Small-molecular clean fracturing fluid and preparation method and application thereof

A technology for cleaning fracturing fluid and fracturing fluid, applied in the field of fracturing fluid, can solve problems such as high price, filter cake damage, blockage, etc., and achieve the effects of complete gel breaking, small filtration loss and simple preparation

Active Publication Date: 2016-03-02
PETROCHINA CO LTD
View PDF3 Cites 14 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Although tight oil and gas resources are abundant, they have not been effectively developed and utilized, mainly because the diameter of pore throats in tight sandstone is very small (nanoscale), and the use of conventional macromolecular guar gum fracturing fluids will often cause damage to the reservoir. It is manifested in three aspects: the adsorption and retention of macromolecular substances block the seepage channel of reservoir fluid, the fracturing fluid residue blocks the support fracture, and the filter cake will cause damage to the wall of the fracture.
[0004] At present, many types of clean fracturing fluids have been developed and applied, but they do not pay attention to the molecular size of fracturing fluids, and most of them are expensive, have a single selection of materials, and are not temperature-resistant (more than 80% of the tight oil reservoir temperature They are all in the range of 80-100°C, while the temperature resistance of conventional fracturing fluid systems cannot meet the temperature requirements of tight oil fields)

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Small-molecular clean fracturing fluid and preparation method and application thereof
  • Small-molecular clean fracturing fluid and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] This embodiment provides a method for preparing small molecule clean fracturing fluid, which comprises the following steps:

[0034] At room temperature, prepare 200 mL of an aqueous solution containing 0.5 wt % potassium chloride;

[0035] Dissolve 1.6g of octadecyltrimethylammonium chloride and 0.04g of fatty alcohol polyoxyethylene ether (AEO-3) in 4g of isopropanol, and mix uniformly to obtain a thickener solution;

[0036] At a constant temperature of 50°C, add the thickener solution to the prepared potassium chloride aqueous solution, continue stirring to form a uniform mixed solution, and then cool to room temperature;

[0037] Finally, 1.0 g of sodium salicylate was added to the above mixed solution, stirred until a uniform gel was formed, and aged at 35° C. for 24 hours to obtain a small-molecule clean fracturing fluid.

[0038] The small molecule clean fracturing fluid provided by this embodiment is in 170s -1 The viscosity-temperature curve under figure 1 ...

Embodiment 2

[0046] This embodiment provides a method for preparing small molecule clean fracturing fluid, which comprises the following steps:

[0047] At room temperature, prepare 200 mL of an aqueous solution containing 0.6 wt % potassium chloride;

[0048] Dissolve 3.6g of octadecyltrimethylammonium chloride and 0.06g of fatty alcohol polyoxyethylene ether (AEO-3) in 4g of isopropanol, and mix uniformly to obtain a thickener solution;

[0049] At a constant temperature of 50°C, add the thickener solution to the prepared potassium chloride aqueous solution; keep stirring to form a uniform mixed solution, and then cool to room temperature;

[0050] Finally, 2.0 g of sodium salicylate was added to the mixed solution, stirred until a uniform jelly was formed, and aged at room temperature for 24 hours to obtain a small-molecule clean fracturing fluid.

Embodiment 3

[0052] This embodiment provides a method for preparing small molecule clean fracturing fluid, which comprises the following steps:

[0053] At room temperature, prepare 200 mL of an aqueous solution containing 0.6 wt % potassium chloride;

[0054] Dissolve 5.6g behenyltrimethylammonium chloride and 0.07g fatty alcohol polyoxyethylene ether (AEO-3) in 6g isopropanol, and mix well to obtain a thickener solution;

[0055] At a constant temperature of 50°C, add the thickener solution into the prepared potassium chloride aqueous solution, continue stirring to form a uniform mixed solution, and then cool to room temperature;

[0056] Finally, 2.3 g of sodium salicylate was added to the above mixed solution, stirred until a uniform jelly was formed, and aged at room temperature for 24 hours to obtain a small-molecule clean fracturing fluid.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
diameteraaaaaaaaaa
viscosityaaaaaaaaaa
viscosityaaaaaaaaaa
Login to view more

Abstract

The invention provides a small-molecular clean fracturing fluid and a preparation method and an application thereof. The fracturing fluid includes a thickening agent, an auxiliary agent, a co-solvent, an activator, an inorganic salt and water, wherein the thickening agent, the auxiliary agent, the co-solvent, the activator and the inorganic salt are each composed of a substance with the molecular weight of less than 500 and the molecular dynamics diameter of less than 60 nm, and the mass ratio of the thickening agent to the auxiliary agent to the co-solvent to the activator to the inorganic salt to water is (0.8-3.5) to (0.01-0.05) to (1.0-3.0) to (0.4-1.5) to (0.1-0.8) to 100. The invention also provides a preparation method for the fracturing fluid. The method comprises the steps: dissolving the inorganic salt in water; mixing the thickening agent, the auxiliary agent and the co-solvent; and adding the thickening agent solution into the salt solution, cooling the mixed solution to room temperature, adding the activator to the mixed solution, aging at room temperature, and thus obtaining the small-molecular clean fracturing fluid. The fracturing fluid provided by the invention has the advantages of wide range of temperature resistance, good shearing property, low cost and simple preparation.

Description

technical field [0001] The invention relates to a fracturing fluid, in particular to a small molecule clean fracturing fluid for fracturing tight oil formations. Background technique [0002] With the sharp increase in world energy demand, unconventional oil and gas resources are getting more and more attention. Tight oil reservoirs belong to unconventional oil reservoirs, which have a large area of ​​continuous distribution of oil and gas, porosity less than 10%, permeability generally less than 0.1mD, oil-bearing Area greater than 1×10 4 km 2 Tight oil is recognized as an important replacement resource for increasing oil and gas reserves and production in the future. It is for this reason that the development of tight oil has attracted widespread attention in recent years and has become the theme of oil and gas resource development in my country and the world. [0003] Although tight oil and gas resources are abundant, they have not been effectively developed and utilize...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/68E21B43/26
CPCC09K8/685E21B43/16
Inventor 郭琳李军李霞刘强李超徐乐曾双红
Owner PETROCHINA CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products