Method for producing spray organic and inorganic composite fertilizer from middle-and-low-grade phosphate ore

A low-grade, compound fertilizer technology, applied in the direction of organic fertilizers, fertilizers made from biological wastes, applications, etc., can solve the problems of waste of resources, high consumption, low phosphoric acid content, etc., to save resources, reduce enterprise costs, and improve ratios The effect of surface area

Inactive Publication Date: 2016-10-26
纪新强
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in my country's traditional dihydrate method to produce phosphoric acid, it is necessary to use P 2 o 5 ≥30% high-grade ore, the extraction rate can reach more than 99%, P 2 o 5 ≤30% low-grade phosphate rock, because it contains more impurities, if it is directly extracted, the extraction rate is generally lower than 96%, and the extracted phosphoric acid content is low, resulting in waste of resources. Direct drying requires a lot of coal consumption, and The content of phosphoric acid is low, and the production of fertilizers is also limited; the medium and low-grade phosphate rock needs to be purified by flotation before it can be used
At present, there is no method to improve the extraction rate by directly extracting low- and medium-grade phosphate rocks

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Put the low-grade phosphate rock with a content of 25.4% into the crusher for coarse crushing first, and the coarsely crushed phosphate rock will directly enter the ball mill. At the same time, add water and dispersant to the ball mill to grind the phosphate rock into pulp. Pour into the extraction tank and use sulfuric acid to extract phosphoric acid to obtain phosphoric acid. The obtained phosphoric acid and potassium bisulfate produced by low-temperature conversion method are pumped into the tubular reactor and neutralized with liquid ammonia to obtain neutralized slurry. Fermented chicken manure is added to the neutralized slurry, and the mass ratio of the neutralized slurry to fermented chicken manure is 80:20 to obtain the slurry. After the slurry is sprayed and granulated, dried, screened and packaged, it can be used Shotcrete organic-inorganic compound fertilizer produced from low-grade phosphate rock;

[0027] The mass ratio of phosphate rock, water, hydrolyzed...

Embodiment 2

[0030] Put the low-grade phosphate rock with a content of 25.4% into the crusher for coarse crushing first, and the coarsely crushed phosphate rock will directly enter the ball mill. At the same time, add water and dispersant to the ball mill to grind the phosphate rock into pulp. Pour into the extraction tank and use sulfuric acid to extract phosphoric acid to obtain phosphoric acid. The obtained phosphoric acid and potassium bisulfate produced by low-temperature conversion method are pumped into the tubular reactor and neutralized with liquid ammonia to obtain neutralized slurry. Mushroom slag is added to the neutralization slurry, and the mass ratio of the neutralization slurry to the mushroom slag is 80:20 to obtain the slurry. After the slurry is sprayed and granulated, dried, screened and packaged, the low-grade Shotcrete organic-inorganic compound fertilizer produced from phosphate rock;

[0031] The mass ratio of phosphate rock, water, hydrolyzed polymaleic anhydride, ...

Embodiment 3

[0034] Put the low-grade phosphate rock with a content of 25.4% into the crusher for coarse crushing first, and the coarsely crushed phosphate rock will directly enter the ball mill. At the same time, add water and dispersant to the ball mill to grind the phosphate rock into pulp. Pour into the extraction tank and use sulfuric acid to extract phosphoric acid to obtain phosphoric acid. The obtained phosphoric acid and potassium bisulfate produced by low-temperature conversion method are pumped into the tubular reactor and neutralized with liquid ammonia to obtain neutralized slurry. Furfural slag is added to the neutralization slurry, and the mass ratio of the neutralization slurry to furfural slag is 75:25 to obtain a slurry. Shotcrete organic-inorganic compound fertilizer produced from phosphate rock;

[0035] The mass ratio of phosphate rock, water, hydrolyzed polymaleic anhydride, sodium polyacrylate and sulfuric acid is: 40:17:0.4:0.6:42.

[0036] The extraction rate of p...

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Abstract

The invention relates to a method for producing spray organic and inorganic composite fertilizer from middle-and-low-grade phosphate ore. The middle-and-low-grade phosphate ore is added to a crusher for coarse crushing firstly, the coarsely crushed middle-and-low-grade phosphate ore enters a ball mill, meanwhile, water and a dispersing agent are added to the ball mill, the middle-and-low-grade phosphate ore is ball-milled to form ore pulp, the ore pulp is pumped into an extraction tank for extraction, phosphoric acid is prepared, and the extraction rate of the phosphate ore is detected; phosphoric acid and potassium hydrogen sulfate produced with a low-temperature transformation method are pumped into a tubular reactor by a pump to be neutralized with liquid ammonia, neutral slurry is obtained, an organic raw material is added to the neutral slurry and evenly stirred, slurry is obtained and subjected to spraying granulation, drying, screening and packaging, and the spray organic and inorganic composite fertilizer produced from the middle-and-low-grade phosphate ore is obtained. According to the method, the dispersing agent is added, so that the extraction rate of the phosphate ore is effectively increased, the extraction time is saved, and the production efficiency of the composite fertilizer is improved.

Description

technical field [0001] The invention relates to a method for producing sprayed organic-inorganic compound fertilizer by using medium and low-grade phosphate rock. Background technique [0002] my country's phosphate rock reserves are large, ranking second in the world. It is characterized by less rich ore and more low-grade ore. However, in recent years, due to the increase in the output of high-concentration compound fertilizers, the phosphate rock with a content of more than 30% has become increasingly tense. However, in my country's traditional dihydrate method to produce phosphoric acid, it is necessary to use P 2 o 5 ≥30% high-grade ore, the extraction rate can reach more than 99%, P 2 o 5 ≤30% low-grade phosphate rock, because it contains more impurities, if it is directly extracted, the extraction rate is generally lower than 96%, and the extracted phosphoric acid content is low, resulting in waste of resources. Direct drying requires a lot of coal consumption, an...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C05G3/00C05G3/04C05G3/80
CPCC05F3/00C05G3/00C05G3/80C05F5/002C05F5/006C05F11/00C05F11/02C05B11/08
Inventor 纪新强
Owner 纪新强
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