A kind of catalytic cracking catalyst and its preparation method and application
A catalytic cracking and catalyst technology, used in catalytic cracking, physical/chemical process catalysts, molecular sieve catalysts, etc., can solve problems such as disadvantages, and achieve the effect of improving selectivity, high catalytic cracking activity, and ensuring gasoline yield
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[0018] According to the catalytic cracking catalyst provided by the present invention, there is no special requirement for the ultra-stable IM-5 molecular sieve, which can be prepared by referring to conventional technical methods. However, in a preferred embodiment of the present invention, the preparation method of the ultra-stable IM-5 molecular sieve comprises: exchanging the IM-5 molecular sieve with an ammonium salt solution until the Na content in the molecular sieve is lower than 0.3% by weight So far, and then calcined in a water vapor atmosphere to obtain the ultra-stable IM-5 molecular sieve.
[0019] More preferably, the preparation method of the above-mentioned super stable IM-5 molecular sieve comprises:
[0020] A1. Exchange the IM-5 molecular sieve with the ammonium salt solution until 75% to 90% by weight of Na in the molecular sieve is removed. ℃ calcination (preferably calcination 2.5-4.5h), to obtain cross-calcination IM-5 molecular sieve;
[0021] A2. Th...
Embodiment 1
[0052] This example is used to illustrate the catalytic cracking catalyst provided by the present invention and its preparation method.
[0053] (1) The preparation method of ultra-stabilized IM-5 molecular sieve comprises the following steps:
[0054] A1. Mix IM-5 molecular sieve and deionized water at a weight ratio of 1:10 to form a water slurry of IM-5 molecular sieve. The water slurry is mixed with an aqueous solution of ammonium chloride, and exchanged at a temperature of 40°C until 90% by weight of Na in the molecular sieve is removed (the exchange step can be divided into several times, and the solution is stirred for 60 minutes each time to obtain a suspension and carry out suction filtration , after the filter cake is dried, measure the Na content in the molecular sieve by X-ray fluorescence method, if the Na content does not meet the requirements, repeat the previous steps), wash with deionized water to remove residual salt, and bake at 800 ° C for 2.5 h under 100% ...
Embodiment 2
[0063] This example is used to illustrate the catalytic cracking catalyst provided by the present invention and its preparation method.
[0064] (1) The preparation method of the ultra-stabilized IM-5 molecular sieve: with reference to the step (1) of Example 1;
[0065] (2) The preparation method of the ultra-stabilized USY molecular sieve: refer to the step (2) of Example 1;
[0066] (3) The preparation method of catalytic cracking catalyst: with reference to the step (3) of embodiment 1, difference is: after obtaining fresh catalyst, do not carry out hydrothermal aging treatment, the obtained catalyst is denoted as S2.
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