Preparation method of nitrogen-resisting hydrocracking catalyst
A hydrocracking and catalyst technology, applied in physical/chemical process catalysts, molecular sieve catalysts, chemical instruments and methods, etc., can solve the problems of poor nitrogen resistance, low cracking activity, poor catalyst activity, etc., and increase secondary pores. Quantity, improve liquid yield, and facilitate the effect of diffusion
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Embodiment 1
[0035] Molecular sieve modification process:
[0036] (1) Take 200g of NaY molecular sieve raw powder prepared in the laboratory, mix it with ammonium nitrate with a concentration of 0.5mol / L according to the liquid-solid ratio of 3:1, exchange at 70°C for 3 hours, repeat this process 3 times, and the exchanged Y molecular sieve Na content in Na 2 O is calculated as 2.5%;
[0037] (2) Hydrothermally treat the Y molecular sieve obtained in step (1) at 540°C and 0.1MPa for 2 hours;
[0038] (3) Molecular sieve obtained in step (2) according to liquid-solid ratio of 5:1 and 0.3mol / L citric acid solution (concentration in H + Total) 300ml mixed, then heated up to 40°C, and reacted at constant temperature for 2 hours;
[0039] (4) Molecular sieve obtained in step (3) was dried at 150°C for 8 hours
[0040] (5) Soak the molecular sieve obtained in step (4) in n-hexane solvent for 2 hours;
[0041] (6) The molecular sieve treated in step (5) was dried at 100°C for 9 minutes;
...
Embodiment 2
[0050] Molecular sieve modification process:
[0051] (1) Take the NaY molecular sieve raw powder prepared in the laboratory, mix it with ammonium nitrate with a concentration of 0.8mol / L according to the liquid-solid ratio of 3:1, exchange at 70°C for 3 hours, repeat this process 3 times, and the Y molecular sieve after exchange Na content in Na 2 O is calculated as 2.0%.
[0052] (2) Hydrothermally treat the Y molecular sieve obtained in step (1) at 560°C and 0.1Mpa for 2 hours;
[0053] (3) Step (2) sieve the oxalic acid solution (concentration in H + Total) 400ml mixed, then heated up to 50°C, and reacted at constant temperature for 2 hours;
[0054] (4) The molecular sieve obtained in step (3) was dried at 200°C for 4 hours;
[0055] (5) Soak the molecular sieve obtained in step (4) in toluene solvent for 3 hours;
[0056] (6) The molecular sieves treated in step (5) were dried at 130°C for 15 minutes;
[0057] (7) The molecular sieve obtained in step (6) is mixed w...
Embodiment 3
[0065] Molecular sieve modification process:
[0066] (1) Take the original NaY molecular sieve powder prepared in the laboratory, mix it with ammonium nitrate with a concentration of 0.5mol / L according to the liquid-solid ratio of 5:1, exchange at 90°C for 1.5 hours, repeat this process twice, and the Y molecular sieve after exchange The Na content is 1.8% as Na2O.
[0067] (2) Hydrothermally treat the Y molecular sieve obtained in step (1) at 550°C and 0.1Mpa for 2 hours;
[0068] (3) Step (2) sieve the acetic acid solution with a liquid-solid ratio of 8:1 and 0.5mol / L (concentration in H + Total) 400ml mixed, then heated up to 60°C, and reacted at constant temperature for 2 hours;
[0069] (4) The molecular sieve obtained in step (3) was dried at 250°C for 2 hours;
[0070] (5) Soak the molecular sieve obtained in step (4) in ethylbenzene solvent for 4 hours;
[0071] (6) Dry the molecular sieve treated in step (5) at 200°C for 20 minutes;
[0072] (7) The molecular si...
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