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A kind of preparation method of composite electrolytic plate

An electrolytic plate and preparation step technology, applied in the direction of electrolytic paint, coating, metal material coating process, etc., can solve the problems of poor corrosion resistance and stamping performance, insufficient hardness of electrolytic plate, poor coating adhesion, etc. The effect of strong coating adhesion, excellent deep drawing performance and excellent corrosion resistance

Active Publication Date: 2018-05-15
江苏鑫冶金属板业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The technical problem mainly solved by the present invention: Aiming at the problems of poor coating adhesion, poor corrosion resistance and stamping processing performance, and insufficient hardness of the electrolytic plate in the electrolytic plate prepared by the prior art, a method for preparing a composite electrolytic plate is provided. Method Soak the cold-rolled steel sheet in acetone solution and dry it, then soak it in a mixture of sodium pyrophosphate, sodium chloride and water for heat treatment, then take out the surface-treated cold-rolled steel sheet, wash the surface with distilled water to neutral After that, soak in the impregnating solution made of salicylate, ammonium bifluoride, etc. to obtain a composite electrolytic plate substrate, and then stir, adjust pH, and oscillate zinc chloride, nickel chloride, and graphite. The obtained electroplating solution is put into the electroplating tank, the composite electrolytic plate substrate is put into the electroplating tank for electroplating treatment, and then dried to obtain the composite electrolytic plate. The composite electrolytic plate prepared by the present invention has high hardness and excellent Stamping processing performance solves the technical problem of difficult assembly after punching the electrolytic plate, and meets the requirements of various complex deep drawing deformation and assembly. The prepared electrolytic plate coating has strong adhesion and excellent corrosion resistance, and has a broad application market

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0020] First, soak the cold-rolled steel sheet in acetone solution and let it stand for 10 minutes, then take out the cold-rolled sheet steel, wipe the surface clean, then soak it in the mixed solution, heat it to 55°C, keep it warm for 1 hour, cool it naturally to room temperature, take it out Surface treatment of cold-rolled steel sheets, using distilled water to wash the surface of the surface-treated cold-rolled steel sheets to neutrality, the mixed solution is formed by mixing sodium pyrophosphate, sodium chloride and water in a mass ratio of 1:1:3; then In parts by weight, take 20 parts of disalicylate, 34 parts of distilled water, 6 parts of ammonium bifluoride, 1 part of dodecyl mercaptan and 19 parts of absolute ethanol, and stir evenly to obtain an impregnating solution. The cold-rolled thin steel plate is soaked in the impregnating solution at a solid-to-liquid ratio of 1:4. After standing at room temperature for 1 minute, take out the surface-treated cold-rolled thi...

example 2

[0023] First, soak the cold-rolled steel sheet in the acetone solution and let it stand for 13 minutes, then take out the cold-rolled steel sheet, wipe the surface clean, then soak it in the mixed solution, heat it to 58°C, keep it warm for 1.5h, and cool it down to room temperature naturally. Take out the surface-treated cold-rolled steel sheet, wash the surface of the surface-treated cold-rolled steel sheet with distilled water to neutrality, and the mixed solution is formed by mixing sodium pyrophosphate, sodium chloride and water in a mass ratio of 1:1:3; Then, in parts by weight, take 23 parts of disalicylate, 36 parts of distilled water, 8 parts of ammonium bifluoride, 1.5 parts of dodecyl mercaptan and 20 parts of absolute ethanol, and stir evenly to obtain an impregnation solution. Treat the cold-rolled thin steel plate with a solid-to-liquid ratio of 1:4, soak it in the impregnating solution, let it stand at room temperature for 2 minutes, take out the surface-treated ...

example 3

[0026]First, soak the cold-rolled steel sheet in acetone solution and let it stand for 15 minutes, then take out the cold-rolled sheet steel, wipe the surface clean, then soak it in the mixed solution, heat it to 60°C, keep it warm for 2 hours, cool it naturally to room temperature, take it out Surface treatment of cold-rolled steel sheets, using distilled water to wash the surface of the surface-treated cold-rolled steel sheets to neutrality, the mixed solution is formed by mixing sodium pyrophosphate, sodium chloride and water in a mass ratio of 1:1:3; then In parts by weight, take 25 parts of disalicylate, 38 parts of distilled water, 9 parts of ammonium bifluoride, 2 parts of dodecyl mercaptan and 21 parts of absolute ethanol, and stir evenly to obtain an impregnating solution. The cold-rolled thin steel plate is soaked in the impregnating solution according to the solid-liquid ratio of 1:4, and after standing at room temperature for 3 minutes, the surface-treated cold-roll...

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Abstract

The invention discloses a manufacturing method for a composite electrolytic plate and belongs to the technical field of manufacturing of electrolytic plates. According to the manufacturing method, a cold rolled steel sheet is soaked with an acetone solution and then is wiped and dried, then the cold rolled steel sheet is soaked in a mixed solution prepared through sodium pyrophosphate, sodium chloride and water, then the cold rolled steel sheet is taken out to be subjected to surface treatment, the surface is washed to be neutral, then the cold rolled steel sheet is put into an impregnating solution prepared through salicylylsalicylic acid, ammonium bifluoride and the like to be soaked, a composite electrolytic plate base material is prepared, zinc chloride, nickel chloride, graphite and the like are subjected to stirring, pH adjustment and oscillating treatment, the obtained electroplating liquid is put into an electroplating bath, the composite electrolytic plate base material is put into the electroplating bath to be subjected to electroplating treatment and then dried, and the composite electrolytic plate is obtained. The manufactured composite electrolytic plate is high in hardness, excellent in stamping machining performance, capable of meeting the requirements of various complex deep-punching deformation and assembly, high in clad layer adhesive force and excellent in corrosion resistance and has the wide application market.

Description

technical field [0001] The invention discloses a method for preparing a composite electrolytic plate, which belongs to the technical field of electrolytic plate preparation. Background technique [0002] Electrolytic plate, also known as electro-galvanized plate, is the process of forming a uniform, dense and well-bonded metal or alloy deposition layer on the surface of the workpiece by electrolysis. [0003] Compared with other metals, zinc is a relatively cheap and easy-to-coat metal, which is a low-value anti-corrosion electroplating layer. It is widely used to protect steel parts, especially against atmospheric corrosion, and for decoration. Plating techniques include tank plating (or rack plating), barrel plating (suitable for small parts), automatic plating and continuous plating (suitable for wire and strip). [0004] The electrolytic plate is rolled by the cold tandem rolling unit and then annealed by the CAPL unit, and then enters the electro-galvanizing unit. Aft...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C25D3/22C25D15/00C25D5/36C23C22/68
CPCC23C22/68C25D3/22C25D5/36C25D15/00
Inventor 张文峰
Owner 江苏鑫冶金属板业有限公司
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