Method for producing stable hypochlorous acid solution
A technology of hypochlorous acid solution and hypochlorite radicals, which is applied in the fields of hypochlorous acid, botanical equipment and methods, and chemicals for biological control, etc. The problem of high cost of use can achieve the effect of continuous automatic production, remarkable stability and low equipment requirements.
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[0028] Take the production of a hypochlorous acid solution with an available chlorine content of 200 mg / L (ie: C=2.8 mmol / L) and a pH value of 4.5 at room temperature as an example.
[0029] Known pK of acetic acid a It is 4.76, close to 4.5, and acetic acid and sodium acetate are all easy-to-get chemical raw materials, so select acetic acid / sodium acetate as the buffer system (so m=10 (pH-pKa) =10 (4 . 5-4 . 76) =10 -0 . 26 = 0.55).
[0030] Select sodium hypochlorite as the hypochlorite providing agent in this example, the concentration of commercially available sodium hypochlorite aqueous solution is generally 8-10%, can be used directly, but need confirm its accurate content before using, assume that its confirmed result is 10% (relative density) in this example 1.10, so C 1 =1.48mol / L).
[0031] Acetic acid can be mixed with water in any proportion, but it is solid at low temperature (≤16.7°C). In order to maintain its fluidity, in this example, a 10mol / L aqueo...
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