Antibacterial anti-mildew plastic and wood composite material plate and preparation method thereof
A wood-plastic composite material, antibacterial and anti-mildew technology, applied in the field of plastic-wood composite materials, can solve the problems of plastic-wood composite materials such as mildew, degradation of material mechanical properties, and shortened service life, so as to achieve low production costs and reduce product raw material costs , The effect of reducing the amount of plastic
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Embodiment 1
[0050] (1) Weigh the wood powder and the wood preservative dimethyldidecylammonium chloride DDAC according to the weight ratio of 100:1. The weight ratio of DDAC:tap water is 1:500, dilute DDAC with tap water, and then put the wood powder in into the diluent, ultrasonically treated for 25 minutes, dehydrated and dried, and sieved to obtain modified wood flour.
[0051](2) Weigh γ-methacryloxypropyltrimethoxysilane, tap water and nano-zinc oxide at a weight ratio of 1.5:10:100, and mix γ-methacryloxypropyltrimethoxysilane After mixing with water, spray evenly on the surface of nano-zinc oxide, then reflux reaction in toluene solution for 3 hours, and filter under reduced pressure to obtain modified nano-zinc oxide, then add styrene, modified nano-zinc oxide and benzoyl peroxide Mix evenly according to the weight ratio of 100:7:1.1, heat up to 65°C, and after 8 hours of reaction, crush the product, extract the product with toluene for 72 hours, and then dry the product under vac...
Embodiment 2
[0066] (1) Weigh the wood powder and the wood preservative dimethyldidecylammonium chloride DDAC according to the weight ratio of 100:1. The weight ratio of DDAC: tap water is 1:500. Dilute DDAC with tap water, and then put the wood powder in into the diluent, ultrasonically treated for 20 minutes, dehydrated and dried, and sieved to obtain modified wood flour.
[0067] (2) Weigh γ-methacryloxypropyltrimethoxysilane, tap water and nano-zinc oxide at a weight ratio of 1:10:100, and mix γ-methacryloxypropyltrimethoxysilane After mixing with water, spray evenly on the surface of nano-zinc oxide, then reflux reaction in toluene solution for 2 hours, and filter under reduced pressure to obtain modified nano-zinc oxide, then add styrene, modified nano-zinc oxide and benzoyl peroxide Mix evenly according to the weight ratio of 100:4:0.8, raise the temperature to 60°C, and after reacting for 6 hours, crush the product, extract the product with toluene for 48 hours, and then vacuum dry...
Embodiment 3
[0082] (1) Weigh the wood powder and the wood preservative dimethyldidecylammonium chloride DDAC according to the weight ratio of 100:1. The weight ratio of DDAC: tap water is 1:500. Dilute DDAC with tap water, and then put the wood powder in into the diluent, ultrasonically treated for 30 minutes, dehydrated and dried, and sieved to obtain modified wood flour.
[0083] (2) Weigh γ-methacryloxypropyltrimethoxysilane, tap water and nano-zinc oxide at a weight ratio of 2:10:100, and mix γ-methacryloxypropyltrimethoxysilane After mixing with water, spray evenly on the surface of nano-zinc oxide, then reflux reaction in toluene solution for 4 hours, and filter under reduced pressure to obtain modified nano-zinc oxide, then add styrene, modified nano-zinc oxide and benzoyl peroxide Mix evenly according to the weight ratio of 100:10:1.4, heat up to 70°C, and after 10 hours of reaction, crush the product, extract the product with toluene for 96 hours, then dry the product under vacuu...
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