gamma is cumulative 50% particle size by volume basis/ cumulative 50% particle size by count basis, the value eta is cumulative 90% particle size by volume basis/ cumulative 90% particle size by count basis, the CV value is particle size by volume basis, the value A is cumulative 10% particle size by volume basis/ cumulative 50% particle size by volume basis, and the value B is cumulative 90% particle size by volume basis/ cumulative 50% particle size by volume basis.

Description

technical field [0001] The present invention relates to acrylic resin particles, coating compositions and optical materials. Background technique [0002] In recent years, liquid crystal display devices have been used in various applications as display devices. The liquid crystal display device is provided with a backlight unit on the back of the liquid crystal cell. The backlight unit is composed of a light-emitting light source such as a cold cathode tube or an LED, a lamp reflector, a light guide plate, a light diffusion plate arranged on the front side of the light guide plate, and a light reflection plate arranged on the rear side of the light guide plate. . The said light-diffusion plate is an optical film which diffuses the light released from a light-emitting light source, and makes it incident on a liquid crystal panel. [0003] In addition, in order to reduce power consumption, it is also required to increase the brightness of the liquid crystal display screen. ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F20/00C08F220/14C08F222/14C08F220/18C08F2/18C09D133/00C09D133/12C09D133/06
Inventor 后藤孝至松本悟
Owner SEKISUI PLASTICS CO LTD
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