Ferrite material for heat-sensitive sensor

A technology of ferrite material and thermal sensor, applied in the field of ferrite material, can solve the problems of high pre-sintering temperature, lower qualified rate of powder finished product, increase of fine powder amount, etc. The effect of reducing and increasing the sintered density

Inactive Publication Date: 2015-03-25
东莞时富电子有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] 1. When Bi 2 o 3 When the content is greater than 0.01%, the initial permeability and density of the soft ferrite thermal core will also decrease, and the core will become brittle and brittle
[0007] 2. Although the fluctuation range of the Curie temperature becomes smaller, the maximum slope of the temperature change of the magnetic permeability is still small at the Curie temperature point, such as only 100-200/°C, so the accuracy of temperature control is still low
[0008] 3. During sintering, ZnO volatilizes seriously, and the application range of soft ferrite heat-sensitive magnetic materials to frequencies is narrow;
[0009] 4. In this application, the soft magnetic ferrite heat-sensitive magnetic powder is directly rolled and pre-fired after the ingredients are mixed and added to the PVA. The PVA is directly added to the dry powder of the raw material, which is easy to make the dry powder agglomerate,...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] A kind of ferrite material for thermosensitive sensor, it mainly comprises Fe 2 o 3 , ZnO, MgO, CuO, NiO, Al 2 o 3 , Nb 2 o 5 and Bi 2 o 3 , wherein, by weight percentage, each component content is as follows respectively:

[0041] ZnO 16%,

[0042] MgO 5%;

[0043] CuO 3%;

[0044] NiO 1%;

[0045] Al 2 o 3 0.008%;

[0046] Nb 2 o 5 0.008%;

[0047] Bi 2 o 3 0.003%;

[0048] Fe 2 o 3 margin.

[0049] The above thermal sensor is made of ferrite material through the following steps:

[0050] The first step, weighing and mixing: the Fe 2 o 3 , ZnO, MgO, NiO and CuO powder according to the ratio, weigh the weight, when weighing, first weigh 1 / 3-1 / 2 weight of Fe 2 o 3 Put it into the mixer, then weigh ZnO, MgO, NiO and CuO and the remaining Fe 2 o 3 Add the powder into the blender; then add PVA solution with 6% weight of the powder and mix well.

[0051] The second step, vibrating mill: put the uniformly ...

Embodiment 2

[0057] A ferrite material for a thermal sensor, the ferrite material for a thermal sensor mainly includes Fe 2 o 3 , ZnO, MgO, CuO, NiO, Al 2 o 3 , Nb 2 o 5 and Bi 2 o 3 , wherein, by weight percentage, each component content is as follows respectively:

[0058] ZnO 20%,

[0059] MgO 6%;

[0060] CuO 5%;

[0061] NiO 2%;

[0062] Al 2 o 3 0.009%;

[0063] Nb 2 o 5 0.0015%;

[0064] Bi 2 o 3 0.009%;

[0065] Fe 2 o 3 margin.

[0066] The above thermal sensor is made of ferrite material through the following steps:

[0067] The first step, weighing and mixing: the Fe 2 o 3 , ZnO, MgO, NiO and CuO powder according to the ratio, weigh the weight, when weighing, first weigh 1 / 3-1 / 2 weight of Fe 2 o 3 Put it into the mixer, then weigh ZnO, MgO, NiO and CuO and the remaining Fe 2 o 3 Add the powder into the blender; then add PVA solution with 7% weight of the powder and mix well.

[0068] The second step, vibrati...

Embodiment 3

[0074] A ferrite material for a thermal sensor, the ferrite material for a thermal sensor mainly includes Fe 2 o 3 , ZnO, MgO, CuO, NiO, Al 2 o 3 , Nb 2 o 5 and Bi 2 o 3 , wherein, by weight percentage, each component content is as follows respectively:

[0075] ZnO 25%,

[0076] MgO 8%;

[0077] CuO 7%;

[0078] NiO 3%;

[0079] Al 2 o 3 0.01%;

[0080] Nb 2 o 5 0.02%;

[0081] Bi 2 o 3 0.01%;

[0082] Fe 2 o 3 margin.

[0083] The above thermal sensor is made of ferrite material through the following steps:

[0084] The first step, weighing and mixing: the Fe 2 o 3 , ZnO, MgO, NiO and CuO powder according to the ratio, weigh the weight, when weighing, first weigh 1 / 3-1 / 2 weight of Fe 2 o 3 Put it into the mixer, then weigh ZnO, MgO, NiO and CuO and the remaining Fe 2 o 3 Add the powder into the blender; then add PVA solution with 8% weight of the powder and mix well.

[0085] The second step, vibrating mill:...

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PUM

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Abstract

The invention discloses a ferrite material for a heat-sensitive sensor. The ferrite material mainly contains the ingredients in percentage by weight: 16-25% of ZnO, 5-8% of MgO, 3-7% of CuO, 1-3% of NiO, 0.008-0.01% of Al2O3, 0.008-0.02% of Nb2O5, 0.003-0.01% of Bi2O3 and the balance of Fe2O3. The ferrite material for the heat-sensitive sensor is prepared mainly through the steps of weighing and mixing, carrying out vibrated-grinding, pelletizing, prefiring, sanding, carrying out spraying granulation and the like. By adopting the ingredients and the preparation method, the crystal grain of the ferrite material for the heat-sensitive sensor can be fine and uniform, the initial magnetic permeability can be improved, the sintering temperature can be lowered, the magnetic core sintered density can be improved, and the range of Curie temperature can be narrowed; the volatilization of zinc oxide can be inhibited, the specific temperature coefficient is increased, the maximum slope of magnetic permeability temperature change is high, and the temperature control accuracy is high; due to vibrated-grinding, large granules and agglomerated powdery materials in mixed powder can be crushed, so that the gluing and mixing are uniform.

Description

technical field [0001] The invention relates to a ferrite material, in particular to a ferrite material for a thermal sensor. Background technique [0002] Thermal sensors are a class of sensors used to detect thermal quantities (mainly temperature) and to achieve process control related to thermal processes. In addition to the function of detecting thermal quantities such as temperature, thermal sensors are often used to help realize automatic control related to thermal processes. The thermal sensor is one of the temperature sensors. Although there are many types of temperature sensors at present, it is still generally believed that the thermal sensor is the most marketable, potential and promising product. [0003] The Chinese Invention Patent No. 201110174152.X published on February 22, 2012 is titled "A Soft Magnetic Ferrite Thermal Core and Its Manufacturing Method". In this patent, the composition (percentage by weight) of the soft ferrite thermosensitive core contai...

Claims

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Application Information

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IPC IPC(8): C04B35/26C04B35/622
Inventor 禹胜林
Owner 东莞时富电子有限公司
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