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A kind of preparation method of polymer dye based on hyperbranched polyamine-ester

A technology of polymer dyes and hyperbranched polymerization, which is applied in the field of preparation of polymer dyes, can solve problems such as undiscovered problems, and achieve the effect of improving the utilization rate of dyes and reducing the content of dyes

Inactive Publication Date: 2017-06-23
QILU UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

So far, no relevant reports have been found on the grafting of reactive dyes and hyperbranched polymers to prepare polymer dyes and apply them to the dyeing of leather, fur and their products.

Method used

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  • A kind of preparation method of polymer dye based on hyperbranched polyamine-ester
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  • A kind of preparation method of polymer dye based on hyperbranched polyamine-ester

Examples

Experimental program
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Effect test

Embodiment 1

[0029] Weigh 13.32g of diisopropanolamine and 30g of methanol into a four-necked flask, slowly raise the temperature to 40°C, then slowly drop 8.6g of methyl acrylate into the four-necked flask for about 12 hours, and remove the methanol under reduced pressure to obtain AB 2 type monomer.

[0030] Add 21.92gAB to the four-neck bottle 2 Type monomer, 0.64g trimethylolpropane, 0.22g p-toluenesulfonic acid were incubated and reacted at 120°C for 4 hours, and then vacuumized to continue the reaction for 4 hours to obtain the third-generation hyperbranched polyamine-ester. Cool the reactant to 90°C, add 8.96g of maleic anhydride, react for 4h, then cool down to below 60°C, and neutralize to pH 8-9 with 30% sodium hydroxide solution.

[0031] Dissolve 6.18g of reactive yellow K-RN in 37g of water, add the above product, and react at 60°C for 2h to obtain a yellow water-soluble polymer dye based on hyperbranched polyamine-ester.

Embodiment 2

[0033] Weigh 10.5g of diethanolamine and 30g of ethanol into the four-necked flask, slowly raise the temperature to 35°C, then slowly drop 8.6g of methyl acrylate into the four-necked flask, react for about 6 hours, and remove the ethanol under reduced pressure to obtain AB 2 type monomer.

[0034] Add 19.1gAB in the four-necked bottle 2 Type monomer, 0.44g glycerol, 0.20g p-toluenesulfonic acid, react at 100°C for 4h, and then continue to react for 4h under vacuum. The temperature of the reactant was lowered to 80°C, 2.28g of succinic anhydride was added, reacted for 4h, then cooled to below 40°C, and neutralized to pH 8-9 with 30% sodium hydroxide solution.

[0035] Dissolve 4.84g of Reactive Brilliant Orange K-GN in 29g of water, add the above product, and react at 95°C for 2h to obtain an orange water-soluble polymer dye based on hyperbranched polyamine-ester.

Embodiment 3

[0037] Weigh 10.5g of diethanolamine and 30g of ethanol into a four-necked flask, slowly raise the temperature to 40°C, then slowly drop 10g of ethyl acrylate into the four-necked flask, react for about 24 hours, and remove ethanol under reduced pressure to obtain AB 2 type monomer.

[0038] Add 20.5gAB to the four-necked bottle 2 Type monomer, 0.71g triethanolamine, 0.21g p-toluenesulfonic acid were reacted under vacuum at 140°C for 8h to obtain the third generation hyperbranched polyamine-ester. The temperature of the reactant was lowered to 80°C, 5.7g of succinic anhydride was added, reacted for 4h, then cooled to below 40°C, and neutralized to pH 8-9 with 30% sodium hydroxide solution.

[0039] After dissolving 9g of Reactive Brilliant Blue X-ARL in 39g of water, add the above product and react at 70°C for 2h to obtain a blue water-soluble polymer dye based on hyperbranched polyamine-ester.

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Abstract

The invention relates to the technical field of special polymeric dyes for leather, fur and leather and fur products, in particular to a preparation method for a polymeric dye based on hyperbranched polyamine-ester. The preparation method comprises the following steps: by taking alcohol amine and acrylate as raw materials, reacting the alcohol amine and the acrylate, and removing a solvent after the reaction is ended to obtain an AB2 type monomer; reacting the AB2 type monomer, a catalyst and a micromolecular polyhydroxy compound to obtain hydroxyl-terminated hyperbranched polyamine-ester, and performing modification by using acid anhydride; reacting acid anhydride modified hyperbranched polyamine-ester with an active dye to obtain the polymeric dye. Compared with the prior art, the obtained polymeric dye can effectively improve the dyeing fastness, washing resistance, sweat resistance and other performance of the leather, the fur and the leather and fur products, the dye utilization rate is increased, and the content of dyes in waste liquor is reduced.

Description

[0001] (1) Technical field [0002] The invention relates to the technical field of polymer dyes for leather, fur and their products, in particular to a preparation method of polymer dyes based on hyperbranched polyamine-ester. [0003] (2) Background technology [0004] Dyeing is an important process in the leather production process, which plays an important role in imparting bright colors and beautiful appearance to the finished leather. In recent years, with the improvement of environmental protection requirements and the progress of society, people have put forward higher standards for leather dyes, which not only require dyes to be lightfast, washable, friction-resistant, and firmly bonded, but also require dyes to have higher absorption rates. Wastewater is easier to treat. However, at present, acid dyes and direct dyes in the laying industry are mainly used for dyeing in tanning production. These dyes can only be combined with skin collagen fibers in the form of ionic ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G83/00D06P1/52D06P3/32D06P3/30C09B69/10
Inventor 王玉路靳丽强
Owner QILU UNIV OF TECH
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