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Diamond nonstick coating composition and preparation method thereof

A technology of non-stick coatings and compositions, applied in the direction of coating, etc., can solve the problems of large abrasion, large coefficient of linear expansion, poor compatibility, etc., and achieve the effect of improving the wear resistance of the coating film

Inactive Publication Date: 2015-07-01
SHANGHAI MINGFU NEW MATERIAL TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Since the non-stick coating uses polytetrafluoroethylene, polyvinylidene fluoride and other organic substances as the non-stick coating, the thermal conductivity is extremely poor. For example, the intrinsic thermal conductivity of polytetrafluoroethylene is 0.24w / m·K, so it is And during use, the thermal conductivity is poor, the heated object heats up slowly, and the energy consumption is high; in addition, polytetrafluoroethylene (PTFE) also has disadvantages such as large wear, large creep, large linear expansion coefficient, and unstable product size.
At present, the thermal conductivity of non-stick coatings is improved by adding fillers with good thermal conductivity such as aluminum powder, alumina powder, silicon carbide, etc. However, the above-mentioned metals, alloys or metal oxides have poor compatibility with solvents, and metals or alloys are easy to be Oxidation, making it have defects such as wear resistance and poor hardness
[0004] Through the search of the prior art, it is found that the patent CN 101717601A discloses a non-stick coating made of polytetrafluoroethylene as a film-forming substance, which is mainly composed of polytetrafluoroethylene, solvent gasoline, alkyd resin, surfactant, Grinding filler, but the PTFE coating has the disadvantages of poor wear resistance and easy scratching
Patent CN 102643582 A discloses a non-stick coating containing main film-forming fluororesin, acrylic emulsion and water, with or without additives. Although its surface has no pinholes and no yellowing defects, it also has wear resistance Insufficient problem
[0005] In summary, the existing PTFE non-stick coatings have problems such as poor thermal conductivity, insufficient hardness, and insufficient wear resistance, which limit their application.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] This embodiment relates to a diamond non-stick coating composition and a preparation method thereof. The diamond non-stick coating composition includes a primer and a top coat:

[0038] Accounting for the weight percent content of the total weight of the primer, the primer includes: 1% carbon black, 10% polyoxyethylene alkyl ether surfactant, PTFE32%, NMP15%, water 31%, diamond powder (grain Diameter 30 microns) 1%, adhesive resin (polyamideimide resin) 10%;

[0039] Accounting for the weight percent content of the total weight of the finish paint, the finish paint comprises: polyoxyethylene alkyl ether surfactant 20%, PTFE 35%, water 26%, diamond powder (30 microns in particle size) 1%, organic Solvent (S-150, ethylene glycol with a mass ratio of 1:1) 18%.

[0040] Concrete preparation comprises the following steps:

[0041] A. Take 10wt.% of water, 3wt.% of surfactant and carbon black for dispersion and grinding, take 10wt.% of water, 3wt.% of surfactant and polyte...

Embodiment 2

[0050] This embodiment relates to a diamond non-stick coating composition and a preparation method thereof. The diamond powder non-stick coating composition comprises primer and topcoat:

[0051] Accounting for the weight percent content of the primer gross weight, the primer comprises: carbon black 5%, polyoxyethylene alkyl ether surfactant 5%, PTFE 10%, NMP 10%, water 50%, diamond powder (grain Diameter 20 microns) 5%, adhesive resin (polyethersulfone resin) 15%;

[0052] Accounting for the weight percentage content of topcoat gross weight, described topcoat comprises: polyoxyethylene alkyl ether surfactant 5%, PTFE40%, water 40%, diamond 0%, organic solvent (mass ratio is 1: 2:1 ethylene glycol, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether) 15%.

[0053] Concrete preparation comprises the following steps:

[0054] A, get 16wt.% water, 1.5wt.% surfactant and carbon black dispersion grinding, get 16wt.% water, 1.5wt.% surfactant and polytetrafluoroet...

Embodiment 3

[0063] This embodiment relates to a diamond non-stick coating composition and a preparation method thereof. The diamond non-stick coating composition includes a primer and a top coat:

[0064] In terms of weight percent of the total weight of the primer, the primer includes: 4.5% carbon black, 9.5% polyoxyethylene alkyl ether surfactant, PTFE31%, NMP20%, water 30%, diamond powder 0% , adhesive resin (a mixture of polyamideimide resin and polyethersulfone resin with a mass ratio of 2:1) 5%;

[0065] Accounting for the weight percent content of the total weight of the topcoat, the topcoat comprises: polyoxyethylene alkyl ether surfactant 6%, PTFE50%, water 20%, diamond powder (50 microns in particle size) 5%, organic Solvent (diethylene glycol monomethyl ether) 19%.

[0066] Concrete preparation comprises the following steps:

[0067] A. Take 10wt.% of water, 3wt.% of surfactant and carbon black for dispersion and grinding, take 10wt.% of water, 3wt.% of surfactant and polyte...

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Abstract

The invention discloses a diamond nonstick coating composition and a preparation method thereof. The coating composition comprises a primer and a finishing coat, wherein the primer comprises the following components in percentage by weight: 1-5% of carbon black, 5-10% of a surfactant, 10-32% of polytetrafluoroethylene, 10-20% of N-methylpyrrolidone, 30-50% of water, 0-5% of diamond powder and 5-15% of bonding resin, totally 100%; the finishing coat comprises the following components in percentage by weight: 5-20% of a surfactant, 35-50% of polytetrafluoroethylene, 20-40% of water, 0-5% of diamond powder and 15-19% of an organic solvent, totally 100%; the percentages by weight of the diamond powder in the primer and finishing coat are not zero at the same time. The diamond nonstick coating composition disclosed by the invention has excellent coating pencil hardness, heat conductivity and wear resistance.

Description

technical field [0001] The invention belongs to the technical field of non-stick coating production, and relates to the production technology of water-based polytetrafluoroethylene non-stick coating, in particular to a diamond non-stick coating composition and a preparation method thereof. Background technique [0002] Non-stick coating is a special coating whose coating surface is not easily adhered by other sticky substances or easily removed after adhesion. This kind of coating is widely used in household appliances, cooking utensils, automobiles, machinery, chemical industry and other industries due to its anti-adhesive properties such as extremely low surface energy, small friction coefficient and easy sliding. Since DuPont of the United States successfully developed polytetrafluoroethylene (PTFE) non-stick coatings in 1938, it developed PVDF (polyvinylidene fluoride resin) resin construction fluorine coatings in the 1960s. Fluorine-containing resins with functional gr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D127/18C09D7/12
CPCC09D127/18C08K3/04C08K2201/003C08K2201/014C08L2205/03C08L2205/035C09D7/61C09D7/69C08L79/08C08L71/02C08L81/06
Inventor 卞东蛟
Owner SHANGHAI MINGFU NEW MATERIAL TECH CO LTD
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