Transparent laser marking sheet, laminate, and method for laser marking
A laser marking and transparent technology, applied in the direction of copying/marking methods, chemical instruments and methods, coatings, etc., can solve the problems of decreased reliability of identity certificates, obstacles to talent movement, etc., and achieves excellent transparency, high versatility, Good adhesion effect
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[0252] Hereinafter, although an Example demonstrates this invention more concretely, this invention is not limited to this. In addition, various evaluations and measurements in Examples and Comparative Examples were implemented by the following methods.
[0253] [1] Transparency of transparent laser marking sheet:
[0254] For the transparent laser marking sheets used in Examples 1 to 5 and Comparative Examples 1 to 6, the total light transmittance of the sheets was measured using a spectrophotometer (manufactured by Macbeth, trade name "EYE7000"). As evaluation, evaluation was performed based on the following criteria.
[0255] "Evaluation Criteria"
[0256] ⊚: The total light transmittance is 80% or more, and the total light transmittance is extremely good.
[0257] ◯: The total light transmittance is 60% or more and less than 80%, and the total light transmittance is good.
[0258] X: The total light transmittance is less than 60%, and the total light transmittance is p...
manufacture example 1
[0280] (Manufacturing Example 1) Substrate sheet A1 (single-layer sheet):
[0281] Use polycarbonate resin (manufactured by Idemitsu Kosan Co., Ltd., trade name "TARFLONFN2500A", melt volume ratio=8cm 3 / 10min) 100 parts by mass, 0.0015 parts by mass of carbon black (#10 manufactured by Mitsubishi Chemical Corporation, average particle diameter 75nm, DBP oil absorption 86ml / 100gr) as an energy absorber for absorbing laser light energy, and 0.0015 parts by mass as a phenolic antioxidant 0.1 parts by mass of n-octadecyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate (manufactured by Ciba Specialty Chemicals, trade name "IRGANOX1076") as an oxidizing agent and 2 -(2'-Hydroxy-3',5'-di-tert-butylphenyl)-5-chlorobenzotriazole (manufactured by Ciba Specialty Chemicals, trade name "Tinuvin327") 0.2 parts by mass, extruded through a T-die A single-layer substrate sheet A1 (single-layer sheet) having a thickness of 100 μm was obtained.
manufacture example 2
[0282] (Manufacturing Example 2) Substrate sheet A2 (multilayer sheet):
[0283] In non-crystalline polyester resin (manufactured by Eastman Chemical Co., trade name "EasterGN071", EG / CHDM (ethylene glycol unit / 1,4-cyclohexanedimethanol unit, the same below) = 70 / 30 mol% ) to 100 parts by mass of calcium stearate as a lubricant was blended as a surface layer of 0.1 parts by mass. Use polycarbonate resin (manufactured by Idemitsu Kosan Co., Ltd., trade name "TARFLONFN2500A", melt volume ratio=8cm 3 / 10min) 100 parts by mass, 0.0015 parts by mass of carbon black (#10 manufactured by Mitsubishi Chemical Corporation, average particle diameter 75nm, DBP oil absorption 86ml / 100gr) as an energy absorber for absorbing laser light energy, and 0.0015 parts by mass as a phenolic antioxidant 0.1 parts by mass of (n-octadecyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate (“IRGANOX1076” manufactured by Ciba Specialty Chemicals) of the oxidizing agent and 2-( 0.2 parts by mass of 2'-hyd...
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