Organic sulfur conversion catalyst for liquefied gas

A technology of organic sulfur and catalyst, which is applied in the field of catalysts for converting organic sulfur contained in liquefied gas, can solve problems such as alkali slag odor, hidden dangers of unsafe operation, and air pollution, and achieve simple production technology, elimination of hidden dangers, and no The effect of secondary pollution

Active Publication Date: 2015-04-29
CHONGQING DIZHIJING TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But this technology has following problems: 1) can produce a large amount of alkali slag, and alkali slag has serious stench smell, can cause environmental problem; Harmful substances exceed the standard); 3) It takes a lot of manpower and material resources to deal with alkali slag, and there is secondary pollution. Discharging sulfur into the atmosphere in the form of oxides will cause air pollution; 4) There are hidden dangers in operation, When mixing lye, caustic soda and lye are easy to hurt people, and when unloading lye residue, it is easy to cause leakage of liquefied petroleum gas

Method used

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  • Organic sulfur conversion catalyst for liquefied gas
  • Organic sulfur conversion catalyst for liquefied gas
  • Organic sulfur conversion catalyst for liquefied gas

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] Example 1. Preparation of liquefied gas organic sulfur conversion catalyst

[0040] Liquefied gas organic sulfur conversion catalyst, composed of the following components in weight percentage: Ni: 10-20%, Na 2 O: 5~10%, the balance is γ-Al 2 o 3 Carrier; The Ni is derived from nickel nitrate, Na 2 O is derived from sodium hydroxide.

[0041] The preparation method of the above liquefied gas organic sulfur conversion catalyst is operated according to the following steps:

[0042] 1) Preparation of impregnating solution: preparing nickel solution: dissolving nickel nitrate to prepare impregnating solution A; preparing sodium solution: preparing sodium hydroxide to prepare impregnating solution B.

[0043] 2) Impregnation: the dried γ-Al 2 o 3 The carrier is placed in the soaking solution A for 2-6 hours, then drained and dried; the dried carrier is placed in the soaking solution B and soaked for 2-6 hours, drained and dried.

[0044] 3) Activation: the carrier obta...

Embodiment 2

[0045] Example 2. Preparation of Liquefied Gas Organosulfur Conversion Catalyst

[0046] Liquefied gas organic sulfur conversion catalyst, composed of the following components in weight percentage: Ni: 10-20%, Na 2 O: 5~10%, the balance is γ-Al 2 o 3 Carrier; The Ni is derived from nickel nitrate, Na 2 O is derived from sodium carbonate.

[0047] The preparation method of the above liquefied gas organic sulfur conversion catalyst is operated according to the following steps:

[0048] 1) Preparation of impregnating solution: preparing nickel solution: dissolving nickel nitrate to prepare impregnating solution A; preparing sodium solution: preparing sodium carbonate to prepare impregnating solution B.

[0049] 2) Impregnation: the dried γ-Al 2 o 3 The carrier is placed in the soaking solution A for 2-6 hours, then drained and dried; the dried carrier is placed in the soaking solution B and soaked for 2-6 hours, drained and dried.

[0050] 3) Activation: the carrier obtain...

Embodiment 3

[0051] Example 3. Preparation of Liquefied Gas Organosulfur Conversion Catalyst

[0052] Liquefied gas organic sulfur conversion catalyst, composed of the following components in weight percentage: Ni: 10-20%, Na2 O: 5~10%, the balance is γ-Al 2 o 3 Carrier; The Ni is derived from nickel sulfate, Na 2 O is derived from sodium carbonate.

[0053] The preparation method of the above liquefied gas organic sulfur conversion catalyst is operated according to the following steps:

[0054] 1) Preparation of impregnating solution: preparing nickel solution: dissolving nickel sulfate to prepare impregnating solution A; preparing sodium solution: preparing sodium carbonate to prepare impregnating solution B.

[0055] 2) Impregnation: the dried γ-Al 2 o 3 The carrier is placed in the soaking solution A for 2-6 hours, then drained and dried; the dried carrier is placed in the soaking solution B and soaked for 2-6 hours, drained and dried. 3) Activation: the carrier obtained by dryin...

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Abstract

The invention relates to an organic sulfur conversion catalyst for liquefied gas and belongs to the technical field of liquefied gas refining. The organic sulfur conversion catalyst for liquefied gas disclosed by the invention comprises the following components in percentage by weight: 10-20 percent of Ni, 5-10 percent of Na2O and the balance of a carrier, wherein the carrier refers to gamma-Al2O3. According to the catalyst disclosed by the invention, the organic sulfur conversion rate in the liquefied gas is high, namely the thiol conversion rate is more than or equal to 95 percent, the carbonyl sulfide conversion rate is more than or equal to 98 percent, and the carbon disulfide conversion rate is more than or equal to 90 percent.

Description

technical field [0001] The invention relates to the technical field of refining liquefied gas in petroleum processing, in particular to a catalyst for converting organic sulfur contained in liquefied gas. Background technique [0002] Liquefied petroleum gas is one of the products in the petroleum processing process, and it is also an important raw material for further processing into other products. Refined raw material liquefied petroleum gas is mainly liquefied gas after desulfurization by alcohol amine method. The main components of liquefied gas from the desulfurization unit by alcohol amine method are C3 and C4 components, containing a small amount of hydrogen sulfide and organic sulfur (mainly mercaptan , carbonyl sulfide, carbon disulfide). [0003] At present, the liquefied gas mercaptan conversion catalysts mainly include sulfonated cobalt phthalocyanine and polyphthalocyanine cobalt catalysts, but these two catalysts only have a good conversion effect on sodium m...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/78B01D53/86B01D53/48C10G70/00
Inventor 王喜平顾法明黄代红张远征曾荣丽刘江
Owner CHONGQING DIZHIJING TECH
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