The application relates to a preparation method of a four-fold frequency
crystal guanidinium
tetrafluoroborate device, which comprises the following steps: firstly, measuring a frequency doubling coefficient of the
crystal by a Maker fringe method to obtain two non-zero
effective frequency doubling coefficients; secondly, measuring main refractive indexes of the
crystal at 11 wavelengths between 253 nm and 2325 nm by a
minimum deviation angle method, and fitting a Sellmeier equation; thirdly, calculating a
phase matching curve of the crystal I or II type by a
computer program according to the Sellmeier equation, and combining the frequency doubling coefficient to determine a
phase matching point of the crystal; fourthly,
cutting the crystal according to the
phase matching direction,
polishing two
light transmission surfaces, and
coating a
dielectric film to obtain the four-fold frequency crystal device; and the four-fold frequency crystal device is used for generating four-fold frequency
laser output, the frequency doubling effect is 4.7 times that of KDP, and the four-fold frequency crystal device has good practical application value in the field of
laser technology.