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Aluminum-based metal glass cladding layer and preparation method thereof

A technology of aluminum-based metallic glass and cladding layer, applied in metal processing equipment, metal material coating technology, coating and other directions, can solve the problem of difficulty in preparing high-performance amorphous aluminum alloy materials, limited amorphous forming ability, The problem of high critical cooling rate can improve the internal defects of the molten pool, improve the ability of amorphous formation, and reduce the temperature gradient.

Inactive Publication Date: 2016-11-23
ACADEMY OF ARMORED FORCES ENG PLA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, due to the high critical cooling rate of ordinary amorphous materials (about 10 6 K / s), so most of them can only prepare strips or powder samples with a thickness on the order of microns, which greatly limits its application range
[0003] Compared with alloys with strong glass-forming ability such as iron-based and nickel-based, aluminum-based metallic glasses have limited amorphous-forming ability and belong to the marginal metallic glass system, so it is difficult to prepare high-performance amorphous aluminum alloy materials
There are few studies at home and abroad on this

Method used

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  • Aluminum-based metal glass cladding layer and preparation method thereof
  • Aluminum-based metal glass cladding layer and preparation method thereof
  • Aluminum-based metal glass cladding layer and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1)

[0039] The element composition of the aluminum-based amorphous alloy powder used in the aluminum-based metallic glass cladding layer of this embodiment is as follows: 6wt% Ni, 4.5wt% Y, 2wt% Co, 1.5wt% La, and the rest is Al; That is Al 86 Ni 6 Y 4.5 co 2 La 1.5 .

[0040] The particle size range of the aluminum-based amorphous alloy powder is 25-71 μm, and the oxygen content is less than 1000 ppm.

[0041] A Quanta 200 environmental scanning electron microscope (SEM) equipped with an energy spectrum (EDS) accessory was used to observe the structure and morphology of the aluminum-based amorphous alloy powder. The SEM photo is shown in figure 1 .

[0042] Depend on figure 1 It can be seen that the aluminum-based amorphous alloy powder is spherical and has good fluidity, and a small amount of satellite balls are bonded to the surface of some large particles, which helps to increase the packing density of the powder and is suitable for the automatic powder-feeding cladding...

Embodiment 2~ Embodiment 3)

[0089]Each example is basically the same as Example 1, except that the elemental composition of the aluminum-based amorphous alloy powder is shown in Table 2 for details.

[0090]

Embodiment 4~ Embodiment 5)

[0092] Each embodiment is basically the same as embodiment 1, except that the specific process parameters of magnetic field agitation laser cladding forming are shown in Table 3.

[0093]

[0094] According to the methods of Test Examples 1, 3, 4, and 6, the relative properties of the cladding layers prepared in Comparative Example 2 and Examples 2 to 5 were tested, and the results are shown in Tables 1 to 3, respectively.

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Abstract

The invention discloses an aluminum-based metal glass cladding layer and a preparation method thereof. The aluminum-based metal glass cladding layer is prepared from aluminum-based amorphous alloy powder serving as a raw material through a magnetic field stirring laser cladding forming technique. The element composition of the aluminum-based amorphous alloy powder is as follows: 5 wt%-8 wt% of Ni, 3 wt%-6 wt% of Y, 1 wt%-5 wt% of Co, 0.5 wt%-3 wt% of La and the balance Al; the particle size range of the aluminum-based amorphous alloy powder ranges from 25 micrometers to 71 micrometers; and the oxygen content of the aluminum-based amorphous alloy powder is below 1,000 ppm. The adopted aluminum-based amorphous alloy powder is high in degree of sphericility, good in fluidity and proper in particle size, and the added alloy components have the characteristics of being high in amorphous forming ability and stable in structure; and the amorphous phase content of the aluminum-based metal glass cladding layer prepared in the manner that the alloy powder is combined with the magnetic field stirring laser cladding forming technique reaches up to 30% or above, and meanwhile the aluminum-based metal glass cladding layer further has excellent mechanical performance and abrasion-resistant and corrosion-resistant performance.

Description

technical field [0001] The invention belongs to the technical field of cladding and forming, and in particular relates to an aluminum-based metallic glass cladding layer and a preparation method thereof. Background technique [0002] Compared with traditional crystalline materials, metallic glasses have many excellent properties, such as high strength, high hardness, large elastic strain limit, high corrosion resistance, and excellent magnetic properties. Moreover, due to its unique organizational structure, efficient preparation process, good material properties and broad application prospects, it is currently attracting attention in materials science and industry. However, due to the high critical cooling rate of ordinary amorphous materials (about 10 6 K / s), so most of them can only prepare strips or powder samples with a thickness on the order of microns, which greatly limits its application range. [0003] Compared with alloys with strong glass-forming ability such as...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C24/10C22C45/08B22F1/052B22F1/08
CPCC22C45/08C23C24/106B22F1/08B22F1/052B23K2103/10C22C1/0416C22C2200/02B23K26/34B23K35/286C22C21/00
Inventor 王晓明朱胜张垚杨柏俊韩国峰王启伟任智强陈永星周超极
Owner ACADEMY OF ARMORED FORCES ENG PLA
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