The invention belongs to the technical field of wireless location, and particularly relates to an ultra wide band wireless locating method based on skewness and maximum slope. The method mainly comprises four steps as follows: step A, collecting an integration energy block and calculating the skewness and the maximum slope, so as to obtain a joint parameter, and establishing a fingerprint database of three parameters, namely the joint parameter, a TOA (Time Of Arrival) estimated error, and a normalized threshold; step B, carrying out curve fitting on the fingerprint database, establishing a correspondence F between the joint parameter corresponding to the minimum TOA estimated error and the normalized threshold; step C, obtaining a joint parameter according to the skewness and the maximum slope of a collected real-time signal, calculating with use of the correspondence F so as to obtain the optimal normalization threshold, and obtaining the TOA estimated value according to the threshold; and step D, carrying out wireless location based on ultra wide band (UWB) by using a traditional UWB location algorithm according to the TOA estimated value. According to the ultra wide band wireless locating method based on skewness and maximum slope disclosed by the invention, the skewness and the maximum slope are combined for the first time; the method has the advantages of high location precision and good stability, and can be applied to high-precision wireless location of applications such as internet of things and wireless sensor networks.