The application relates to the technical field of waste
lithium ion battery recycling, in particular to a method for
lithium recovery by low-temperature efficient deconstruction of
lithium iron phosphate based on the local strengthening effect of
sodium peroxide. The method comprises the following steps: S1, uniformly mixing
lithium iron phosphate material and
sodium peroxide according to a preset
mass ratio,
grinding and refining to obtain a dry mixture containing
sodium peroxide; S2, placing the mixture in a
calcination device to obtain a
calcination product; S3,
water immersion separation: stirring and leaching the
calcination product in deionized water, and performing
solid-liquid separation to obtain a lithium-containing
aqueous solution and an iron-based leaching residue; S4, lithium
recovery and purification: removing impurities from the lithium-containing
aqueous solution by separation and purification to obtain a lithium salt product; and S5, iron
resource recovery: performing acid leaching treatment on the iron-based leaching residue to obtain an iron-containing leaching solution, so that the iron
resource recovery is realized. The application solves multiple technical bottlenecks such as large acid consumption in the existing
hydrometallurgy,
high energy consumption in the
pyrometallurgy and insufficient activity of conventional alkaline salt calcination.