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Production method of anti-ozone high-performance natural rubber

A technology of natural rubber and production method, which is applied in the production of ozone-resistant high-performance natural rubber and the field of natural rubber production, which can solve the problems of easy mold growth, intermingling, and thermal damage of non-glue substances in molecular chains, so as to maintain ozone resistance and The effect of high performance, low production cost and simple production process

Inactive Publication Date: 2015-12-02
HAINAN UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The control of the drying process is the key to maintaining ozone resistance and obtaining high-performance products. Excessive temperature will seriously damage the molecular chains of rubber, degrade the molecular chains, and cause the non-adhesive substances on the molecular chains to be destroyed by heat, resulting in mechanical properties and aging properties of the product. The ozone resistance performance is reduced; the temperature is too low and the drying time is too long, and it is easy to grow mildew and sandwiches.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Take 1000Kg of fresh PRIM600 natural rubber latex with a dry rubber content of 28% and an ammonia content of 0.008% in the mixing tank, add protease and clear water that meets the standard to adjust the dry rubber content to 24%, and use 2% formic acid after calculation Dosage, add acid to the coagulation tank through parallel flow, the latex is mixed for 10 minutes to flocculate, and matured for 15 hours to form a coagulation without white water. The clot is thinned and dehydrated, washed, pressed into tablets (wherein: the thickness of the film is 7-9mm, and the nitrogen content is 0.20%), dried for 5 days (at a temperature of 60°C), granulated, and dried to obtain an ozone-resistant high-performance natural rubber product. Determine the quality index and performance of dry glue.

[0028] Quality index and performance: impurity content is 0.015%, plastic initial value P0 is 50, plastic retention rate PRI is 90%, ash content is 0.2%, nitrogen content is 0.20%, Mooney v...

Embodiment 2

[0030] Take 1000Kg of fresh PR107 natural rubber latex with a dry rubber content of 32% and an ammonia content of 0.006% in the mixing tank, add protease and clear water that meets the standard to adjust the dry rubber content to 24%, and use 2% formic acid after calculation Dosage, add acid to the coagulation tank through parallel flow, the latex is mixed for 8 minutes to flocculate, and matured for 15 hours to form a coagulation without white water. The clot was thinned and dehydrated, washed, pressed into tablets (wherein: film thickness 8-9mm, nitrogen content 0.25%), dried for 6 days (temperature 55°C), granulated, and dried to obtain high-performance natural rubber products. Quality indicators and properties of dry glue.

[0031] Quality index and performance: impurity content is 0.015%, plastic initial value P0 is 50, plastic retention rate PRI is 90%, nitrogen content is 0.25%, ash content is 0.18%, Mooney viscosity is 82 units; vulcanization time of pure rubber formul...

Embodiment 3

[0033] Take 1000Kg of fresh Reyan 7-33-97 natural rubber latex with a dry rubber content of 30% and an ammonia content of 0.005% in the mixing tank, add protease and clear water that meets the standard to adjust the dry rubber content to 22%. Concentration is the dosage of formic acid of 2%, add acid to coagulation tank through parallel flow, latex mixes 8 minutes to appear flocculation, aging 15 hours forms the coagulation without white water. The clot is subjected to thinning and dehydration, washing, granulation, tabletting (among them: film thickness 7-9mm, nitrogen content 0.18%), hanging sheet drying for 9 days (temperature 65°C), granulation, and drying to obtain high-performance natural rubber Products, determine the quality index and performance of dry glue.

[0034] Quality indicators and performance: impurity content is 0.013%, plastic initial value P0 is 50, plastic retention rate PRI is 92%, nitrogen content is 0.18%, ash content is 0.16%, Mooney viscosity is 80 u...

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Abstract

The invention belongs to the field of natural rubber production technology, and relates to a production method of anti-ozone high-performance natural rubber. The production method comprises the steps of taking fresh natural rubber latex of a natural rubber strain, which is suitable for binding with protein, adding alkaline protease and adopting a freezing method to freeze the fresh rubber latex, so as to obtain flocculation glue; curdling and curing the flocculation glue to obtain a curd or a sheet rubber; laminating and dewatering, washing, pelleting, and pressing to obtain a rubber sheet; hanging and drying the rubber sheet, pelleting, drying and obtaining an anti-ozone high-performance natural rubber product. The production method provided by the invention is simple in production process and low in production cost, and each step adopts the process and the method having minimum damage on a rubber molecular chain, the nitrogen content is controlled, the protein having an important effect on ozone resistance and ageing resistance is retained, micro orientation of a local molecular chain is formed, the ozone resistance and high performance of the product are kept, the product quality is good, the production recovery is high, the production process is green and environment friendly, and the production is economical and efficient.

Description

technical field [0001] The invention belongs to the technical field of natural rubber rubber production, and relates to a production method of natural rubber, in particular to a production method of ozone-resistant high-performance natural rubber. Background technique [0002] In addition to rubber hydrocarbons and water, natural rubber latex also contains a large amount of non-colloidal substances such as proteins, lipids, organic acids and sugars. Because the rubber particles in natural rubber latex are doubled by hydrophilic substances such as proteins and lipids, Electric layer protection, so that the natural latex can maintain a stable colloidal state, when the natural latex is contaminated by microorganisms, or added with acid, inorganic salt, or under the conditions of heating, freezing, radiation, etc., the natural latex can be destabilized and solidified or gelled . At present, the coagulation methods of natural latex are mainly chemical method, biological method a...

Claims

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Application Information

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IPC IPC(8): C08L7/00C08L89/00C08C1/15
Inventor 廖建和黄桂春黄向前谢兴怀陈永平黄海清王兵兵张仁奕陈琅
Owner HAINAN UNIVERSITY