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A kind of aluminum alloy resin composite body

A technology of aluminum alloy and composite body, applied in the direction of coating, surface reaction electrolytic coating, electrolytic coating, etc., can solve the problem of weak bonding between aluminum alloy and resin

Active Publication Date: 2017-05-31
BYD CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] The present invention aims to solve the technical problem in the prior art that the bonding force between aluminum alloy and resin is weak when preparing an aluminum alloy resin composite

Method used

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  • A kind of aluminum alloy resin composite body
  • A kind of aluminum alloy resin composite body
  • A kind of aluminum alloy resin composite body

Examples

Experimental program
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preparation example Construction

[0036] The present invention also provides a method for preparing the above-mentioned aluminum alloy resin composite body, comprising the following steps: placing the surface-treated aluminum alloy base material in a mold, and then injecting the resin composition into the mold to combine with the surface-treated aluminum alloy base material , to obtain an aluminum alloy composite body after molding, wherein the surface-treated aluminum alloy substrate is the above-mentioned surface-treated aluminum alloy.

[0037] According to the preparation method of the aluminum alloy resin composite provided by the present invention, the main resin and the polyolefin resin are uniformly mixed to prepare a resin composition. The preparation method of the resin composition adopts the method of physical blending commonly used by those skilled in the art, that is, the main resin and the polyolefin resin are uniformly mixed, extruded and granulated by a twin-screw extruder, and ready for use.

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Embodiment 1

[0043] This example prepares an aluminum alloy resin composite body;

[0044] 1. Pretreatment: Cut the commercially available 1mm thick 5052 aluminum alloy plate into 15mm*80mm rectangular pieces, put it into a polishing machine for grinding, and then wash it with absolute ethanol, and then dip the aluminum alloy substrate in 40g / L sodium hydroxide aqueous solution, after 2min, take it out and rinse it with deionized water to obtain a pretreated aluminum alloy sheet;

[0045] 2. Surface treatment 1: Put the above-mentioned aluminum alloy sheet as an anode into an H2SO4 anodizing tank with a concentration of about 20wt%, electrolyze it at 20V and 18°C ​​for 10min, and dry it;

[0046] 3. Surface treatment 2: prepare 500ml of 10wt% sodium carbonate (pH=12) in a beaker, soak the obtained aluminum alloy sheet in it at 20°C, take it out after 5min, put it into a beaker filled with water and soak for 1min, Cycle like this for 5 times, after the last soaking in water, dry the alumin...

Embodiment 2

[0051] The aluminum alloy resin composite was prepared by the same method as in Example 1, except that the surface treatment 1 was to put the above-mentioned aluminum alloy sheet as an anode into an H2SO4 anodic oxidation tank containing a concentration of about 20 wt%, at a voltage of 15V and at 18°C. Electrolyze for 10min and blow dry. Adopt the same method as claim 1 to record the aluminum oxide film layer with a thickness of 5um on the surface of the aluminum alloy sheet after electrolysis, the aluminum oxide film layer contains nano-micropores with an aperture of 20-40nm, and the hole depth of the nano-micropores is 1um. It is measured that there are corrosion holes with a diameter of 300-1000nm on the surface of the aluminum alloy sheet after soaking, and the depth of the corrosion holes is 4um. It can be observed that there are such as figure 1 The structure shown is similar to the double-layer three-dimensional hollow structure, and there are interconnected structure...

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Abstract

The invention provides an aluminum alloy resin complex comprising an aluminum alloy substrate and a resin layer, wherein the aluminum alloy substrate comprises an aluminum alloy body and an anode oxide film layer on the surface of the aluminum alloy body, the anode oxide film layer is composed of an outer surface layer part and an inner layer part, a corrosion hole is formed in the outer surface layer part, the aperture of the corrosion hole is 200-2000 nm, the inner layer part contains a nanopore produced by anode oxidation, and the corrosion hole is communicated with the nanopore; the nanopore and the corrosion hole are filled with a resin composition forming the resin layer. In the aluminum alloy resin complex provided by the invention, the aluminum alloy has a good binding force with the resin, and moreover the process is simple, easily achieves large-scale production and is pollution-free.

Description

[0001] related application [0002] This application is a divisional application of the Chinese invention patent application with application number 201210043634.6. technical field [0003] The invention relates to an aluminum alloy resin composite body and a preparation method thereof, more specifically, to an aluminum alloy resin composite body formed by integrating an aluminum alloy with double-layer channels and a thermoplastic resin and a preparation method thereof. Background technique [0004] In the field of parts manufacturing of automobiles, household electrical appliances, industrial machines, etc., the integrated molding technology of metal and resin is required. At present, the industry uses adhesives to integrate metal and synthetic resin at room temperature or under heating. Although the above method can be used to prepare a composite body formed of metal and plastic, the bonding force between the metal and plastic of the composite obtained according to these ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C25D11/04C25D11/24B29C45/14
Inventor 孙剑曾娟程俊
Owner BYD CO LTD