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Preparation method of adsorbing material for removing Congo red in dye wastewater

A technology for adsorption materials and dye wastewater, which is applied in the field of preparation of Congo red adsorption materials, can solve problems such as easy saturation, low adsorption capacity, and difficult regeneration, and achieve the effects of simple operation, obvious treatment effect, and good stability

Inactive Publication Date: 2017-01-18
吴迪
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The technical problem mainly solved by the present invention is: aiming at the difficulty to remove the easily soluble Congo red dye in the printing and dyeing wastewater, while the traditional adsorption Congo red material has the disadvantages of low adsorption capacity, easy saturation and difficult regeneration, it provides a modified dye using natural organic matter. The pore structure of the mesoporous adsorption material, the specific surface area of ​​the mesoporous adsorption material solidified by microbial fermentation, and the preparation method of the adsorption material with corresponding organic groups compatible with Congo red

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0018] Select 1kg of mature tung seeds, put them in the sun until the tung seeds crack, then remove the shells, pick out the tung seeds, wash them, and dry them in the sun until the water content of the tung seeds is 2%. The seeds are crushed in a grinder and passed through a 20-mesh sieve to obtain tung seed powder, which is placed in an oil press and pressed at 130°C, and then the oil is extracted to obtain crude tung oil, which is filtered and removed Impurities in tung oil were obtained from the filtrate, and the obtained filtrate was left to settle for 5 days at a temperature of 30°C, and the supernatant was taken to obtain refined tung oil; according to the mass ratio of 1:10, the attapulgite was soaked in The above obtained refined tung oil was soaked in 12h, after attapulgite was saturated, filtered to obtain saturated tung oil attapulgite, saturated tung oil attapulgite and deionized water were mixed in a mass ratio of 1:8, placed in an ultrasonic oscillator at 300r / ...

example 2

[0021] Select 1.5kg of mature tung seeds, expose them to the sun until the tung seeds crack, then remove the shells, pick out the tung seeds, wash them, and dry them until the water content of the tung seeds is 3%. The tung seed kernels are put into a pulverizer and crushed, and passed through a 23-mesh sieve to obtain tung seed powder, which is placed in an oil press, and the oil is pressed at 140 ° C, and then the oil is extracted to obtain crude tung oil, which is filtered and Remove the impurities in the tung oil to obtain the filtrate, and put the obtained filtrate at a temperature of 35°C for 7 days, and take the supernatant to obtain the refined tung oil; according to the mass ratio of 1:10, soak the attapulgite In the refined tung oil obtained above for 16 hours, after attapulgite is saturated, filter to obtain saturated tung oil attapulgite, mix saturated tung oil attapulgite with deionized water at a mass ratio of 1:8, place in an ultrasonic oscillator at 400r / min s...

example 3

[0024] Select 2kg of mature tung seeds, put them in the sun until the tung seeds crack, then remove the shells, pick out the tung seeds, wash them and dry them until the water content of the tung seeds is 5%. The seeds are crushed in a pulverizer and passed through a 25-mesh sieve to obtain tung seed powder, which is placed in an oil press and pressed at 160°C, and then the oil is extracted to obtain crude tung oil, which is filtered and removed Impurities in tung oil were obtained from the filtrate, and the obtained filtrate was left to settle for 10 days at a temperature of 40°C, and the supernatant was taken to obtain refined tung oil; according to the mass ratio of 1:10, the attapulgite was soaked in Put the above-mentioned refined tung oil for 24 hours, after the attapulgite is saturated, filter to obtain saturated tung oil attapulgite, mix saturated tung oil attapulgite with deionized water at a mass ratio of 1:8, place in an ultrasonic oscillator at 600r / Min speed stir...

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PUM

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Abstract

The invention discloses a preparation method of an adsorbing material for removing Congo red in dye wastewater and belongs to the technical field of sewage treatment. The preparation method comprises the steps that firstly, China wood oil is extracted from China wood seeds and is mixed with attapulgite to obtain turbid mixed liquid, a certain proportion of ferrous nitrate and nickel nitrate mixed liquid is prepared, the turbid mixed liquid is added, a sodium hydroxide solution is added dropwise, particulate matter is obtained through precipitation, filtration, drying and high-temperature calcination and is soaked with domestic kitchen wastewater, filtration is performed, fermentation is performed under anaerobic condition, then the particulate matter is constantly subjected to drip washing by using China wood oil to make mould grow, air is isolated by using nitrogen under ultraviolet light to perform high temperature activation, and then the adsorbing material for removing the Congo red in dye wastewater is obtained. The invention provides a method for treating a dye Congo red. The operation is simple, the cost is low, the prepared adsorbent has the advantages of being good in absorption property, obviously reducing the Congo red concentration and the like, and accordingly comprehensive resource utilization, low cost and high-efficiency dye wastewater purification are achieved.

Description

technical field [0001] The invention discloses a preparation method for Congo red adsorption material used for removing dye wastewater, and belongs to the technical field of sewage treatment. Background technique [0002] Dyes play a very important role in people's daily life, and are widely used in industries such as textiles and papermaking. Because of their existence, dyes make our lives colorful. At present, the output of various dyes in my country has reached 900,000 tons, and dye wastewater has become one of the key sources of environmental pollution. Its wastewater contains a large amount of organic matter and salt, and has the characteristics of high CODCr, deep color, strong acidity and alkalinity, etc., which has always been a difficult problem in wastewater treatment. This not only caused great economic losses, but also brought serious pollution to the environment. Among the many fuels, azo dyes are the most widely used and most abundant organic synthetic fuels...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/24B01J20/30C02F1/28C02F101/30
CPCY02W10/37B01J20/24B01J20/06C02F1/288C02F2101/308C02F2303/16
Inventor 吴迪张晶庄敏
Owner 吴迪