Selenium-containing rubber material for tire and preparation method of material
A technology for rubber materials and tires, applied in the field of selenium-containing rubber materials for tires and their preparation, can solve problems such as irreparable losses, and achieve the effect of good thermal stability
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Embodiment 1
[0033] (1) In parts by mass, weigh raw materials: 100 parts of natural rubber NR, 3 parts of crosslinking agent, 1 part of accelerator CZ (N-cyclohexyl-2-benzothiazyl sulfenamide), 5 parts of active zinc oxide , 1 part of antioxidant 4010 (N-cyclohexyl-N'-phenyl-p-phenylenediamine), 30 parts of white carbon black, 10 parts of liquid coumarone, 1 part of titanate; the crosslinking agent is sulfur powder (95% by mass content of sulfur) and selenium powder (95% by mass content of selenium, directly purchased in the market, 100 orders) are mixed in a mass ratio of 1:0.25;
[0034] (2) Mixing: Add the materials weighed in step (1) into the internal mixer in order for mixing, the roller temperature is 50°C, and the feeding sequence is as follows: figure 1 As shown, the details are: natural rubber, active zinc oxide, accelerator CZ, anti-aging agent 4010, white carbon black, liquid coumarone, titanate, selenium powder, sulfur powder, thin through-out sheet, packed in a triangular bag...
Embodiment 2
[0036] (1) In parts by mass, weigh raw materials: 100 parts of natural rubber NR, 2 parts of crosslinking agent, 1 part of accelerator CZ (N-cyclohexyl-2-benzothiazyl sulfenamide), 5 parts of active zinc oxide , 1.5 parts of antioxidant 4010 (N-cyclohexyl-N'-phenyl-p-phenylenediamine), 35 parts of white carbon black, 8 parts of liquid coumarone; the cross-linking agent is sulfur powder (sulfur mass content 95% ) and selenium powder (selenium mass content 95%, direct purchase in the market, 100 orders) is mixed in a mass ratio of 1:1;
[0037] (2) Mixing: Add the materials weighed in step (1) into the internal mixer in order for mixing, the roller temperature is 50°C, and the order of addition is: natural rubber, active zinc oxide, accelerator CZ, anti-aging agent 4010, white Carbon black, liquid coumarone, selenium powder, sulfur powder, thin slices, packed into triangular bags, and sliced to obtain selenium-containing rubber materials.
Embodiment 3
[0039] The difference between this example and Example 1 is that the crosslinking agent does not contain sulfur powder, all of it is selenium powder, and the prepared selenium-containing rubber material is recorded as Se (selenium powder). The heat aging performance test is shown in Table 1.
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