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Easy-to-clean and antibacterial sanitary ceramic and preparation method thereof

A sanitary ceramic and functional technology, applied in the field of antibacterial functional sanitary ceramic glaze, super hydrophilic and easy to clean, can solve the problems of increasing production process and production cost, easy oxidation and blackening, endangering human health, etc., to achieve antibacterial and easy to clean function simplified, simple and easy glaze hardness, and the effect of increasing production costs

Active Publication Date: 2016-05-11
HEBEI UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Sanitary ware is easy to adhere to dirt, which not only affects the appearance, but also becomes a breeding ground for bacteria to grow and multiply
If the dirt and bacteria are not removed in time, people's health will be endangered.
201310022848.X announced a self-cleaning glaze for sanitary ware, which enhances the ease of cleaning by applying a self-cleaning glaze on the outer layer of opaque glaze, which increases the production process and production costs
201310450589.0 announced a method for preparing antibacterial sanitary ceramics, adding nano-silver as an antibacterial agent to improve the antibacterial properties of sanitary ceramics. Nano-silver is easily oxidized and blackened during firing, which affects the whiteness of glaze

Method used

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  • Easy-to-clean and antibacterial sanitary ceramic and preparation method thereof
  • Easy-to-clean and antibacterial sanitary ceramic and preparation method thereof
  • Easy-to-clean and antibacterial sanitary ceramic and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0043] Sanitary ceramics with easy-to-clean and antibacterial functions include the following components (% by weight): 10 calcite, 5 dolomite, 2 talc, 30 feldspar, 25 quartz, 2 kaolin, 11 zircon, 0.5 barium carbonate, and burnt zinc oxide 0.5. Rare earth composite phosphate inorganic antibacterial material 3. 3 wt% cerium oxide doped tourmaline 10. Sepiolite mineral nanofiber 1.

[0044] The production process of the present invention's easy-to-clean, antibacterial functional sanitary ceramics comprises the following steps:

[0045] Glaze preparation: mix calcite, talc, feldspar, quartz, kaolin, zircon, barium carbonate, and burnt zinc oxide according to the proportion, add carboxymethyl cellulose (CMC) with a mass ratio of 0.3% of the above glaze, add water, Make water account for 35% of the total mass of solid and liquid, use zirconia balls as the grinding body, add balls according to the ratio of material: ball = 1:1.5 for wet grinding, the glaze particle size D50 is 5 μm, p...

Embodiment 2

[0050] Sanitary ceramics with easy-to-clean and antibacterial functions include the following components (% by weight): 9 calcite, 8 dolomite, 1 talc, 30 feldspar, 26 quartz, 1.5 kaolin, 11 zircon, 0.5 barium carbonate, burnt oxide Zinc 1, rare earth composite phosphate inorganic antibacterial material 2, 5wt% lanthanum oxide doped medical stone 8, sepiolite mineral nanofiber 2.

[0051] The production process of the present invention's easy-to-clean, antibacterial functional sanitary ceramics comprises the following steps:

[0052] Glaze preparation: mix calcite, dolomite, talc, feldspar, quartz, kaolin, zircon, barium carbonate, and burnt zinc oxide according to the ratio, add CMC with a mass ratio of 0.3% of the above glaze, and add water to make the water account for the water. 40% of the total mass of the material, use zirconia balls as the grinding body, add grinding balls according to the ratio of material: ball = 1:1.5, and carry out wet grinding. When the glaze partic...

Embodiment 3

[0057] Other steps are the same as in Example 1, except that calcite and dolomite, talc, feldspar, quartz, kaolin, zircon, barium carbonate, burnt zinc oxide, rare earth composite phosphate inorganic antibacterial material, 3wt% cerium oxide doping The components of tourmaline are calcite 10, dolomite 6, talc 3, feldspar 30, quartz 23, kaolin 2, zircon 10, barium carbonate 0.5, zinc oxide 1, rare earth composite phosphate inorganic antibacterial material 4, 4wt% neodymium oxide doped with 60wt% tourmaline 36wt% medical stone 9, sepiolite mineral nanofiber 1.5. The highest firing temperature is 1250°C.

[0058] Its properties are: (1) Ease of cleaning: A = 0.3g / cm 2 (2) Escherichia coli bacteriostatic rate is 98%; (3) Vickers hardness: 660Hv.

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Abstract

The invention provides an easy-to-clean and antibacterial sanitary ceramic and a preparation method thereof. The ceramic is prepared from, by mass, 77-97 parts of ceramic glaze, 1-5 parts of inorganic antibacterial material, 5-15 parts of far infrared radiation material and 1-3 parts of sepiolite mineral nano-fiber. The inorganic antibacterial material is an inorganic composite antibacterial agent or inorganic silver antibacterial agent. The far infrared radiation material is a compound of a natural mineral material and a rare earth material. The sepiolite mineral nano-fiber is a product obtained after sepiolite is crushed through an air-current mill. The easy-to-clean performance and the antibacterial performance of the sanitary ceramic are obviously improved, and antibacterial and easy-to-clean functionalization of a glaze surface is achieved on the basis that production cost is not increased.

Description

technical field [0001] The invention relates to sanitary ceramics with easy-to-clean and antibacterial functions, in particular to super-hydrophilic and easy-to-clean sanitary ceramic glazes with antibacterial functions. Background technique [0002] With the development of rapid industrialization and urbanization, my country's sanitary ceramics industry has also developed rapidly. Since the early 1990s, my country's production of sanitary ceramics has been ranked first in the world. Especially in the last 10 years, with the large-scale industrial production, my country's sanitary ceramics has emerged in Guangdong, Fujian, Sichuan and Jiangxi and other major sanitary ceramic production areas, making my country a major producer and exporter of sanitary ceramics in the world. In 2014, the output of my country's sanitary ceramics reached 197 million pieces, and the export volume was about 76.8 million pieces, with an export value of 3.205 billion US dollars. However, in my co...

Claims

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Application Information

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IPC IPC(8): C03C8/00C03C8/14C04B41/86
CPCC03C8/00C03C8/14C03C2204/02C04B41/5022C04B41/86
Inventor 王丽娟梁金生张跃丹冉松松
Owner HEBEI UNIV OF TECH
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