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Green and environment-friendly composite scale and corrosion inhibition chemical and preparation method thereof

A scale and corrosion inhibiting, green and environmentally friendly technology, applied in chemical instruments and methods, complex/solubilizing agent treatment, scale removal and water softening, etc., can solve the problems of increased cost of chemicals, water pollution, etc., and achieve low cost and easy Biodegradable, high tolerance effect

Inactive Publication Date: 2016-10-12
鞍钢栗田(鞍山)水处理有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Under the condition that the concentration of industrial circulating cooling water is more than 5 times, the use of existing water treatment chemicals can only increase the concentration, which will not only increase the cost of chemicals, but also cause greater water pollution. Under the current environmental pressure and economic situation, The development of a green and efficient scale and corrosion inhibitor is a new direction in this field

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  • Green and environment-friendly composite scale and corrosion inhibition chemical and preparation method thereof
  • Green and environment-friendly composite scale and corrosion inhibition chemical and preparation method thereof
  • Green and environment-friendly composite scale and corrosion inhibition chemical and preparation method thereof

Examples

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Effect test

Embodiment 1

[0031] Composite antiscaling and corrosion inhibitor, the weight of each component is as follows: 15 parts of polyamino polyether group methylene phosphonic acid, 20 parts of polyol phosphate, 12 parts of polyepoxy succinic acid, acrylic acid-acrylic acid ester-sulfonate 13 parts of copolymer, 6 parts of anhydrous zinc chloride, 5 parts of co-solvent, 29 parts of water. The preparation process is carried out according to the above-mentioned preparation method to obtain the composite anti-scaling and slow-release agent of the present invention.

[0032] The preparation method of the compound scale and corrosion inhibitor in this example is as follows:

[0033] 1) According to the above component distribution ratio, add polyamino polyether group methylene phosphonic acid, polyol phosphate and 1 / 2 water into the reaction kettle and mix, heat to 40°C, adjust the speed to 110r / min, and stir for 15min , to obtain solution A;

[0034] 2) Add polyepoxysuccinic acid, acrylic acid-acr...

Embodiment 2

[0038] In the composite scale and corrosion inhibitor of the present invention, the parts by weight of each component are as follows: 18 parts of polyaminopolyether-based methylene phosphonic acid, 22 parts of polyol phosphate, 8 parts of polyepoxysuccinic acid, acrylic acid-acrylic acid 15 parts of ester-sulfonate copolymer, 5 parts of anhydrous zinc chloride, 4 parts of co-solvent, 28 parts of water. The preparation process is carried out according to the above-mentioned preparation method to obtain the composite anti-scaling and slow-release agent of the present invention.

[0039] The preparation method of the compound scale and corrosion inhibitor in this example is as follows:

[0040] 1) According to the above component distribution ratio, add polyamino polyether group methylene phosphonic acid, polyol phosphate and 1 / 2 water into the reaction kettle and mix, heat to 40°C, adjust the speed to 120r / min, and stir for 20min , to obtain solution A;

[0041] 2) Add polyepo...

Embodiment 3

[0045] In the composite scale and corrosion inhibitor of the present invention, the parts by weight of each component are as follows: 12 parts of polyamino polyether group methylene phosphonic acid, 18 parts of polyol phosphate, 10 parts of polyepoxysuccinic acid, acrylic acid-acrylic acid 17 parts of ester-sulfonate copolymer, 6 parts of anhydrous zinc chloride, 5 parts of co-solvent, 32 parts of water. The preparation process is carried out according to the above-mentioned preparation method to obtain the composite anti-scaling and slow-release agent of the present invention.

[0046] 1) According to the above component distribution ratio, add polyaminopolyether group methylene phosphonic acid, polyol phosphate and 1 / 2 water into the reaction kettle and mix, heat to 40°C, adjust the speed to 110r / min, and stir for 20min , to obtain solution A;

[0047] 2) Add polyepoxysuccinic acid, acrylic acid-acrylic acid ester-sulfonate copolymer and remaining water into the reaction ke...

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Abstract

The invention relates to a green and environment-friendly compound scale and corrosion inhibitor agent and its preparation method. The composition and mass parts of the agent are as follows: polyamino polyether group methylene phosphonic acid: 10-20 parts, polyol phosphate : 15-25 parts, polyepoxysuccinic acid: 5-15 parts, acrylic acid-acrylate-sulfonate copolymer: 10-20 parts, anhydrous zinc chloride: 5-15 parts, co-solvent : 1-10 parts, water: 20-40 parts. The components of the composite antiscaling and corrosion inhibiting agent of the present invention have a good synergistic effect, so that the compounding agent has excellent scale and corrosion inhibiting properties. The calcium ion tolerance is high, and the scale inhibition rate can reach 98% according to the standard measurement. It is especially suitable for industrial circulating water with a water temperature of 50°C-60°C. It has excellent scale and corrosion inhibition performance when used in circulating cooling water systems with high concentration, high temperature, and high alkalinity.

Description

technical field [0001] The invention relates to a compound scale and corrosion inhibitor, in particular to a green and environment-friendly compound scale and corrosion inhibitor and a preparation method thereof. Background technique [0002] Industrial cooling water accounts for a considerable proportion of my country's industrial water. With the continuous growth of the economy, the contradiction between supply and demand of existing water resources has become more prominent. In order to save water and reduce energy consumption, it is necessary to continuously increase the concentration of circulating water. The Ministry of Science and Technology " During the Tenth Five-Year Plan period, it focused on supporting the project of "development and application demonstration of industrial circulating cooling water water-saving technology", and encouraged the concentration of industrial circulating cooling water to increase to more than 5 times, which played an important role in sa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F5/14C02F5/10C02F5/08C02F103/02
CPCC02F5/14C02F5/08C02F5/10C02F2103/023
Inventor 张柏鸿王坤鹏李俊峰王志成张冲褚运伟孙辉
Owner 鞍钢栗田(鞍山)水处理有限公司
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