Laminated aluminum plate and preparation method thereof
A technology of aluminum plate and film coating, applied in the field of aluminum plate, can solve the problems of restricting the application of high-end products, single color of aluminum plate, easy to be oxidized, etc., and achieve the effect of not easy to deform and bulge, not easy to decolorize, and not easy to open glue
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[0040] Above-mentioned a kind of carbon-nitrogen co-doped nano-TiO 2 The preparation method is characterized in that the specific steps are as follows: (1) first adopt the reactive magnetron sputtering coating method to prepare a TiCN thin film with adjustable C and N components, wherein a carbon-titanium inlaid sputtering target is used, and the cross-section of the sputtering target is Among them, the area ratio of carbon and titanium is 0.04~0.06; first pump the studio to 10 -2 Vacuum of Pa level, through reaction gas nitrogen and sputtering gas argon in turn, adjust the volume ratio of nitrogen and argon to 1:1~1:1.5; then adjust the high vacuum valve to keep the working pressure at 8~30Pa , the sputtering current is controlled at 1.5-2A, and the sputtering time is 10-28min; during the preparation process, the TiO is controlled by adjusting the area ratio of carbon and titanium in the sputtering target and the volume ratio of nitrogen and argon gas. 2 The content ratio of...
Embodiment 1
[0058] Preparation of Nano-TiC:
[0059] Step S101, weighing tetrabutyl titanate and sucrose solution with a molar ratio of 1:1.5 as raw materials; dissolving tetrabutyl titanate in ethanol to obtain a first solution;
[0060] Dissolving sucrose in ethanol, adding acetic acid to adjust the pH value to 1.5, to obtain a second solution;
[0061] Step S102, under stirring, add the second solution to the first solution, stir for 5 hours to obtain a sol system, and after aging for 18 hours, dry at 170°C to obtain a xerogel;
[0062] Step S103, transfer the xerogel obtained in step S102 into a vacuum furnace with a vacuum degree of 65 Pa for sintering to obtain nano-TiC powder; the heating process during sintering is: the heating rate is 15°C / min at 400-900°C, and the heat preservation time is 5°C. hours; when the temperature reaches 1000-1200°C, the heating rate is 12°C / min, and the heat preservation is 1.5 hours; when the temperature is 1200-1400°C, the heating rate is 13°C / min, ...
Embodiment 2
[0076] A method for preparing a film-coated aluminum plate, comprising the following steps:
[0077] 1) passivating the aluminum plate to form a substrate;
[0078] 2) Using a roller coating method, coating a chromate chemical pretreatment solution with a mass concentration of 20 wt% on both sides of the substrate to form an organic film with a network structure, and the thickness of the organic film is 1 μm;
[0079] 3) the carbon-nitrogen co-doped nano TiO that embodiment 1 makes 2 Formation of nano-TiO on one side of the substrate by PVD 2 layer; paint layer on the other side; the nano-TiO 2 The thickness of the paint layer is 2 μm; the thickness of the paint layer is 8 μm;
[0080] 4) The above-mentioned nano-TiO 2 Apply glue on the layer and cure at 230°C, the thickness of the glue layer is 4 μm;
[0081] 5) At 230°C, stick a PET film with a thickness of 60 μm on the adhesive layer;
[0082] 6) After the temperature is cooled to 110°C, stick a PE protective film wit...
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