Biodiesel hydrodeoxygenation process

Abstract

The invention discloses a biodiesel hydrodeoxygenation process. The biodiesel hydrodeoxygenation process is characterized in that a fixed bed reactor is adopted in the process, the fixed bed reactor is filled with a hydrodeoxygenation catalyst, and the catalyst comprises a carrier and an active component; the carrier is KIT-1 formed by doping heteroatom Cu2+ in a synthetic framework structure. The active component is a mixture of molybdenum nitride (MO2N), tungsten nitride (W2N), molybdenum carbide (Mo2C) and tungsten carbide (WC). The catalyst further comprises a catalytic promoter, and the catalytic promoter is a mixture of TiO2, CeO2, V2O5 and NbOPO4. According to the reaction conditions of the fixed bed reactor, the reaction temperature ranges from 300 DEG C to 450 DEG C, the hydrogen pressure ranges from 2.5 MPa to 3.5 MPa, the hydrogen-oil volume ratio ranges from 500 to 800, and the volume air speed ranges from 1.0 h<-1> to 2.5 h<-1>. According to the process, hydrodeoxygenation of biodiesel can be controlled at a high deoxygenation rate (99.8% or above), and catalytic activity is not obviously reduced after the process continuously runs for 500 hours.

Description

Technical field [0001] The invention relates to a biodiesel hydrodeoxygenation process. Background technique [0002] In the 21st century, the demand and use of fuel oil have increased significantly, and the environmental pollution caused by sulfur-containing compounds has attracted more attention. The sulfur oxides (SO x ) Discharge into the air, causing acid rain and sulfuric acid smog type pollution, causing air pollution. [0003] In order to solve the increasingly severe environmental problems and reduce the pollution of fossil fuels to the environment, in the recent period, it has become a hot spot to make full use of renewable resources based on vegetable oil as fuel. [0004] In the 1980s, American Graham Quick introduced linseed oil and cottonseed methyl oleate into diesel engines for the first time. Since then, the fatty acid monoester compounds obtained through the transesterification reaction have been defined as biodiesel. This fatty acid monoester compound can be used...

AI Technical Summary

Problems solved by technology

However, with the wide application of biodiesel, more and more defects are found: animal and vegetable oils and fats contain different types of fatty acids, and the production process will not change the degree of unsaturation, which is high, such as Biodiesel produced from cottonseed oil, rapeseed oil, etc., contains a large number of carbon-carbon unsaturated bonds in the molecular structure, which is easy to oxidize and cause deterioration during storage, transportation and use. If the unsaturation is low, such as industrial lard and tallow The freezing point of the biodiesel produced by biodiesel is much higher than that of petrochemical diesel. Even if it is mixed with petrochemical diesel in a lower proportion, it is easy to precipitate in low temperature seasons such as autumn and winter, resulting in pipeline blockage, and even damage to the engine in severe cases.

Despite a lot of research and improvements, the molecular structure of biodiesel has not changed, so its defects still exist