A kind of multifunctional amphiphilic comb polymer modifier and its preparation method and application
A comb-type polymer and amphiphilic technology, which is applied in the field of multifunctional amphiphilic comb-type polymer modifiers, can solve the problems of general anti-fouling effect, achieve increased chemical heterogeneity, increased surface roughness, good compatibility
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0036] Example 1: Preparation of amphiphilic comb copolymers in this example
[0037] 1) Take 5g PEGMA, 3g PDMSMA, 2g KH570, 0.6g benzoyl peroxide, 30g butyl acetate. Divide 2,2-azobisisobutyronitrile into three parts, the first part is 0.028g, the second part is 0.144g, the third part is 0.028g, and the butyl acetate is divided into two parts, the first part is 2g, the second serving is 8g.
[0038] 2) Dissolve the first part of benzoyl peroxide in the first part of butyl acetate, put it into a condensing tube and N 2 The three-necked flask of the blowing device is preheated to 70°C;
[0039]3) all PEGMA, PDMSMA, KH570 and the second part of benzoyl peroxide are dissolved in the second part of butyl acetate, put into a constant pressure dropping funnel, and added dropwise to the there-necked flask of step 2), and The dripping was controlled within 2h, under nitrogen protection, after 12h of polymerization reaction, the third part of benzoyl peroxide was added, the temperat...
Embodiment 2
[0042] Example 2: Preparation of amphiphilic comb copolymers in this example
[0043] 1) Take 7g PEGMA, 2g PDMSMA, 1g KH570, 0.3g 2,2-azobisisobutyronitrile, and 30g propylene glycol methyl ether acetate. Divide 2,2-azobisisobutyronitrile into three parts, the first part is 0.069g, the second part is 0.162g, the third part is 0.069g, and propylene glycol methyl ether acetate is divided into two parts, the first part is 0.162g, the third part is 0.069g One serving is 8.1 g and the second serving is 21.9 g.
[0044] 2) Dissolve the first part of 2,2-azobisisobutyronitrile in the first part of propylene glycol methyl ether acetate, put it into a condenser tube and N 2 The three-necked flask of the blowing device is preheated to 80°C;
[0045] 3) Dissolve all PEGMA, PDMSMA, KH570, and the second part of 2,2-azobisisobutyronitrile in the second part of propylene glycol methyl ether acetate, put it into a constant pressure dropping funnel, and add step 2) by dropwise addition) In...
Embodiment 3
[0048] Example 3: Preparation of amphiphilic comb copolymers in this example
[0049] 1) Take 8g PEGMA, 1g PDMSMA, 0.4g benzoyl peroxide, 20g methyl ethyl ketone. Divide the benzoyl peroxide into three parts, the first part is 0.076g, the second part is 0.256g, the third part is 0.068g, and the methyl ethyl ketone is divided into two parts, the first part is 5g, and the third part is 0.068g. Two servings are 15g.
[0050] 2) Dissolve the first part of benzoyl peroxide in the first part of methyl ethyl ketone, put it into a condensing tube and N 2 The three-necked flask of the blowing device is preheated to 70°C;
[0051] 3) Dissolve all PEGMA, PDMSMA, KH570 and the second part of benzoyl peroxide in the second part of methyl ethyl ketone, put into a constant pressure dropping funnel, and add dropwise to the there-necked flask of step 2). , and controlled to finish dropping within 2h, under nitrogen protection, after 12h of polymerization reaction, add the third part of benz...
PUM
Login to View More Abstract
Description
Claims
Application Information
Login to View More