A kind of preparation method of composite antibacterial water-based varnish
A water-based varnish and composite technology, which is applied to biocide-containing paints, anti-fouling/underwater coatings, coatings, etc., can solve the problems of general dispersibility and effect, fast drying speed, and harmfulness to human body, and achieve improvement Better antibacterial effect, enhanced bactericidal effect, and good load fastness
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Embodiment 1
[0046] A preparation method of composite antibacterial water-based varnish, carried out as follows, wherein the following parts of each material are parts by weight,
[0047] (1) Preparation of halloysite nanotubes modified by silane coupling agent:
[0048]The halloysite nanotubes with a purity of 85% through a 500-mesh sieve were roasted at 400°C for 3.5 hours to obtain heat-activated halloysite nanotubes from which crystal water had been removed; the heat-activated halloysite nanotubes obtained above were obtained 10 parts and 13 parts of silane coupling agent were added to 125 parts of ethanol aqueous solution, ultrasonically dispersed at 60°C for 2 hours, then suction filtered, washed, and vacuum-dried to obtain silane coupling agent-modified halloysite nano Tube.
[0049] (2) Preparation of silver-loaded halloysite nanotubes:
[0050] Dissolve 10 parts of silver nitrate in deionized water, then add 10 parts of the silane coupling agent-modified halloysite nanotubes obt...
Embodiment 2
[0065] A preparation method of composite antibacterial water-based varnish, carried out as follows, wherein the following parts of each material are parts by weight,
[0066] (1) Preparation of halloysite nanotubes modified by silane coupling agent:
[0067] Pass halloysite nanotubes with a purity of 85% through a 500-mesh sieve, take 20 parts of halloysite nanotubes and 200 parts of a 3wt% hydrochloric acid solution into 200 parts of deionized water, and stir at 50°C for 4 hours After filtering and drying, acid-activated halloysite nanotubes are obtained. Calcining the obtained acid-activated halloysite nanotubes at a temperature of 400°C for 3.5 hours to obtain heat-activated halloysite nanotubes from which crystal water has been removed; take 10 parts of the heat-activated halloysite nanotubes obtained above and a silane coupling agent 13 parts, which were added to 125 parts of ethanol aqueous solution, ultrasonically dispersed at 60°C for 2 hours, and then suction filtere...
Embodiment 3
[0086] A preparation method of composite antibacterial water-based varnish, carried out as follows, wherein the following parts of each material are parts by weight,
[0087] (1) Preparation of halloysite nanotubes modified by silane coupling agent:
[0088] Pass halloysite nanotubes with a purity of 90% through a 500-mesh sieve, take 20 parts of halloysite nanotubes and 200 parts of 2wt% hydrochloric acid solution into 200 parts of deionized water, and stir for 4 hours at 50°C After filtering and drying, acid-activated halloysite nanotubes are obtained. Calcining the obtained acid-activated halloysite nanotubes at a temperature of 300° C. for 4 hours to obtain heat-activated halloysite nanotubes from which crystal water has been removed; take 10 parts of the above-mentioned heat-activated halloysite nanotubes and a silane coupling agent 10 parts, which were added to 100 parts of ethanol aqueous solution, ultrasonically dispersed at 50° C. for 2 hours, and then suction filter...
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