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Manufacturing method of fiber reinforced polyethylene composite double-layered tube

A fiber-reinforced and composite material technology, applied in the direction of tubular objects, applications, household appliances, etc., can solve the problems of adjusting the thickness ratio of reinforced layer/fiber-reinforced layer, reducing the seismic performance of the overall pipe, and undisclosed preparation methods, etc., to achieve integration Good performance, good photo-oxidation resistance, effect of increasing compressive strength and photo-oxidation resistance

Inactive Publication Date: 2016-07-06
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] CN102408610A only discloses reinforced polyethylene pipe products, but does not disclose its preparation method, and what CN102408610A discloses is the overall reinforcement method of directly extruding pipes after mixing polyethylene with fibers and additives, and CN102408610A cannot realize specific Use requirements, adjust the thickness ratio of reinforcement layer / fiber reinforcement layer, which cannot be achieved by directly extruding pipes after mixing fibers with polyethylene
In this invention, there is no adhesive between the metal layer and the polyethylene layer in the middle, and it is simply physically superimposed and covered. From the cut surface of the composite pipe, the polyethylene layer and the metal layer can be peeled off, and the entire composite pipe has an integrated structure. Performance will be affected. For example, the excellent tensile properties of polyethylene materials during earthquake resistance will be restricted by the outer metal layer, which will reduce the seismic performance of the overall pipe; at the same time, the invention requires metal The layer is extremely thin, which brings high technical requirements to the processing, and the carbon fiber reinforced part added to the metal outer layer, due to the use of carbon fiber cloth or resin-impregnated continuous fibers (carbon fiber or glass fiber), the process is more complicated. Production higher cost

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] Preparation of carbon fiber reinforced polyethylene composite pipe with pipe diameter and pipe wall thickness ratio of 11: use cutting equipment to cut continuous carbon fiber (12KT300, Jihua Petrochemical) into chopped fiber with a length of 5mm, chopped carbon fiber and PE100 powder (Jilin Petrochemical) mixed in a ratio of 1:4 by weight, and then added 0.01wt% of antioxidant 1076 and 0.01wt% of antioxidant 1010, after thorough mixing, they were granulated together through a twin-screw extruder, and the extruder head The temperature is 200° C., and carbon fiber reinforced PE100 pellets are obtained, the fiber content of which is 20 wt%. Through the multi-layer co-extrusion pipeline production equipment, double-layer co-extrusion of PE100 pellets and carbon fiber-reinforced PE100 pellets, cooling and shaping, to obtain carbon fiber-reinforced polyethylene composite double-layer pipes. The outer layer of the pipe is a carbon fiber reinforced polyethylene layer, the inne...

Embodiment 2

[0044] Prepare a carbon fiber reinforced polyethylene composite pipe with a pipe diameter and pipe wall thickness ratio of 26: use a cutting device to cut continuous carbon fiber (12KT300, Jilin Petrochemical) into chopped fibers with a length of 7 mm, and mix chopped carbon fibers with PE100 powder (Jilin Petrochemical) mixed in a ratio of 1:3 by weight, then add 0.01wt% antioxidant 1076 and 0.01wt% antioxidant Irgafos168, after fully mixing, granulate together through a twin-screw extruder, extruder head The temperature is 200° C., and carbon fiber reinforced PE100 pellets are obtained with a fiber content of 25 wt%. Through the multi-layer co-extrusion pipeline production equipment, double-layer co-extrusion of PE100 pellets and carbon fiber-reinforced PE100 pellets, cooling and shaping, to obtain carbon fiber-reinforced polyethylene composite double-layer pipes. The outer layer of the pipe is a carbon fiber reinforced polyethylene layer, the inner layer is a polyethylene l...

Embodiment 3

[0046] Preparation of carbon fiber reinforced polyethylene composite pipe with pipe diameter and pipe wall thickness ratio of 33: use cutting equipment to cut continuous carbon fiber (12KT300, Jihua Petrochemical) into chopped fibers with a length of 9mm, chopped carbon fibers and PE100 powder (Jilin Petrochemical) mixed in a ratio of 1:1 by weight, and then added 0.01wt% of antioxidant 1076 and 0.01wt% of antioxidant 618, after thorough mixing, they were granulated together through a twin-screw extruder, and the head of the extruder The temperature is 200° C. to obtain carbon fiber reinforced PE100 pellets, the fiber content of which is 50 wt%. The raw material uses the carbon fiber reinforced PE100 pellets and PE100 pellets used in Example 1, through the multi-layer co-extrusion pipeline production equipment, the PE100 pellets and the carbon fiber reinforced PE100 pellets are double-layered co-extruded, cooled and shaped, and carbon fiber reinforced Polyethylene composite do...

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Abstract

A manufacturing method of a fiber reinforced polyethylene composite double-layered tube comprises following steps: firstly, carbon fibers or glass fibers are cut into short fibers of 5 mm to 9 mm; secondly, the cut short fibers, polyethylene powder and an antioxygen are fully mixed to be extruded out for granulation through a double-screw extruder, and fiber reinforced polyethylene granules are obtained, wherein the polyethylene powder and the antioxygen are evenly mixed; and thirdly, a multi-layer co-extrusion technology is used, polyethylene and the fiber reinforced polyethylene granules in the step (2) are subject to double-layered extrusion, the double layers are combined through heat sealing, and after cooling, the fiber reinforced polyethylene composite double-layered tube is formed.

Description

technical field [0001] The invention provides a fiber-reinforced polyethylene composite double-layer pipe. Specifically, using a multi-layer co-extrusion process, polyethylene and short-cut fiber-reinforced polyethylene pellets are double-layer co-extruded to obtain a fiber-reinforced polyethylene composite double-layer pipe, and the outer layer of the pipe wall is chopped fiber-reinforced polyethylene Vinyl layer, the inner side of the pipe wall is a polyethylene layer. Background technique [0002] The usual polyethylene pipe material uses PE100. Under the condition of the maximum allowable pressure of 1MPa, the ratio (SDR) of the outer diameter of the pipe to the wall thickness of the pipe is specified as 11. At present, PE100 pipe is the polyethylene material with the highest practical specification. Due to the characteristics of shock resistance, flexibility and corrosion resistance of PE pipe, it is widely used in buried water pipes. The polyethylene material has exc...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B29C47/06C08L23/06C08K13/04C08K7/14C08K7/06B29L23/00
Inventor 张东杰陈光岩张海霞俆永田许济峰田月
Owner PETROCHINA CO LTD
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