Low-cost packaging bonding silver alloy wire and preparation method thereof

A silver alloy, low-cost technology, used in semiconductor/solid-state device manufacturing, electrical components, circuits, etc., can solve the problems of coating stability and environmental protection requirements restricting materials, high manufacturing costs, and improve LED luminous attenuation efficiency and easy operation. , The effect of superior welding performance

Active Publication Date: 2017-01-04
江苏天康电子合成材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The gold content in the currently developed silver alloy bonding wire reaches 20-55%, such as the CN102776405A patent, whose gold content reaches 20-30%, and the CN104388861A patent, whose gold content reaches 35-55%, and other trace elements are also added in these materials. relatively high cost
There are also inventions that use electroplating to plate gold on the surface of pure silver wire to improve material performance, but the stability of the coating and environmental protection requirements restrict the use and development of materials.

Method used

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  • Low-cost packaging bonding silver alloy wire and preparation method thereof
  • Low-cost packaging bonding silver alloy wire and preparation method thereof
  • Low-cost packaging bonding silver alloy wire and preparation method thereof

Examples

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Embodiment 1

[0045] The present invention relates to a bonding silver alloy wire for low-cost and high-stability packaging and a preparation method thereof, wherein the composition of the bonding silver alloy wire is: Au<1%, Pd 1000-10000ppm, Pb10-200ppm, Mg 5ppm, and the rest are Ag.

[0046] The preparation method comprises the following steps: 1. material preparation; 2. preparation of master alloy; 3. vacuum melting and drawing casting; 4. rough drawing; 5. intermediate annealing;

[0047] 1. Prepare materials. Weigh a number of 99.99% silver ingots, 500g of gold with a purity of not less than 99.99%, 2kg of industrial pure palladium flakes, 500g of pure magnesium pellets, and 500g of lead pellets.

[0048] 2. Preparation of master alloy.

[0049] aPut 1.5kg of palladium flakes into the crucible, heat the temperature to 1600 degrees under vacuum, after the palladium flakes are completely melted, put 1kg of silver ingots into the molten palladium liquid, stop heating when all the silv...

Embodiment 2

[0060] Vacuum melting and drawing casting. Put 4930g of silver ingot into a vacuum furnace and heat it to about 1000 degrees to melt, then add 50g of silver-palladium master alloy described in Example 1, 0.5g of silver-magnesium master alloy, 20g of gold grains, and 0.05g of lead grains in sequence under a protective atmosphere. Stir under vacuum, continue to stir for 10 minutes after all melting, and then carry out drawing casting into 8mm diameter alloy rod.

[0061] 2), rough drawing. The alloy rod was drawn to 3.0 mm by multiple drawing.

[0062] 3), intermediate annealing. The 3.0mm wire is annealed in a protective atmosphere, the annealing temperature is controlled at 400-450 degrees, and the line speed is controlled at about 500mm / min.

[0063] 4), medium selah. The annealed wire rod is drawn to 0.025mm through multiple passes.

[0064] 5), stabilization annealing. The 0.025mm microwire is stabilized by annealing, the annealing temperature is controlled at 400-450...

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Abstract

The invention relates to a low-cost packaging bonding silver alloy wire and a preparation method thereof and belongs to the technical field of bonding wire processing. The silver alloy wire is composed of the following metal materials by weight ratio (wt%): less than 1% of Au, 1000-10000ppm of Pd, 10-200ppm of Pb, 5ppm of Mg and the balance of Ag. The method comprises the following steps: preparing materials; preparing intermediate alloy; performing vacuum melting and pull casting; making an alloy bar into a 2 to 4mm alloy bus by using a coarse drawing machine unit; performing intermediate on-line annealing on the alloy bus; drawing the alloy bus subjected to the intermediate on-line annealing into micro filaments with diameters of 0.015-0.030mm by a continuous drawing machine unit; and performing stabilized on-line annealing on the micro filaments to make silver alloy wires. The method adopts a principle of physical chemistry in metallurgy to design a simple and easy alloying component, greatly improves the content of palladium, adds the intermediate alloy to the liquid silver to significantly improve the oxidation resistance of the silver alloy, The different amount of magnesium is added by the method of the intermediate alloy to adjust the strong plasticity of the alloy wire, and a trace of Pb elements are added to enhance ball stability.

Description

technical field [0001] The invention relates to a low-cost packaging and bonding silver alloy wire and a preparation method thereof, belonging to the technical field of bonding wire processing technology. Background technique [0002] There are many kinds of microwires for bonding, such as gold wire, silver wire, copper wire, palladium-plated copper wire, silver-plated gold, etc., but the overall performance is still better than gold wire, especially for many years, various bonding equipment is also suitable for gold wire. The stability of the gold wire is also recognized. Although the cost of newly developed single crystal copper wire has been greatly reduced compared with gold wire in recent years, it is difficult to popularize and apply it at present due to the strong toughness of copper wire, especially its poor oxidation resistance. Palladium-plated copper wire, silver-plated gold, etc. have solved the oxidation problem of the bonding wire, but the electroplating cause...

Claims

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Application Information

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IPC IPC(8): H01L23/49H01L21/48C22C5/06C22F1/14
CPCC22C5/06C22F1/14H01L24/43H01L24/45H01L2224/45139H01L2224/45144H01L2224/43H01L2224/43848H01L2924/12041H01L2924/01047H01L2924/00H01L2924/00015H01L2924/013H01L2224/45344H01L2224/45147H01L2224/45H01L2224/45565H01L2224/45664H01L2924/00011H01L2924/01079H01L2924/01082H01L2924/01012H01L2924/01046H01L2924/00012H01L2924/00014H01L2924/01049H01L2924/01005
Inventor 李康李松林李扣民曹鹏谭佃龙余新泉
Owner 江苏天康电子合成材料有限公司
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