Ferritic stainless steel and method for manufacturing same

A manufacturing method and stainless steel technology, applied in the field of ferritic stainless steel and its manufacturing, can solve the problems of poor impact toughness, high content of precious metal Nb, high metallurgical difficulty, etc., and achieve the effect of excellent corrosion resistance

Inactive Publication Date: 2012-07-25
BAOSHAN IRON & STEEL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, 444 ferritic stainless steel still has some disadvantages, such as poor impact toughness at room temperature and low temperature, resulting in high requirements for cold and hot processing and high temperature requirements for processing and use environments.
Especially when the thickness of the material is greater than 3mm, the brittleness tendency of stainless steel increases significantly, so the application range of this steel is still relatively small
[0003] The impact toughness of 444 ferritic stainless steel is generally low
[0007] CN101168822A discloses a high-toughness nickel-free ferritic stainless steel and its manufacturing method, the patent contains 0.02-0.1 mass fraction of rare earth, the manufacturing process is difficult, and it is not easy to realize at the production site
[0013] CN101285152A discloses a magnetic s

Method used

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  • Ferritic stainless steel and method for manufacturing same
  • Ferritic stainless steel and method for manufacturing same
  • Ferritic stainless steel and method for manufacturing same

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0056] Take Example 1 as an example:

[0057] 1. Smelting and casting

[0058] Embodiment 1 is smelted with a vacuum induction furnace. Firstly, after the addition of stabilized elements Nb and V, it is fully alloyed, and the casting temperature is controlled at 1580°C.

[0059] 2. Hot rolling

[0060] The slab is heated to 1100°C and rolled into a hot-rolled strip with a thickness of 6.0mm. The final rolling temperature is 850°C and air-cooled.

[0061] 3. Annealing and pickling after hot rolling

[0062] The strip after hot rolling is pickled by continuous annealing, the annealing temperature is kept at 1050° C., and the holding time is 6 minutes.

Example Embodiment

[0063] Experimental Example 1: Pitting Potential

[0064] The pitting potential is measured by a potentiostat, and the test standard is GB / T 17899-1999 "Measurement method for pitting potential of stainless steel". The measurement and evaluation results are listed in Table 3. For comparison and analysis, the table also lists the test results of the 444 steel grade for comparison.

Example Embodiment

[0065] Experimental Example 2: Mechanical Properties

[0066] The mechanical properties are tested by MTS universal testing machine, and the testing method is carried out according to GB / T228-2008. The impact toughness is characterized by the ductile-brittle transition temperature. First, measure the impact value of the experimental sample at different temperatures according to the method GB / T229-2007, and take the temperature corresponding to the average value of the impact values ​​of the upper platform and the lower platform as the ductile-brittle transition temperature. The lower the ductile-brittle transition temperature is, the more favorable it is for production and subsequent use. The measurement data and evaluation results are listed in Table 3. For comparison and analysis, the table also lists the test results of the 444 steel grade for comparison.

[0067]

[0068] Table 3 The performance indexes of steel of the present invention and contrast steel

[0069] ...

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Abstract

The invention relates to a ferritic stainless steel which comprises the following chemical components in percent by weight: 0.001-0.025% of C, less than1.0% of Si, less than 1.0% of Mn, less than 0.03% of P, less than 0.010% of S, 17-20% of Cr, 1.70-2.00% of Mo, less than 0.02% of Al, 0.005-0.025% of N, less than 0.0100% of O, less than 0.2% of Nb, 0.10-0.15% of V, less than 0.5% of Ni and the balance of Fe and inevitable impurities. A method for manufacturing the ferritic stainless steel comprises the following steps: smelting by using a vacuum induction furnace, or by using an electric arc furnace through external refining or by using a converter through external refining; continuously casting, wherein the degree of superheat is controlled at 30-50 DEG C, and the slab pulling speed is controlled at 0.8-2m/min; pouring at 1,580-1,600 DEG C; heating the continuously-cast billet to 1,050-1,100 DEG C, and hot rolling, wherein the finish rolling temperature is 800-900 DEG C, and the hot rolling reduction is more that 90%; cooling in air; continuously annealing the hot-rolled strip steel, and pickling, wherein the annealing temperature is 950-1,050 DEG C, the temperature is preserved for 1-1.5t min, and the t represents the thickness (mm) of the strip steel. The ferritic stainless steel has excellent impact toughness, corrosion resistance and mechanical properties.

Description

technical field [0001] The invention relates to a method capable of improving the impact toughness of ferritic stainless steel and its manufacturing technology, and simultaneously has excellent corrosion resistance and mechanical properties. Background technique [0002] Ultra-pure ferritic stainless steel 444 (18Cr-2Mo) stainless steel has excellent corrosion resistance, crevice corrosion, stress corrosion resistance, intergranular corrosion resistance and high temperature oxidation resistance, and its corrosion resistance is even better than that in some fields. 304 and 316 are currently widely used in heat exchange equipment resistant to weak medium pitting corrosion and fermentation equipment resistant to weak acids such as acetic acid, such as hot water tanks, solar water heaters, water tanks, fermentation and storage tanks, etc. 444 has replaced part of the market volume of 304 in the stainless steel water tank industry. About 90% of 444 has replaced 304 austenitic st...

Claims

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Application Information

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IPC IPC(8): C22C38/26C22C33/04C21D8/02
Inventor 张志霞江来珠王伟明韩俭余海峰李实林刚
Owner BAOSHAN IRON & STEEL CO LTD
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