Preparation of extreme pressure anti-wear agent and vehicle gear oil containing extreme pressure anti-wear agent

A technology of extreme pressure antiwear agent and gear oil, which is applied in additives, petroleum industry, organic chemistry, etc. It can solve the problems of poor multifunctionality, anti-oxidation, anti-cleaning performance and weak repair function, and achieve good wear resistance, Effect of lower friction coefficient, good load carrying capacity and extreme pressure resistance

Inactive Publication Date: 2016-10-26
SHANDONG YUANGEN PETROLEUM CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Due to the above-mentioned environmental protection problems of traditional extreme pressure antiwear agents, poor multifunctionality, anti-oxidation, anti-cleaning properties and weak repair functions, people have paid more attention to rare earths and their compounds in recent years.

Method used

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  • Preparation of extreme pressure anti-wear agent and vehicle gear oil containing extreme pressure anti-wear agent

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] This embodiment provides a preparation method of an extreme pressure antiwear agent, and a vehicle gear oil containing the extreme pressure antiwear agent.

[0030] A preparation method of an extreme pressure antiwear agent, specifically comprising the following steps:

[0031] a, add the borax of 115mg in the 80mg lanthanum nitrate solution and react, and the reaction time is 2h;

[0032] B, then add 89mg of n-butanol to the lanthanum nitrate solution to carry out esterification reaction, the reaction time is 3h;

[0033] c. After the esterification reaction is finished, add an appropriate amount of 100mg dodecyl alcohol-modified graphene oxide to carry out a transesterification reaction to obtain a preliminary reaction solution;

[0034] d. Distilling the preliminary reaction solution to remove impurities to obtain graphene modified by lanthanum dodecyloxyborate, which is the extreme pressure antiwear agent;

[0035] A vehicle gear oil prepared by using an extreme p...

Embodiment 2

[0037] This embodiment provides a preparation method of an extreme pressure antiwear agent, and a vehicle gear oil containing the extreme pressure antiwear agent.

[0038] A preparation method of an extreme pressure antiwear agent, specifically comprising the following steps:

[0039] a, add the borax of 116mg in 90mg lanthanum nitrate solution and react, and the reaction time is 3h;

[0040] B, then add 89mg of n-butanol to the lanthanum nitrate solution to carry out esterification reaction, the reaction time is 5h;

[0041] c. After the esterification reaction is finished, add an appropriate amount of 104 mg dodecyl alcohol-modified graphene oxide to carry out a transesterification reaction to obtain a preliminary reaction solution;

[0042] d. Distilling the preliminary reaction solution to remove impurities to obtain graphene modified by lanthanum dodecyloxyborate, which is the extreme pressure antiwear agent;

[0043] A vehicle gear oil prepared by using an extreme pres...

Embodiment 3

[0045] This embodiment provides a preparation method of an extreme pressure antiwear agent, and a vehicle gear oil containing the extreme pressure antiwear agent.

[0046] A preparation method of an extreme pressure antiwear agent, specifically comprising the following steps:

[0047] a, add the borax of 114mg in the 88mg lanthanum nitrate solution and react, and the reaction time is 4h;

[0048] B, then add 86mg of n-butanol to the lanthanum nitrate solution to carry out esterification reaction, the reaction time is 6h;

[0049]c. After the esterification reaction is finished, add an appropriate amount of 98mg dodecyl alcohol-modified graphene oxide to carry out a transesterification reaction to obtain a preliminary reaction solution;

[0050] d. Distilling the preliminary reaction solution to remove impurities to obtain graphene modified by lanthanum dodecyloxyborate, which is the extreme pressure antiwear agent;

[0051] A vehicle gear oil prepared by using an extreme pre...

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Abstract

The invention belongs to the field of vehicle gear lubricant, and relates to preparation of an extreme pressure anti-wear agent and vehicle gear oil containing the extreme pressure anti-wear agent. The preparation of the extreme pressure anti-wear agent comprises steps as follows: a certain amount of borax is added to a lanthanum nitrate solution and subjected to a reaction for a few hours; then a certain amount of n-butyl alcohol is added to a reaction liquid and subjected to esterification for a few hours; after the reaction, an appropriate amount of lauryl alcohol modified graphene oxide is added and subjected to transesterification, impurities of a reaction product are removed through distillation, and the extreme pressure anti-wear agent is obtained. The vehicle gear oil containing the extreme pressure anti-wear agent comprises components as follows: base oil, the extreme pressure anti-wear agent, ammonium thiophosphate, sulfurized isobutylene, a clearing agent, a dispersing agent, a pour point depressant and a deforming agent. According to the preparation of the extreme pressure anti-wear agent and the vehicle gear oil containing the extreme pressure anti-wear agent, the friction coefficient of the surface of a friction pair is reduced, a rare earth element and a boron element are diffused from the friction surface to a substrate in a friction process so as to form a permeable layer, the wear resistance of a material surface is improved, an extreme pressure anti-wear effect is realized, and properties of good wear resistance, rust resistance, corrosion resistance and the like are achieved.

Description

technical field [0001] The invention belongs to the field of vehicle gear lubricating oil, and in particular relates to the preparation of an extreme pressure antiwear agent and vehicle gear oil containing the extreme pressure antiwear agent. Background technique [0002] The development of the automobile industry has promoted the upgrading of vehicle gear oil, and the increase in truck load has increased the power of drive axle gear transmission, while the geometric dimensions of drive axle gears have not changed much, resulting in increased tooth surface pressure and temperature. After the Second World War, in order to obtain a multi-effect gear oil with both high-speed performance and high-torque performance, phosphorus-containing extreme pressure agents were introduced, and S-P-Cl type multi-effect gear oil was developed. The U.S. military formulated the MIL- L-2105A specification, the extreme pressure agent introduced zinc dialkyldithiophosphate on the original basis, w...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07F5/05C10M139/00C10M169/04C10N30/06C10N30/12C10N40/04
CPCC07F5/05C10M139/00C10M169/048C10M2201/085C10M2219/082C10M2227/062C10N2010/06C10N2030/06C10N2030/12C10N2040/04
Inventor 何茂伟袁俊洲徐金玲乔良
Owner SHANDONG YUANGEN PETROLEUM CHEM
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