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A treatment process for lead-containing wastewater

A technology for treating process and waste water, which is applied in water/sewage treatment, multi-stage water/sewage treatment, neutralized water/sewage treatment, etc. It can solve the problems of poor effect, large energy consumption, difficulty in compliance, etc., and achieve excellent results , The processing technology is simple, the production process is simple and easy to implement

Active Publication Date: 2019-03-26
ZHEJIANG OCEAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are also many deficiencies, such as electrolysis, although the effect of removing heavy metal lead ions is not bad, but in the process of treatment, especially in the treatment of a large amount of wastewater, a large amount of electric energy will be consumed, and its energy consumption is relatively large, which is difficult to meet the current requirements. The requirements for energy saving and emission reduction advocated; precipitation method, precipitation method can usually be divided into chemical precipitation and physical precipitation. Chemical precipitation is to add a large amount of alkali to the wastewater to make the wastewater alkaline, and then generate insoluble sediment. After filtration, the physical method is to add flocculant to the wastewater containing heavy metals. Most of the flocculants are colloids, which use a large number of similar charges on their surface to absorb heavy metal ions, and then settle by gravity and then remove them by filtration; ion exchange method and adsorption method, Although the operation is simple and the energy consumption is small, there is also the problem that the effect of a single method is not good.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] A treatment process for lead-containing waste water, comprising the following steps:

[0036] 1. Wastewater filtration;

[0037] 2. Adjust the pH value of the wastewater to 7;

[0038] 3. According to 45kg / m 3 Addition amount Add modified montmorillonite heavy metal adsorbent to wastewater, and aerate for 40 hours;

[0039] Four, filter and remove the modified montmorillonite heavy metal adsorbent after adsorbing heavy metal lead;

[0040] 5. The treated wastewater is discharged after passing the inspection.

[0041] Wherein, the modified montmorillonite heavy metal adsorbent is prepared by the following steps:

[0042] a) The montmorillonite dispersion is prepared according to the solid-liquid mass ratio of 1:4;

[0043] b) Add the hydroxyl aluminum ion solution to the montmorillonite dispersion prepared in step a, and after ultrasonic dispersion for 20 minutes, dry the solution to obtain intercalated modified montmorillonite; wherein the montmorillonite dispersio...

Embodiment 2

[0047] A treatment process for lead-containing waste water, comprising the following steps:

[0048] 1. Wastewater filtration;

[0049] 2. Adjust the pH value of the wastewater to 7;

[0050] 3. According to 45kg / m 3 Addition amount Add modified montmorillonite heavy metal adsorbent to wastewater, and aerate for 40 hours;

[0051] Four, filter and remove the modified montmorillonite heavy metal adsorbent after adsorbing heavy metal lead;

[0052] 5. Discharge the treated wastewater after passing the inspection;

[0053] 6. After the modified montmorillonite heavy metal adsorbent absorbs heavy metal lead, it can be recovered and used to treat lead-containing wastewater after ultrasonic treatment in 6mol / L sodium chloride solution for 1.5 hours.

[0054] Wherein, the modified montmorillonite heavy metal adsorbent is prepared by the following steps:

[0055] a) Purification of montmorillonite. After purification, the montmorillonite dispersion is prepared according to the soli...

Embodiment 3

[0060] A treatment process for lead-containing waste water, comprising the following steps:

[0061] 1. Wastewater filtration;

[0062] 2. Adjust the pH value of the wastewater to 6 by using 1mol / L acetic acid and 1mol / L potassium acetate;

[0063] 3. According to 40kg / m 3 Addition amount Add modified montmorillonite heavy metal adsorbent to wastewater, and aerate for 20 hours;

[0064] Four, filter and remove the modified montmorillonite heavy metal adsorbent after adsorbing heavy metal lead;

[0065] 5. Discharge the treated wastewater after passing the inspection;

[0066] 6. After the modified montmorillonite heavy metal adsorbent absorbs heavy metal lead, it can be recovered and used to treat lead-containing wastewater after ultrasonic treatment in 5mol / L sodium chloride solution for 0.5 hours.

[0067] Wherein, the modified montmorillonite heavy metal adsorbent is prepared by the following steps:

[0068] a) Purification of montmorillonite. After purification, the m...

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PUM

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Abstract

The invention discloses a treatment process of lead-containing wastewater. The treatment process comprises steps of wastewater filtration, adjustment of a pH value, adsorption by a modified montmorillonite heavy metal adsorbent, secondary filtration, inspection and emission of wastewater and the like. The treatment process of the wastewater containing heavy metal lead is simple and has a good effect, the treated wastewater can meet the emission standard, a preparation process of the adopted modified montmorillonite heavy metal adsorbent is simple and easy to implement, and the adopted modified montmorillonite heavy metal adsorbent can be reused through simple treatment after being used for treating the wastewater.

Description

technical field [0001] The invention relates to the technical field of wastewater treatment, in particular to a treatment process for lead-containing wastewater. Background technique [0002] Lead is often used as a raw material in manufacturing industries such as batteries, electroplating, pigments, rubber, pesticides, and fuels. The acid wastewater (pH = 3) discharged from the lead plate manufacturing process has the highest lead concentration, and the wastewater produced by electroplating waste liquid also has a high lead concentration. Lead is an element widely distributed in nature and one of the elements commonly used in industry. Both lead and soluble lead salts are toxic, and lead-containing wastewater is harmful to human health and animal and plant growth. If the daily intake of lead exceeds 0.3-1.0 mg, it can accumulate in the human body, causing anemia, neuritis, etc. With the rapid development of industrial technology, the heavy metal lead in industrial wastew...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/04B01J20/12C02F101/20
CPCB01J20/046B01J20/12C02F1/281C02F1/66C02F9/00C02F2101/20
Inventor 孙静亚高志伟张异凡
Owner ZHEJIANG OCEAN UNIV
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