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A kind of concrete silt inhibitor based on clay mineral flocculation and preparation method thereof

A flocculation, clay mineral technology, applied in the field of concrete mud inhibitor and its preparation, can solve the problem of increasing concrete compactness, environmental pollution of sewage and sediment, concrete strength, drying shrinkage performance, impermeability, frost resistance and resistance problems such as the adverse effect of wear performance, to achieve the effect of reducing operating costs, wide application prospects and theoretical value

Inactive Publication Date: 2016-09-28
HUBEI UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Most of the studies on the effect of mud powder content on the performance of concrete in the MB value of machine-made sand concentrate on the effect of mud powder content on the performance of concrete. It is believed that mud powder is generally finer, which increases the specific surface area of ​​the aggregate. The strength, drying shrinkage, impermeability, frost resistance and wear resistance of concrete will all be adversely affected, but there are few reports on the dynamic relationship between the MB value of machine-made sand and the limit index of stone powder and its practical application in concrete
If the machine-made sandstone is washed and desilted according to the national standard, although the quality of the aggregate can be improved, it consumes limestone powder resources and water resources that can increase the compactness and strength of concrete, and the discharged sewage and sediment pollute the environment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] 100 parts by weight of ferrous sulfate heptahydrate from industrial production are added to the synthesis container, 20 parts of water are added, the temperature is raised to 50° C., slowly dripping sulfuric acid and 10% nitric acid that account for 35% of the amount of ferrous sulfate heptahydrate, The dropping time is 0.5h, and the temperature during the whole dropping process is controlled not to exceed 60°C; after the sulfuric acid and nitric acid mixture is added dropwise, and the temperature is stabilized to 55°C, add 4.2 parts by weight of potassium permanganate and 10 parts by weight of sulfuric acid The speed of adding aluminum and potassium permanganate is based on controlling the reaction temperature without obvious rise. Potassium permanganate can be dissolved in 20 parts by weight of water and added dropwise within 45 minutes; potassium permanganate can also be insoluble in water and directly spaced Due to the large instantaneous concentration of the input a...

Embodiment 2

[0038] 100 parts by weight of ferrous sulfate heptahydrate from industrial production are added to the synthetic container, without adding water, the temperature is raised to 60° C., and slowly add sulfuric acid and 5% silicic acid that account for 25% of the amount of ferrous sulfate heptahydrate dropwise. The adding time is 45 minutes, and the temperature during the whole dropping process is controlled not to exceed 60 degrees; after the sulfuric acid and silicic acid mixture is added dropwise, and the temperature is stabilized to 60°C, 5 parts by weight of hydrogen peroxide and 15 parts by weight of zinc oxide are added. The speed of addition is subject to controlling the reaction temperature without obvious rise. Dissolve the hydrogen peroxide in 200 parts by weight of water and add it dropwise within 3 hours; the zinc oxide is directly added, and the addition time is subject to the temperature of the reactants in the container not being significantly lowered; hydrogen perox...

Embodiment 3

[0040] 100 parts by weight of ferrous sulfate heptahydrate from industrial production are added to the synthesis container, 100 parts by weight of water are added, the temperature is raised to 50° C., and the sulfuric acid that accounts for 40% of the amount of ferrous sulfate heptahydrate is slowly added dropwise, and the dropping time is 1h, the temperature of the whole dropping process is controlled not to exceed 60°C; after the sulfuric acid is added dropwise, after the temperature is stabilized to 40°C, add 10 parts by weight of aluminum sulfate, add directly, and use the pump to feed in the air for 20 hours After 20 hours, measure the concentration (solid content) of the flocculant, and then add magnesium fluorosilicate according to the compound ratio of flocculant (solid content): stabilizer: corrosion inhibitor: enhancer = 70:10:5:15 mass percent , hexamethylenetetramine, sodium nitrite, mix and stir well.

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Abstract

The invention provides a concrete mud retarder based on clay mineral flocculation and a preparation method thereof. The concrete mud retarder comprises a main ingredient and auxiliary ingredients, wherein the main ingredient is multiple-ion complex salt flocculant, and the auxiliary ingredients comprise a stabilizer, a corrosion inhibitor and a reinforcing agent. The concrete mud retarder can eliminate the sour corrosion and side effects on influencing the early strength of concrete of the flocculant. The preparation method comprises two steps of flocculant synthesis and mud retarder compounding. The mud retarder ingredients are matched and reasonable, the flowability and the mechanical performance indexes of concrete are comprehensively considered, the performance cost ratio is high, and the dosage of a water reducer and the preparation cost of concrete are effectively reduced.

Description

technical field [0001] The invention belongs to the technical field of building materials, and relates to water reducing agent technology and the use of machine-made sandstone, in particular to a concrete mud inhibitor based on clay mineral flocculation and a preparation method thereof. Background technique [0002] With the rapid development of my country's economy and society, the scale of construction has expanded rapidly, leading to a sharp increase in the demand for construction sand and increasing pressure on resources and the environment. Based on the ratio of cement and sand in concrete, which is 1:5, the cement output in my country was more than 2.41 billion tons in 2013, and the theoretical consumption of sand and stone should be more than 12 billion tons. Due to years of large-scale consumption, my country's non-renewable natural sand and gravel resources are on the verge of exhaustion. In order to protect the ecological environment, many local governments have al...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B24/12C04B22/14C04B22/12
Inventor 柯凯苏英贺行洋颜红专
Owner HUBEI UNIV OF TECH