Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Preparation method of nitrogen-resisting hydrocracking catalyst

A hydrocracking and catalyst technology, applied in physical/chemical process catalysts, molecular sieve catalysts, chemical instruments and methods, etc., can solve the problems of poor nitrogen resistance, low cracking activity, poor catalyst activity, etc., and increase secondary pores. Quantity, improve liquid yield, and facilitate the effect of diffusion

Active Publication Date: 2016-06-01
CHINA PETROLEUM & CHEM CORP +1
View PDF6 Cites 19 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In this way, there is an unsolvable contradiction between improving the nitrogen resistance of the catalyst and maintaining the hydrocracking activity. It is difficult to take care of these two problems at the same time in the conventional molecular sieve modification process.
[0003] CN200710158784.0 discloses a hydrocracking catalyst containing Y molecular sieve and its preparation method. In this invention, Y-type molecular sieve is obtained after hydrothermal treatment with a mixed aqueous solution of aluminum salt and acid, and the obtained catalyst has high activity. But nitrogen tolerance is poor
[0004] CN200810012212.6 discloses a hydrocracking catalyst carrier and its preparation method. The hydrocracking catalyst prepared by the invention has high nitrogen tolerance but low cracking activity
[0005] CN98114489.6 discloses a nitrogen-resistant hydrocracking catalyst for high-yielding middle oil, which is used for one-stage serial hydrocracking of heavy distillate oil to produce a large amount of middle distillate oil. The nitrogen content of the feed in the cracking section can reach 100 μg / g, but the Catalyst activity is poor

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Preparation method of nitrogen-resisting hydrocracking catalyst
  • Preparation method of nitrogen-resisting hydrocracking catalyst
  • Preparation method of nitrogen-resisting hydrocracking catalyst

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Molecular sieve modification process:

[0036] (1) Take 200g of NaY molecular sieve raw powder prepared in the laboratory, mix it with ammonium nitrate with a concentration of 0.5mol / L according to the liquid-solid ratio of 3:1, exchange at 70°C for 3 hours, repeat this process 3 times, and the exchanged Y molecular sieve Na content in Na 2 O is calculated as 2.5%;

[0037] (2) Hydrothermally treat the Y molecular sieve obtained in step (1) at 540°C and 0.1MPa for 2 hours;

[0038] (3) Molecular sieve obtained in step (2) according to liquid-solid ratio of 5:1 and 0.3mol / L citric acid solution (concentration in H + Total) 300ml mixed, then heated up to 40°C, and reacted at constant temperature for 2 hours;

[0039] (4) Molecular sieve obtained in step (3) was dried at 150°C for 8 hours

[0040] (5) Soak the molecular sieve obtained in step (4) in n-hexane solvent for 2 hours;

[0041] (6) The molecular sieve treated in step (5) was dried at 100°C for 9 minutes;

...

Embodiment 2

[0050] Molecular sieve modification process:

[0051] (1) Take the NaY molecular sieve raw powder prepared in the laboratory, mix it with ammonium nitrate with a concentration of 0.8mol / L according to the liquid-solid ratio of 3:1, exchange at 70°C for 3 hours, repeat this process 3 times, and the Y molecular sieve after exchange Na content in Na 2 O is calculated as 2.0%.

[0052] (2) Hydrothermally treat the Y molecular sieve obtained in step (1) at 560°C and 0.1Mpa for 2 hours;

[0053] (3) Step (2) sieve the oxalic acid solution (concentration in H + Total) 400ml mixed, then heated up to 50°C, and reacted at constant temperature for 2 hours;

[0054] (4) The molecular sieve obtained in step (3) was dried at 200°C for 4 hours;

[0055] (5) Soak the molecular sieve obtained in step (4) in toluene solvent for 3 hours;

[0056] (6) The molecular sieves treated in step (5) were dried at 130°C for 15 minutes;

[0057] (7) The molecular sieve obtained in step (6) is mixed w...

Embodiment 3

[0065] Molecular sieve modification process:

[0066] (1) Take the original NaY molecular sieve powder prepared in the laboratory, mix it with ammonium nitrate with a concentration of 0.5mol / L according to the liquid-solid ratio of 5:1, exchange at 90°C for 1.5 hours, repeat this process twice, and the Y molecular sieve after exchange The Na content is 1.8% as Na2O.

[0067] (2) Hydrothermally treat the Y molecular sieve obtained in step (1) at 550°C and 0.1Mpa for 2 hours;

[0068] (3) Step (2) sieve the acetic acid solution with a liquid-solid ratio of 8:1 and 0.5mol / L (concentration in H + Total) 400ml mixed, then heated up to 60°C, and reacted at constant temperature for 2 hours;

[0069] (4) The molecular sieve obtained in step (3) was dried at 250°C for 2 hours;

[0070] (5) Soak the molecular sieve obtained in step (4) in ethylbenzene solvent for 4 hours;

[0071] (6) Dry the molecular sieve treated in step (5) at 200°C for 20 minutes;

[0072] (7) The molecular si...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Thicknessaaaaaaaaaa
Cell constantaaaaaaaaaa
Specific surface areaaaaaaaaaaa
Login to View More

Abstract

The invention discloses a preparation method of a nitrogen-resisting hydrocracking catalyst. The preparation method comprises the following steps: 1, uniformly mixing a modified Y type molecular sieve, amorphous silicon-aluminum and / or aluminum oxide, adding dilute nitric acid, carrying out slurrying, then performing extrusion molding, and performing drying and calcination to obtain a silicon-aluminum carrier containing the modified Y type molecular sieve; and 2, performing impregnation on the carrier of the step 1 by adopting impregnation liquid containing an active metal, drying the impregnated carrier and calcining the dried carrier to obtain the hydrocracking catalyst, wherein the modified Y type molecular sieve has the following characteristics: the crystal cell constant of the modified Y type molecular sieve is 2.425-2.455nm; the bulk phase silicon-aluminum ratio is 8-30, wherein the surface layer silicon-aluminum ratio is 20-80, and the surface layer silicon-aluminum ratio is higher than the bulk phase silicon-aluminum ratio; and the specific surface area of the modified Y type molecular sieve is 600-800m<2> / g, and the pore volume is 0.40-0.70ml / g. The hydrocracking catalyst prepared by the preparation method disclosed by the invention has good reactivity and nitrogen resistance, and can be applied to different hydrocracking reaction processes such as a process for increasing the production of diesel oil, a process for increasing the production of chemical raw materials, and a process for catalyzing diesel oil hydro-conversion and the like.

Description

technical field [0001] The invention relates to a method for preparing a hydrocracking catalyst, in particular to a method for preparing a hydrocracking catalyst with strong nitrogen resistance. Background technique [0002] Hydrocracking technology has the characteristics of strong adaptability to raw materials, great flexibility in production operations and product plans, and good product quality. It can directly convert various heavy and low-quality feedstocks into high-quality jet fuel, diesel, and lubricating oil base materials that are urgently needed by the market. As well as chemical naphtha and tail oil steam cracking raw materials for ethylene production, it has become one of the most important heavy oil deep processing processes in modern oil refining and petrochemical industries, and has been increasingly widely used at home and abroad. The heart of the hydrocracking process is the hydrocracking catalyst. Hydrocracking catalyst is a typical dual-function catalys...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): B01J29/16C10G47/20
Inventor 柳伟杜艳泽王凤来刘昶秦波张晓萍
Owner CHINA PETROLEUM & CHEM CORP
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products