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PVDF ultrafilter membrane

A technology of ultrafiltration membrane and polyvinylidene fluoride, applied in ultrafiltration, membrane technology, semi-permeable membrane separation, etc., can solve problems that need to be improved, and achieve excellent corrosion resistance

Inactive Publication Date: 2016-03-30
CHANGSHU LIYUAN MEMBRANE TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Corrosion resistance, heat resistance, cold resistance, oxidation resistance, and weather resistance of existing ultrafiltration membranes, separation membranes, and hollow fiber membranes need to be improved

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A kind of PVDF ultrafiltration membrane, take polyvinylidene fluoride as the raw material of membrane, described polyvinylidene fluoride is prepared by following steps:

[0021] 1) Put 1 to 2 parts by weight of sodium peroxide, 1.6 parts by weight of hydrogen peroxide, and 1.9 parts by weight of inorganic alkali solution into the reaction kettle, mix well, and then put in 0.9 parts by weight of sodium butyl ricinoleate sulfate, 15.2 parts by weight of hexafluoroethane Solvent, 0.4 parts by weight of sulfuryl chloride solution, stirred and reacted at -5.5°C for 36 minutes;

[0022] 2) Add 4.7 parts by weight of polyglycerol monostearate, 7.3 parts by weight of polyacrylic acid solution, 78 parts by weight of vinylidene fluoride monomer, and 3.8 parts by weight of 2,2,3-trimethylpentane, and stir at 31°C Reaction, the reaction is terminated when the pressure drops below 0.26MPa;

[0023] 3) Filtrate, wash, and dry to obtain powdered polyvinylidene fluoride.

Embodiment 2

[0025] The PVDF ultrafiltration membrane uses polyvinylidene fluoride as the raw material of the membrane, and the polyvinylidene fluoride is prepared by the following steps:

[0026] 1) Put 1 part by weight of sodium peroxide, 1.6 parts by weight of hydrogen peroxide, and 1.9 parts by weight of inorganic alkali solution into the reaction kettle, mix them evenly, and then put in 0.9 parts by weight of sodium butyl ricinoleate sulfate, 15.2 parts by weight of hexafluoroethane solvent, 0.4 parts by weight of sulfonyl chloride solution, stirred and reacted at -5.5°C for 36 minutes;

[0027] 2) Add 4.7 parts by weight of polyglycerol monostearate, 7.3 parts by weight of polyacrylic acid solution, 78 parts by weight of vinylidene fluoride monomer, and 3.8 parts by weight of 2,2,3-trimethylpentane, and stir at 31°C Reaction, the reaction is terminated when the pressure drops below 0.26MPa;

[0028] 3) Filtrate, wash, and dry to obtain powdered polyvinylidene fluoride.

Embodiment 3

[0030] The PVDF ultrafiltration membrane uses polyvinylidene fluoride as the raw material of the membrane, and the polyvinylidene fluoride is prepared by the following steps:

[0031] 1) Put 2 parts by weight of sodium peroxide, 1.6 parts by weight of hydrogen peroxide, and 1.9 parts by weight of inorganic alkali solution into the reaction kettle, mix evenly, and then add 0.9 parts by weight of sodium butyl ricinoleate sulfate, 15.2 parts by weight of hexafluoroethane solvent, 0.4 parts by weight of sulfonyl chloride solution, stirred and reacted at -5.5°C for 36 minutes;

[0032] 2) Add 4.7 parts by weight of polyglycerol monostearate, 7.3 parts by weight of polyacrylic acid solution, 78 parts by weight of vinylidene fluoride monomer, and 3.8 parts by weight of 2,2,3-trimethylpentane, and stir at 31°C Reaction, the reaction is terminated when the pressure drops below 0.26MPa;

[0033] 3) Filtrate, wash, and dry to obtain powdered polyvinylidene fluoride.

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PUM

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Abstract

The invention discloses a PVDF ultrafilter membrane. The PVDF ultrafilter membrane adopts polyvinylidene fluoride (PVDF) as a raw material, and is made through the following steps: 1, adding 1-2 parts by weight of water glass, 1.6 parts by weight of hydrogen peroxide and 1.9 parts by weight of an inorganic alkali solution to a reaction kettle, mixing above materials until uniformity, adding 0.9 parts by weight of Alirol AH, 15.2 parts by weight of a hexafluoroethane solvent and 0.4 parts by weight of a sulfonyl chloride solution, and stirring and reacting above materials at -5.5DEG C for 36min; 2, adding 4.7 parts by weight of polyglycerol monostearate, 7.3 parts by weight of a polyacrylic acid solution, 78 parts of a vinylidene fluoride monomer and 3.8 parts by weight of 2,2,3-trimethylpentane, stirring and reacting above materials at 31DEG C, and terminating the reaction when the pressure reduces to 0.26MPa or below; and 3, filtering the obtained material, washing the filtered material, and drying the washed material to obtain powdery PVDF. The PVDF ultrafilter membrane can resist corrosion, heat, coldness, oxidation and weather.

Description

technical field [0001] The invention relates to a PVDF ultrafiltration membrane. Background technique [0002] The corrosion resistance, heat resistance, cold resistance, oxidation resistance and weather resistance of existing ultrafiltration membranes, separation membranes and hollow fiber membranes need to be improved. Contents of the invention [0003] The purpose of the present invention is to provide a PVDF ultrafiltration membrane, which uses polyvinylidene fluoride as the raw material of the membrane, and the prepared membrane has excellent corrosion resistance, heat resistance, cold resistance, oxidation resistance and weather resistance. [0004] In order to achieve the above object, the technical solution of the present invention is to design a PVDF ultrafiltration membrane, using polyvinylidene fluoride as the raw material of the film, and the polyvinylidene fluoride is prepared through the following steps: [0005] 1) Put 1 to 2 parts by weight of sodium perox...

Claims

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Application Information

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IPC IPC(8): C08L27/16C08L33/02C08L71/02C08F114/22B01D71/34B01D69/02B01D67/00B01D61/14
CPCC08L27/16B01D61/145B01D67/0006B01D69/02B01D71/34C08F114/22C08J5/18C08J2327/16C08J2433/02C08L2201/08C08L2203/16C08L2205/03
Inventor 徐建林邹建良宗建青
Owner CHANGSHU LIYUAN MEMBRANE TECH