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Foaming type flame-retardant polypropylene granules and preparation method thereof

A flame-retardant polypropylene, foaming technology, applied in the field of foamed flame-retardant polypropylene particles and its preparation, can solve the problems of high air permeability of polypropylene, narrow temperature range, high transportation costs, etc., to expand the application field , broad market prospects, and the effect of high production efficiency

Active Publication Date: 2016-06-22
南京法宁格节能科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, at present, almost all polypropylene foamed material products in China are prepared and produced by imported expanded polypropylene. There is no technical method for industrialized production in China, and the price of foreign expanded polypropylene is very high, and the transportation cost is very high. bigger
Although polypropylene foam has good performance and application prospects, the development of polypropylene foam is very difficult. At present, the relevant core technology that can be industrialized has not been mastered in China. For foreign countries, the core technology of foamed polypropylene is also mastered. In the hands of a few large companies in a few countries, the main reason is: polypropylene is a crystalline polymer, which hardly flows below the crystalline melting point, but above the crystalline melting point, the melt viscosity decreases sharply, so in polypropylene The gas generated during the foaming process of propylene is difficult to be enveloped by the melt
In addition, the transformation of polypropylene from a molten state to a crystalline state will release a large amount of heat, and it takes a long time to transform from a melt to a solid
In addition, polypropylene has a high air permeability and foaming gas is easy to escape, so the temperature range suitable for polypropylene foaming is narrow, so it is difficult to obtain products with uniform and fine cells and high foaming ratio

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] (1) Material preparation: select high melt strength polypropylene, the polypropylene is the polypropylene of model HMSPPSELON-H120 produced by Guangzhou Jusailong Engineering Plastics Co., Ltd., the color masterbatch is black masterbatch, and the flame retardant is hexabromo Dodecane, the physical foaming agent adopts pentane;

[0032] (2) Through the loss-in-weight multi-component feeding system, accurately control the feeding amount of each component, according to the predetermined production formula, set the feeding amount of polypropylene to 73 parts by weight, and the amount of polyethylene to 20 parts by weight , the amount of flame retardant is 2 parts by weight, and the amount of masterbatch is 0.1 parts by weight;

[0033] (3) Set the working temperature of each part of the extruder system: the barrel temperature is 190°C, 190°C, 185°C, 185°C, 180°C, 175°C, set the temperature of the connecting section between the extruder and the heat exchanger 170°C, set the...

Embodiment 2

[0040] (1) Raw materials: select high melt strength polypropylene, the polypropylene is the model HMSPPSELON-B120 polypropylene produced by Guangzhou Jusailong Engineering Plastics Co., Ltd., the color masterbatch is pink masterbatch, and the flame retardant is hexabromo Dodecane, butane is used as physical foaming agent;

[0041] (2) Through the loss-in-weight multi-component feeding system, the feeding amount of each component is precisely controlled. According to the predetermined production formula, the amount of polypropylene is set to 80 parts by weight, and the amount of polyethylene is 18 parts. The amount of combustion agent is 1 weight part, and the amount of color masterbatch is 0.5 weight part;

[0042] (3) Set the working temperature of each part of the extruder system: the barrel temperature is 190°C, 190°C, 185°C, 185°C, 180°C, 175°C, set the temperature of the connecting section between the extruder and the heat exchanger 160°C, set the heat exchanger temperat...

Embodiment 3

[0049] (1) Raw materials: select high-melt strength polypropylene, the color masterbatch is pink masterbatch, the flame retardant is hexabromododecane, and the physical blowing agent is a mixture of carbon dioxide and nitrogen;

[0050] (2) Through the weight-loss multi-component feeding system, the feeding amount of each component is precisely controlled, and according to the predetermined production formula, the amount of polypropylene is set to 60 parts by weight, and the amount of polyethylene to 30 parts by weight, The amount of fire retardant is 5 parts by weight;

[0051] (3) Set the working temperature of each part of the extruder system: the barrel temperature is 190°C, 190°C, 185°C, 185°C, 180°C, 175°C, set the temperature of the connecting section between the extruder and the heat exchanger 180°C, set the heat exchanger temperature to 160°C;

[0052] (4) Adjust the pressure of the extruder system, then start to inject 1 part by weight of the foaming agent, and main...

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Abstract

The invention belongs to the technical field of new materials, and particularly relates to foaming type flame-retardant polypropylene granules and a preparation method thereof. The foaming type flame-retardant polypropylene granules comprise components in parts by weight as follows: 60-80 parts of polypropylene, 18-30 parts of polyethylene, 1-5 parts of a foaming agent, 1-5 parts of a flame retardant and 0-0.5 parts of color masterbatch. The preparation method comprises steps as follows: (1), polypropylene, polyethylene, the flame retardant and the color masterbatch in a formula ratio are mixed in a feeding system; (2), the component materials are sufficiently fused and mixed under the shearing action of a double-screw extruder; (3), the foaming agent in the formula ratio is injected; (4), a melt cut into granules on a template of an underwater granule cutting machine; (5), polypropylene granules obtained through cutting are screened by a sieve shaker, the screened granules are classified, and products with different granule diameters are weighed and packaged. According to the foaming type flame-retardant polypropylene granules, adverse factors in a foaming process of polypropylene can be overcome, and a foamed polypropylene material is produced successfully.

Description

technical field [0001] The invention belongs to the technical field of new materials, and in particular relates to foamed flame-retardant polypropylene particles and a preparation method thereof. Background technique [0002] Expanded polypropylene products have excellent shock resistance and energy absorption performance, high recovery rate after deformation, good heat resistance, chemical resistance, oil resistance and heat insulation. In addition, its light weight can greatly reduce the weight of items . Expanded polypropylene is also an environmentally friendly material, not only recyclable, but also naturally degradable, without causing white pollution, known as "green" foam. Due to its good mechanical properties, excellent heat resistance and environmental friendliness, expanded polypropylene is a new generation of foam materials after traditional polystyrene foam, polyurethane foam and polyethylene foam, and has a wide range of application prospects . However, at p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L23/06C08K5/02C08J9/14C08J9/12B29C47/92B29C48/92
CPCB29C48/92B29C2948/92704C08J9/122C08J9/141C08J2203/182C08J2323/12C08J2423/06C08L23/12C08L2201/02C08L2203/14C08L2205/02C08L23/06C08K5/02
Inventor 郭鑫齐许鹏
Owner 南京法宁格节能科技股份有限公司
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