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Technology for recycling low-calcium and low-chlorine purified water

A water purification and process technology, applied in the field of environmental engineering, can solve the problems of high cost, achieve the effect of high reuse rate of reused water, realize zero discharge of waste water, and low cost of waste water treatment

Inactive Publication Date: 2015-03-11
ZHUZHOU SMELTER GRP
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  • Claims
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Problems solved by technology

These generated particles can strongly coagulate and adsorb organic or inorganic colloidal particles in wastewater, and at the same time, under the action of overvoltage, O 2 and H 2 , during its ascent process, the colloidal particles and oil slicks in the wastewater are adhered to float together, so as to achieve the purpose of removing heavy metal ions in acidic heavy metal wastewater. This method can also realize the reuse of low-calcium and low-chlorine purified water, but the cost At present, the application of electrochemical technology to treat acidic heavy metal wastewater at home and abroad is still relatively small.

Method used

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  • Technology for recycling low-calcium and low-chlorine purified water
  • Technology for recycling low-calcium and low-chlorine purified water

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Embodiment Construction

[0018] Such as figure 1 As shown, one or several high-efficiency flocculants of polyiron, polyaluminum, and polyacrylamide are added to heavy metal-containing wastewater, and the groups in the flocculant and heavy metal ions undergo a coordination reaction to form alum flowers. Liquid caustic soda, adjust the pH to 9-11 to make the coordination bond more stable and facilitate the settlement. Finally, the solid-liquid separation is carried out through the inclined plate settling tank to remove most of the heavy metal ions.

[0019] The supernatant water after removing heavy metal ions enters the buffer pool, and the water in the buffer pool is added with sodium carbonate, Na 2 CO 3 .10H 2 O is 99% industrially pure, with a concentration of 10% and a density of about 1.2 g / mL. It is necessary to reduce the calcium ion content of the pretreated water to less than 50 mg / L, and add an excess of 1.5 times according to the excess coefficient. For wastewater with a calcium content ...

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Abstract

The invention discloses a technology for recycling low-calcium and low-chlorine purified water after heavy-metal-containing wastewater is treated. A high-efficiency flocculating agent is added into the heavy-metal-containing wastewater; by acid-base adjustment, the pH is adjusted to be base, and solid-liquid separation is finally executed through an inclined plate settling basin so as to remove most heavy metal ions; supernate enters a buffering water basin for calcium reduction treatment and then enters an ultrafiltration-reverse osmosis system for advanced purification; produced fresh water serving as production water returns to a production system, and concentrated water serves as water for flushing residues. Part of bottom flow subjected to calcium reduction is used as crystal seeds for backflowing, and most of the bottom flow enters the buffering water basin for repeated use. The recycling rate of the recycled water is high; the phenomenon of calcium scaling is avoided; the wastewater treatment cost is low, and zero emission of the wastewater is realized.

Description

technical field [0001] The invention relates to a process for the treatment and reuse of heavy metal wastewater, in particular to a process for the treatment and recycling of wastewater containing one or more heavy metals such as cadmium, arsenic, lead, zinc, copper, etc. It belongs to the field of environmental engineering. Background technique [0002] The rapid development of industrialization has caused a large amount of heavy metal wastewater to be discharged into the environment. The acidic heavy metal wastewater has a low pH (pH value between 4-6) and contains a variety of heavy metal ions, such as Cu 2+ 、Cd 2+ , Pb 2+ , Zn 2+ 、As 2+ etc., they cannot be decomposed by organisms, and once they enter the environment, they will continue to accumulate in the environment, causing serious pollution to water bodies and even destroying the ecological environment. Many domestic smelting enterprises have purified water reuse systems, and the purified water treated by tradi...

Claims

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Application Information

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IPC IPC(8): C02F9/04
CPCC02F9/00C02F1/441C02F1/444C02F1/52C02F1/56C02F1/66C02F5/06C02F2103/10C02F2103/16
Inventor 张天芳李迪汉刘宏志雷宇李正明张伟陈顺高盟
Owner ZHUZHOU SMELTER GRP
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