Conductive composite fluoroether rubber and preparation method thereof

A technology of fluoroether rubber and compound fluorine, which is applied in the field of conductive compound fluoroether rubber and its preparation, can solve the problems of less research on fluoroether rubber, and achieves good market prospects, good electrical conductivity and mechanical properties, and simple preparation method. Effect

Inactive Publication Date: 2016-06-15
SUZHOU JIEDERUI PRECISION MACHINERY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are few studies on conductive fluoroelastomers

Method used

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  • Conductive composite fluoroether rubber and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A conductive composite fluoroether rubber, prepared from the following components in parts by weight: 52 parts of fluoroether rubber, 34 parts of nitrile rubber, 6 parts of adamantine, 4 parts of tantalum powder, 3 parts of nickel sulfate, nano-chloride 4 parts of zinc chloride, 2 parts of calcium stearate, 5 parts of conductive filler, 2 parts of titanium chloride, 1 part of methyltriacetone oximinosilane, 7 parts of 2-mercaptobenzothiazole, 0.5 parts of antioxidant MB, compound Accelerator 1 part;

[0025] The conductive filler is a mixture of aluminum-doped zinc oxide, graphene powder, and carbon nanotube powder, and the weight ratio of the three is 1:1:1;

[0026] The composite accelerator includes a compound of accelerator TMTD, accelerator DM and accelerator TT in a weight ratio of 0.3:1:0.5.

[0027] The preparation method of the above-mentioned conductive composite fluoroether rubber, the preparation method comprises the following steps:

[0028] (1) Weigh acc...

Embodiment 2

[0032] A conductive composite fluoroether rubber, prepared from the following components in parts by weight: 68 parts of fluoroether rubber, 50 parts of nitrile rubber, 15 parts of adamantine, 11 parts of tantalum powder, 14 parts of nickel sulfate, nano chloride 12 parts of zinc chloride, 11 parts of calcium stearate, 16 parts of conductive filler, 10 parts of titanium chloride, 6 parts of methyltriacetone oximinosilane, 24 parts of 2-mercaptobenzothiazole, 4 parts of antioxidant MB, composite accelerator 6 copies;

[0033] Described conductive filler is the mixture of graphene powder, carbon nanotube powder, conductive carbon black and the weight ratio of the three is 1:2:1;

[0034] The composite accelerator includes a compound of accelerator TMTD, accelerator DM and accelerator TT in a weight ratio of 0.3:1:0.5.

[0035] The preparation method of the above-mentioned conductive composite fluoroether rubber, the preparation method comprises the following steps:

[0036] (1...

Embodiment 3

[0040] A conductive composite fluoroether rubber, prepared from the following components in parts by weight: 60 parts of fluoroether rubber, 42 parts of nitrile rubber, 10 parts of adamantine, 7 parts of tantalum powder, 8 parts of nickel sulfate, nano chloride 8 parts of zinc chloride, 6 parts of calcium stearate, 10 parts of conductive filler, 6 parts of titanium chloride, 3.5 parts of methyltriacetone oximinosilane, 11 parts of 2-mercaptobenzothiazole, 2.2 parts of antioxidant MB, compound Accelerator 3.5 parts;

[0041] The conductive filler is a mixture of carbon nanotube powder, conductive carbon black and nano silver powder, and the weight ratio of the three is 3:2:0.4;

[0042] The composite accelerator includes a compound of accelerator TMTD, accelerator DM and accelerator TT in a weight ratio of 0.3:1:0.5.

[0043] The preparation method of the above-mentioned conductive composite fluoroether rubber, the preparation method comprises the following steps:

[0044] (1...

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Abstract

The invention discloses conductive composite fluoroether rubber.The conductive composite fluoroether rubber is prepared from, by weight, fluoroether rubber, butadiene-acrylonitrile rubber, Jingangsu (a novel carbon material), tantalum powder, nickel sulfate, nano-zinc chloride, calcium stearate, conductive filler, titanium chloride, methyl tripropanone oxime silane, 2-mercaptobenzothiazole, an anti-aging agent MB and a compound promoter.The invention further discloses a preparation method of the conductive composite fluoroether rubber.According to the prepared conductive composite fluoroether rubber, the volume resistivity is 5.42-6.82 omega.cm, the tensile strength is 13.4-17.9 MPa, the tearing strength is 32.4-39.2 KN / m, and the electrical conductivity and the mechanical property are good; the preparation method is simple, convenient and suitable for industrial production.Therefore, the conductive composite fluoroether rubber serves as a novel conductive rubber material and has a good market prospect.

Description

technical field [0001] The invention belongs to the field of conductive materials, and in particular relates to a conductive composite fluoroether rubber and a preparation method thereof. Background technique [0002] Rubber material is one of the irreplaceable and indispensable key materials in the fields of national economy and science and technology, and it is widely used in various fields. With the continuous progress and development of science and technology and chemical industry, various requirements are put forward for the performance of rubber materials. [0003] Rubber itself is a good electrical insulator. In order to make the rubber material better applied in the field of electronic equipment, some filler materials are often added to the rubber material to endow the rubber material with new properties, such as electrical conductivity, magnetic shielding and antistatic properties. Although there are many types of conductive rubber materials in the prior art, most...

Claims

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Application Information

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IPC IPC(8): C08L71/03C08L9/02C08K13/04C08K3/04C08K7/24C08K3/22C08K5/098B29C35/02
CPCC08L71/03B29C35/02B29C35/0288C08K2201/001C08K2201/011C08L9/02C08K13/04C08K3/04C08K7/24C08K2003/2296C08K5/098
Inventor 姚振红
Owner SUZHOU JIEDERUI PRECISION MACHINERY
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