Method of producing gasoline blending component with high octane value by light aromatic hydrocarbon and/or alcohol/ether compound

A technology for high-octane gasoline and light aromatics, applied in the preparation of liquid hydrocarbon mixtures, petroleum industry, biological raw materials, etc., can solve the problems of reduced conversion rate of raw materials, poor catalyst stability, low conversion rate of toluene, etc., to promote high efficiency Transformation, simple process, high conversion rate of raw materials

Inactive Publication Date: 2015-03-18
DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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AI Technical Summary

Problems solved by technology

In the production process of p-xylene by alkylation of toluene and methanol, the acidity and pore structure of the catalyst can be adjusted by various methods, so that the selectivity of p-xylene can reach more than 95%, but the conversion rate of toluene is low (usually lower than 25 %), low utilization rate of methanol, poor catalyst stability and other key problems; especially, there is an "inverse effect" between catalyst activity and selectivity in this process: the increase in selectivity is accompanied by a significant decrease in the conversion rate of raw materials, and with the extension of reaction time, Activity decays quickly
To date, the challenge of maintaining high activity and stability in this process while maintaining high para-selectivity has not been effectively resolved

Method used

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Effect test

Embodiment 1

[0014] Using the method provided by the invention, using benzene and methanol as raw materials, the reaction conditions are as follows: the inlet temperature of each section of the reaction bed is 360 ° C, the pressure is 0.5 MPa, the molar ratio of benzene to alcohol is 0.5, and the feed space velocity is 2.0 h -1 .

[0015] The raw material benzene enters the reactor from the top of the reactor, and the methanol raw material is equally divided into 4 paths and enters the inlets of each bed of the alkylation reactor, and reacts with benzene on the DL0812 special catalyst. The methanol conversion rate is 100%, and the liquid product yield is >99.8% (based on the hydrocarbon group in the raw material). The product is separated, benzene is recycled back to the alkylation reactor, and the hydrocarbonated liquid is fractionated to obtain high-octane gasoline (>98%) and 91%, the content of normal paraffins with low octane number is less than 1%, and the rest are isoparaffins, norma...

Embodiment 2

[0017] Using the method provided by the invention, coking hydrogenated benzene (purity>99.9%) and dimethyl ether are used as raw materials, and the reaction conditions are as follows: the inlet temperature of each stage of the reaction bed is 320 ° C, the pressure is 0.5 MPa, and the molar ratio of benzene to alcohol is 1. Material space velocity 2.0h -1 .

[0018] The raw material coking and hydrogenation benzene enters the reactor from the top of the reactor, and the dimethyl ether raw material is divided into 5 paths and enters each bed entrance of the alkylation reactor, and reacts with the raw material benzene on the DL0802G special catalyst. The conversion rate of dimethyl ether is 100%, and the liquid product yield is >99.6% (based on the hydrocarbon group in the raw material). The product is separated, benzene is recycled back to the alkylation reactor, and the hydrocarbonated liquid is fractionated to obtain high-octane gasoline (>98%) and 93%, the content of normal ...

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Abstract

The invention discloses a method of producing a gasoline blending component with a high octane value by a light aromatic hydrocarbon and/or alcohol/ether compound. The method comprises the following steps: enabling raw material light aromatic hydrocarbon to enter a reactor from the top of a reactor, dividing alcohol/ether oxygenated compounds into a plurality of paths, enabling each path to enter each reaction bed layer of a multi-section quench type fixed bed reactor and then mix with the light aromatic hydrocarbon entering from the top of the reactor to react on a special catalyst to produce an alkyl-rich aromatic hydrocarbon gasoline blending component with the high octane value. The method disclosed by the invention has characteristics of a high raw material conversion ratio, good catalyst stability, a high gasoline product octane value, a simple process, low energy consumption, strong flexibility in operation scheme, and the like, and can be used for effectively promoting the light aromatic hydrogen and the alcohol/ether oxygenated compounds to efficiently convert to the gasoline blending component with the high octane value.

Description

technical field [0001] The invention belongs to the technical field of clean vehicle fuel production, and in particular relates to a method for producing high-octane gasoline blending components by alkylation of light aromatics and alcohol / ether oxygen-containing compounds. Background technique [0002] With the rapid development of my country's economy, the demand for oil resources is increasing. At present, my country's dependence on foreign oil demand has exceeded 55%, and the shortage of oil resources has become a bottleneck restricting the sustainable development of my country's economy and society. In the next few decades, the most scarce downstream products will be vehicle transportation fuels, mainly gasoline and diesel (Contemporary Petroleum and Petrochemical, Volume 17, Issue 11, 2009, Countermeasures for Sustainable Development of my country's Oil Refining and Petrochemical Industry) . In view of the current situation of my country's energy structure that is ric...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G3/00
CPCY02P30/20C10G3/42
Inventor 朱向学王玉忠李秀杰谢素娟安杰陈福存刘盛林徐龙伢
Owner DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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