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Wear-resistant cemented carbide and preparation method thereof

A cemented carbide and anti-corrosion technology, applied in the field of cemented carbide, can solve the problems such as the inability to balance wear resistance and toughness, and achieve the effect of improving comprehensive performance, strong corrosion resistance and improving impact resistance.

Inactive Publication Date: 2018-01-16
HUNAN CENTURY SPECIAL ALLOY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The invention provides an anti-corrosion cemented carbide and a preparation method thereof to solve the technical problem that the strength, corrosion resistance and toughness of the existing cemented carbide cannot be balanced

Method used

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Effect test

preparation example Construction

[0029] Another aspect of the present invention provides a method for preparing a corrosion-resistant cemented carbide, comprising the following steps:

[0030] Prepare raw materials according to the composition of the corrosion-resistant cemented carbide;

[0031] The tungsten carbide mixed powder and the nickel powder are mixed and batched, and sintered to obtain a wear-resistant hard alloy.

[0032] The preparation method of the corrosion-resistant cemented carbide can be prepared according to the conventional preparation method, such as the preparation method of the corrosion-resistant cemented carbide whose raw materials only contain tungsten carbide and nickel powder.

[0033] Optionally, the steps of wet grinding, drying with forming agent, granulation and compression molding are sequentially included between mixing ingredients and sintering.

[0034] Optionally, the ball milling medium for wet milling is acetone and n-hexane, the ratio of ball to material is 3.3:1, the...

Embodiment 1

[0039] A preparation method of an anti-corrosion cemented carbide, which comprises the following process steps: batching, wet grinding, drying mixed with a forming agent, granulation, compression molding and vacuum low-pressure integrated sintering.

[0040] The mixed powder of nickel powder and tungsten carbide is used for batching, and the mass ratio of nickel powder and tungsten carbide mixed powder is 5:95. In the tungsten carbide mixed powder, the tungsten carbide mixed powder is mixed with conventional tungsten carbide powder with Fsss particle size of 6.8 μm and cast tungsten carbide powder with Fsss particle size of 2.0 μm in a mass ratio of 50:50. The carbon content (total carbon) of conventional tungsten carbide powder is 6.12wt%, and the carbon content (total carbon) of cast tungsten carbide powder is 3.2wt%. The particle size of the nickel powder is 1.25 μm.

[0041] Wet milling is ball milling, the ball milling medium is acetone and n-hexane, the ratio of ball to...

Embodiment 2

[0044] A preparation method of an anti-corrosion cemented carbide, which comprises the following process steps: batching, wet grinding, drying mixed with a forming agent, granulation, compression molding and vacuum low-pressure integrated sintering.

[0045] The mixed powder of nickel powder and tungsten carbide is used for batching, and the mass ratio of nickel powder and tungsten carbide mixed powder is 8:92. In the tungsten carbide mixed powder, the tungsten carbide mixed powder is mixed with conventional tungsten carbide powder with Fsss particle size of 7.8 μm and cast tungsten carbide powder with Fsss particle size of 3.2 μm in a mass ratio of 70:30. The carbon content (total carbon) of conventional tungsten carbide powder is 6.15wt%, the carbon content (total carbon) of cast tungsten carbide powder is 4.5wt%; the particle size of nickel powder is 1.45μm.

[0046] Wet milling is ball milling, the ball milling medium during wet milling is acetone and n-hexane, the ratio o...

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Abstract

The invention discloses abrasion-resistant hard alloy and a preparation method thereof. The abrasion-resistant hard alloy is mainly formed by sintering, by weight percentage, 75-95% of tungsten carbide mixed powder and 5-25% of nickel powder. The tungsten carbide mixed powder comprises ordinary tungsten carbide powder and cast tungsten carbide powder. The ordinary tungsten carbide powder, the cast tungsten carbide powder and the nickel powder are sintered, so that the abrasion-resistant hard alloy is obtained. Nickel serves as binding metal and is high in corrosion resistance. Cast tungsten carbide and ordinary tungsten carbide are of different eutectic structures. Nickel, cast tungsten carbide and ordinary tungsten carbide are sintered together, so that strength of a binding phase is enhanced; the inter-crystal microstructure is improved; toughness and abrasion resistance of the alloy are improved; impact resistance of the alloy is remarkably improved; abrasion resistance, corrosion resistance and impact toughness of the prepared alloy are greatly improved; strength and microhardness can be coupled well; and thus comprehensive performance of the abrasion-resistant hard alloy is greatly improved.

Description

technical field [0001] The invention relates to the field of hard alloys, in particular to an anti-corrosion hard alloy. In addition, the present invention also relates to a preparation method comprising the above-mentioned corrosion-resistant cemented carbide. Background technique [0002] With the continuous development of the cemented carbide industry and the accelerated pace of deep-sea engineering, oil and gas exploration is developing in areas with more complex geological conditions and physical environments. Some high H 2 S and CO 2 Areas with high sulfur-containing geological environment have become the focus of oil and gas exploration, and the demand for high-strength materials in deep sea has increased sharply, and its failure life has attracted more and more attention. Corrosion research in drilling engineering at home and abroad mainly focuses on CO 2 、H 2 S and CO 2 / H 2 In terms of S corrosion and protection, anti-corrosion measures mainly include materia...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C29/08C22C1/05
CPCB22F2009/042B22F2009/043B22F2999/00C22C1/051C22C29/08B22F3/14B22F2201/20B22F2203/13
Inventor 肖华单水桃
Owner HUNAN CENTURY SPECIAL ALLOY