High-strength polyurethane rigid foam as well as preparation method and application thereof
A technology of rigid foam plastics and polyurethane, applied in the field of high-strength polyurethane rigid foam plastics, can solve the problems of increased usage of flame retardant additives, foam release, poor strength, fluidity and other performance problems, and achieve flame retardancy Improved performance and heat resistance, good mold release and heat insulation performance, and improved strength
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[0036] In order to better understand the present invention, the content of the present invention is further illustrated below in conjunction with the examples, but the content of the present invention is not limited to the following examples.
[0037] Benzene imide modifier:
[0038] Add trimellitic anhydride and p-aminophenylacetic acid and 300ml acetone solvent into the reaction kettle with a molar ratio of 1:1, and then add 2.0wt% catalyst based on trimellitic anhydride and p-aminophenylacetic acid total amount after completely dissolving Anhydrous sodium acetate was subjected to ammoniation dehydration cyclization reaction at 70°C for 3 hours to form a nitrogen-containing five-membered heterocyclic dicarboxylic acid. The dibasic acid is then reacted with epichlorohydrin (molar ratio=1:2.0) through the catalysis of 0.6wt% triphenylphosphine to obtain a hydroxyl value of 220±25mgKOH / g and a functionality of 2.
[0039] Preparation of aromatic amine polyether polyols:
[00...
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