Easy-to-clean and antibacterial sanitary ceramic and preparation method thereof
A sanitary ceramic and functional technology, applied in the field of antibacterial functional sanitary ceramic glaze, super hydrophilic and easy to clean, can solve the problems of increasing production process and production cost, easy oxidation and blackening, endangering human health, etc., to achieve antibacterial and easy to clean function simplified, simple and easy glaze hardness, and the effect of increasing production costs
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Embodiment 1
[0043] Sanitary ceramics with easy-to-clean and antibacterial functions include the following components (% by weight): 10 calcite, 5 dolomite, 2 talc, 30 feldspar, 25 quartz, 2 kaolin, 11 zircon, 0.5 barium carbonate, and burnt zinc oxide 0.5. Rare earth composite phosphate inorganic antibacterial material 3. 3 wt% cerium oxide doped tourmaline 10. Sepiolite mineral nanofiber 1.
[0044] The production process of the present invention's easy-to-clean, antibacterial functional sanitary ceramics comprises the following steps:
[0045] Glaze preparation: mix calcite, talc, feldspar, quartz, kaolin, zircon, barium carbonate, and burnt zinc oxide according to the proportion, add carboxymethyl cellulose (CMC) with a mass ratio of 0.3% of the above glaze, add water, Make water account for 35% of the total mass of solid and liquid, use zirconia balls as the grinding body, add balls according to the ratio of material: ball = 1:1.5 for wet grinding, the glaze particle size D50 is 5 μm, p...
Embodiment 2
[0050] Sanitary ceramics with easy-to-clean and antibacterial functions include the following components (% by weight): 9 calcite, 8 dolomite, 1 talc, 30 feldspar, 26 quartz, 1.5 kaolin, 11 zircon, 0.5 barium carbonate, burnt oxide Zinc 1, rare earth composite phosphate inorganic antibacterial material 2, 5wt% lanthanum oxide doped medical stone 8, sepiolite mineral nanofiber 2.
[0051] The production process of the present invention's easy-to-clean, antibacterial functional sanitary ceramics comprises the following steps:
[0052] Glaze preparation: mix calcite, dolomite, talc, feldspar, quartz, kaolin, zircon, barium carbonate, and burnt zinc oxide according to the ratio, add CMC with a mass ratio of 0.3% of the above glaze, and add water to make the water account for the water. 40% of the total mass of the material, use zirconia balls as the grinding body, add grinding balls according to the ratio of material: ball = 1:1.5, and carry out wet grinding. When the glaze partic...
Embodiment 3
[0057] Other steps are the same as in Example 1, except that calcite and dolomite, talc, feldspar, quartz, kaolin, zircon, barium carbonate, burnt zinc oxide, rare earth composite phosphate inorganic antibacterial material, 3wt% cerium oxide doping The components of tourmaline are calcite 10, dolomite 6, talc 3, feldspar 30, quartz 23, kaolin 2, zircon 10, barium carbonate 0.5, zinc oxide 1, rare earth composite phosphate inorganic antibacterial material 4, 4wt% neodymium oxide doped with 60wt% tourmaline 36wt% medical stone 9, sepiolite mineral nanofiber 1.5. The highest firing temperature is 1250°C.
[0058] Its properties are: (1) Ease of cleaning: A = 0.3g / cm 2 (2) Escherichia coli bacteriostatic rate is 98%; (3) Vickers hardness: 660Hv.
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