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Single-packaging organic silicon gel packaging adhesive for high-power white light LEDs (light-emitting diodes) and preparation method thereof

A silicone gel sealing, single-packaging technology, used in adhesives, adhesive additives, electrical components, etc., can solve problems such as difficulty in uniform mixing, poor compatibility, and performance degradation of LED encapsulation adhesives. Cross-linking curing reaction characteristics, simple preparation process, overcoming the effect of easy imbalance

Inactive Publication Date: 2015-01-07
SHANGHAI INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The main problems in this preparation are: on the one hand, when the refraction difference between the vinyl phenyl silicone resin and the crosslinking agent increases, the molecular structure of the two will differ greatly, so the compatibility will become poor. The light transmittance of the gel is poor; on the other hand, it is difficult to achieve uniform mixing and full curing when mixing and curing the two, resulting in a decrease in the performance of the LED encapsulant; it is difficult to meet the development needs of the high-power LED encapsulation industry

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] A method for preparing a single-pack silicone gel encapsulant for high-power white light LEDs, calculated in parts by weight, the composition and content of its raw materials are as follows:

[0033] 100 parts of self-crosslinking phenyl silicone resin with 40% phenyl content

[0034] Catalyst 0.001 parts

[0035] Inhibitor 0.005 part

[0036] 1 part of tackifier;

[0037] The self-crosslinking phenyl silicone resin with 40% phenyl content is a phenyl silicone resin with hydrogen in the molecular main chain and vinyl in the terminal group, wherein the hydrogen content is 1.25×10 -4 mol / g, vinyl content is 1.05×10 -4 mol / g;

[0038] The catalyst is a complex of platinum and tetramethyldivinyldisiloxane, provided by Shanghai Huasi Chemical New Materials Co., Ltd.;

[0039] The inhibitor is 3-methyl-1-butyn-3-ol;

[0040] The tackifier is the AM-511 tackifier of Guangzhou Xinhou Chemical Technology Co., Ltd.

[0041] The preparation method of the above-mentioned sin...

Embodiment 2

[0048] A single-pack silicone gel encapsulant for high-power white light LEDs, calculated in parts by weight, its raw material composition and content are as follows:

[0049] 120 parts of self-crosslinking phenyl silicone resin with 30% phenyl content

[0050] Catalyst 0.005 parts

[0051] Inhibitor 0.002 parts

[0052] 10 parts of tackifier;

[0053] The self-crosslinking phenyl silicone resin with 30% phenyl content is a phenyl silicone resin with hydrogen in the molecular main chain and vinyl in the terminal group, wherein the hydrogen content is 2.15×10 -4 mol / g, vinyl content is 2.05×10 -4 mol / g;

[0054] The catalyst is a complex of platinum and tetramethyltetravinylcyclotetrasiloxane, provided by Shanghai Huasi Chemical New Materials Co., Ltd.;

[0055] The inhibitor is 3-phenyl-1-butyn-3-ol;

[0056] The tackifier is the AM-511 tackifier of Guangzhou Xinhou Chemical Technology Co., Ltd.

[0057] The preparation method of the above-mentioned single-pack silicone...

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Abstract

The invention discloses a single-packaging organic silicon gel packaging adhesive for high-power white light LEDs (light-emitting diodes) and a preparation method thereof. The single-packaging organic silicon gel packaging adhesive for high-power white light LEDs is prepared from the following raw materials in parts by weight: 100-120 parts of self-crosslinked phenyl organic silicon resin with 30-40% of phenyl group, 0.001-0.005 part of catalyst, 0.002-0.005 part of inhibitor and 1-10 parts of tackifying agent. The preparation method comprises the following steps: adding the catalyst, inhibitor and tackifying agent into the self-crosslinked phenyl organic silicon resin with 30-40% of phenyl group, stirring uniformly, and carrying out vacuum degassing for 15-30 minutes to obtain the high-transparency high-refractivity single-packaging organic silicon gel packaging adhesive for high-power white light LEDs. The preparation method has the characteristics of simple preparation process and the like, and is convenient to operate and suitable for industrial production.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, and in particular relates to a single-package organic silicon gel encapsulant for high-power white light LEDs and a preparation method. Background technique [0002] With the rapid development of LED packaging, electronic packaging and other industries, the development of packaging materials that are resistant to thermal shock, non-yellowing, high light transmittance, and high refractive index is an important key technology that urgently needs to be solved in the manufacture of power-type white light LEDs. At present, ordinary LED packaging materials are mainly bisphenol A transparent epoxy resin, which is the most widely used because of its low price, but due to the poor heat resistance, moisture resistance, and softness of epoxy resin, it is easy to turn yellow, brittle, and has low impact strength. , It is easy to produce stress cracking, shrinkage of cured products, etc., and intern...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L83/05C08K5/05C09J183/05C09J11/06C09J11/08H01L33/56
Inventor 张英强李烨
Owner SHANGHAI INST OF TECH
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