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Composite wavelength conversion powder, resin composition containing composite wavelength conversion powder, and light emitting device

A technology of resin composition and multiple wavelengths, which is applied in luminescent materials, lighting devices, electroluminescent light sources, etc., can solve problems such as insufficient performance of wavelength conversion materials, reduced luminous efficiency of nano-phosphors, and influence of humidity to achieve high-efficiency luminescence Reliability, high utilization efficiency, and the effect of improving reliability

Active Publication Date: 2015-03-25
SUMITOMO OSAKA CEMENT CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0020] In addition, for the nano-phosphors whose dispersion particle size in the binder described in Patent Documents 2 and 3 is smaller than the wavelength of the excitation light and the emission light, although the loss of light utilization efficiency caused by scattering is reduced, there is a problem caused by the surface The shortcomings of the nano-phosphor itself due to defects are that the luminous efficiency is greatly reduced. In addition, there are reliability problems such as being easily affected by humidity, and the performance as a wavelength conversion material is not sufficient.

Method used

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  • Composite wavelength conversion powder, resin composition containing composite wavelength conversion powder, and light emitting device
  • Composite wavelength conversion powder, resin composition containing composite wavelength conversion powder, and light emitting device
  • Composite wavelength conversion powder, resin composition containing composite wavelength conversion powder, and light emitting device

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Experimental program
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no. 1 Embodiment approach

[0064] Embodiments for implementing the composite wavelength conversion powder and the resin composition containing the composite wavelength conversion powder of the present invention will be described.

[0065] In addition, the following embodiments are specifically described for a better understanding of the gist of the invention, and unless otherwise specified, do not limit the present invention.

[0066] [Composite wavelength conversion powder]

[0067] The composite wavelength converting powder of this embodiment is a powder formed by dispersing phosphor particles having a refractive index of 1.6 or more in matrix particles containing magnesium fluoride fine particles or calcium fluoride fine particles.

[0068] Here, the reason for using magnesium fluoride fine particles (refractive index: 1.38) or calcium fluoride fine particles (refractive index: 1.43) as the material constituting the above-mentioned matrix particles is that the refractive index is low, and heat resist...

Embodiment 1

[0126] [Example 1] (preparation of magnesium fluoride colloid)

[0127] Magnesium chloride hexahydrate (MgCl 2 ·6H 2 O) 406.6g was dissolved in 2000g of pure water (room temperature: 25 degreeC), and the magnesium chloride aqueous solution was prepared. Next, ammonium fluoride (NH 4 F) Magnesium fluoride particles were produced by stirring an aqueous ammonium fluoride solution obtained by dissolving 148.2 g in 2000 g of pure water (room temperature: 25° C.).

[0128] Next, the solution containing the magnesium fluoride particles is cleaned by ultrafiltration to remove impurity ions in the solution, and then concentrated to prepare a solution containing 2% by mass of magnesium fluoride (MgF 2 ) particles of magnesium fluoride colloid.

[0129] The dispersed particle diameter of this magnesium fluoride colloid is 30nm, magnesium fluoride (MgF 2 ) The crystal particle size of the particles is 8nm.

[0130] (Preparation of phosphor precursor solution with garnet structure) ...

Embodiment 2

[0144] [Example 2] (preparation of calcium fluoride colloid)

[0145] Calcium chloride dihydrate (CaCl 2 2H 2 O) 376.6g was dissolved in 9624g (room temperature: 25 degreeC) of pure water, and the calcium chloride aqueous solution was prepared. Next, ammonium fluoride (NH 4 F) An ammonium fluoride aqueous solution obtained by dissolving 190 g in 9810 g of pure water (room temperature: 25° C.) was stirred to produce calcium fluoride particles.

[0146] Next, the solution containing the calcium fluoride particles is cleaned by ultrafiltration to remove impurity ions in the solution, and then concentrated to prepare a solution containing 2% by mass of calcium fluoride (CaF 2 ) particles of calcium fluoride colloid.

[0147] The dispersed particle diameter of this calcium fluoride colloid is 80nm, calcium fluoride (CaF 2 ) The crystal particle size of the particles is 20nm.

[0148] ]

[0149] (Preparation of phosphor precursor solution with garnet structure)

[0150] Acco...

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Abstract

Provided are: a composite wavelength conversion powder which has high utilization efficiency of light and high utilization efficiency of a constituent material, and which is capable of achieving a good balance between highly efficient light emission and high reliability; and a resin composition which contains this composite wavelength conversion powder. This composite wavelength conversion powder is obtained by dispersing phosphor particles having a refractive index of 1.6 or more in a matrix particle which contains fine magnesium fluoride particles or fine calcium fluoride particles. Also provided is a light emitting device which is capable of improving the utilization efficiency of light produced by phosphor particles that are excited by primary irradiation light irradiated from a light emitting element, and which is capable of improving the optical output of light emission by increasing the amount of secondary irradiation light produced by the phosphor particles, while suppressing the occurrence of color unevenness or color variation of the light discharged to the outside of the device. A light emitting device (1) of the present invention is provided with a substrate (2), a light emitting element (3) that is mounted on the surface of the substrate (2), and a light transmitting member (4) that covers the light emitting element (3). This light transmitting member (4) contains composite wavelength conversion particles (12) which are composed of phosphor particles that have an average particle diameter of 500 nm or less and inorganic particles that are transparent to visible light and have an average particle diameter of 500 nm or less.

Description

technical field [0001] The present invention relates to a composite wavelength conversion powder and a resin composition containing the composite wavelength conversion powder. More specifically, it relates to an In various optical devices such as the composite wavelength conversion powder and the resin composition containing the composite wavelength conversion powder that can combine high-efficiency light emission and high reliability. [0002] In addition, the present invention relates to a light emitting device, and more specifically, to a light emitting device capable of achieving both high-efficiency light emission and high reliability, and high output and uniform light emission with little color unevenness, such as white light. [0003] This application claims priority based on Japanese Patent Application No. 2012-208651 filed in Japan on September 21, 2012, and Japanese Patent Application No. 2013-015563 filed in Japan on January 30, 2013, which are cited here content. ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L33/50C09K11/08C09K11/80
CPCH01L33/501H01L33/502H01L2224/48091H01L2224/8592C09K11/7774H01L2924/181H01L2924/00011H01L2924/1033H01L2924/15747H01L2924/00014H01L2924/00012H01L2924/01005H01L2924/01015H01L2924/01077H01L2924/01033C01F5/28C01F11/22C09K11/0833C01P2002/30C01P2002/76H01L2224/45147C09K11/025H05B33/22
Inventor 木下畅野添勉
Owner SUMITOMO OSAKA CEMENT CO LTD
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