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Rigid foam polyurethane material with integration of heat preservation, water resistance and thermal insulation

A technology of rigid polyurethane foam and raw materials, applied in the field of materials, to achieve the effects of light weight, good wear resistance and corrosion resistance, and environmental protection in the production process

Inactive Publication Date: 2017-03-15
GUANGXI JISHUN ENERGY TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the existing sprayed polyurethane materials only have the function of thermal insulation. During roof construction, in addition to the thermal insulation layer, an additional waterproof layer and thermal insulation layer are required.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] An integrated rigid foam polyurethane heat-preservation, waterproof and heat-insulation material, which is made by foaming the following raw materials in proportions by weight:

[0023] Polyphenyl polymethylene polyisocyanate 70kg, diphenylmethane diisocyanate 20kg, polyether polyol 30kg, antioxidant 1kg, ultraviolet absorber 2kg, catalyst 0.8kg, flame retardant 1kg, blowing agent 0.6kg, Silicone oil 4kg, deionized water 12kg.

[0024] The polyester polyol is phthalic anhydride-based, rosin-based polyester polyol or a mixture thereof, and the hydroxyl value is between 240-550 mgKOH / g, preferably between 300-450 mgKOH / g.

[0025] The catalyst is a mixture of dimethylformamide and triethanolamine with a mass ratio of 2:1.

[0026] The flame retardant is a mixture of dibromophenyl polyol and trichloroethyl phosphate, and the mass ratio is 1:2.

[0027] The foaming agent is a mixture of HCFC-141b and cyclopentane with a mass ratio of 1:1.

[0028] The method for preparin...

Embodiment 2

[0035] An integrated rigid foam polyurethane heat-preservation, waterproof and heat-insulation material, which is made by foaming the following raw materials in proportions by weight:

[0036] Polyphenyl polymethylene polyisocyanate 80kg, diphenylmethane diisocyanate 25kg, polyether polyol 40kg, antioxidant 2kg, ultraviolet absorber 3kg, catalyst 0.9kg, flame retardant 1.5kg, blowing agent 0.8kg , silicone oil 5kg, deionized water 15kg.

[0037] The polyester polyol is phthalic anhydride-based, rosin-based polyester polyol or a mixture thereof, and the hydroxyl value is between 240-550 mgKOH / g, preferably between 300-450 mgKOH / g.

[0038] The catalyst is a mixture of dimethylformamide and triethanolamine with a mass ratio of 2:1.

[0039] The flame retardant is a mixture of dibromophenyl polyol and trichloroethyl phosphate, and the mass ratio is 1:2.

[0040] The foaming agent is a mixture of HCFC-141b and cyclopentane with a mass ratio of 1:1.

[0041] The method for prepa...

Embodiment 3

[0048] An integrated rigid foam polyurethane heat-preservation, waterproof and heat-insulation material, which is made by foaming the following raw materials in proportions by weight:

[0049] Polyphenyl polymethylene polyisocyanate 90kg, diphenylmethane diisocyanate 30kg, polyether polyol 50kg, antioxidant 3kg, ultraviolet absorber 4kg, catalyst 1kg, flame retardant 2kg, blowing agent 1kg, silicone oil 6kg, deionized water 18kg.

[0050] The polyester polyol is phthalic anhydride-based, rosin-based polyester polyol or a mixture thereof, and the hydroxyl value is between 240-550 mgKOH / g.

[0051] The catalyst is a mixture of dimethylformamide and triethanolamine with a mass ratio of 2:1.

[0052] The flame retardant is a mixture of dibromophenyl polyol and trichloroethyl phosphate, and the mass ratio is 1:2.

[0053] The foaming agent is a mixture of HCFC-141b and cyclopentane with a mass ratio of 1:1.

[0054] The method for preparing and using the above-mentioned rigid po...

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PUM

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Abstract

The invention discloses a rigid foam polyurethane material with integration of heat preservation, water resistance and thermal insulation. The rigid foam polyurethane material with integration of heat preservation, water resistance and thermal insulation is prepared from, by weight, 70-90 parts of polyaryl polymethylene isocyanate, 20-30 parts of diphenylmethane diisocyanate, 30-50 parts of polyether polyol, 1-3 parts of antioxygen, 2-4 parts of ultraviolet light absorber, 0.8-1 part of catalyst, 1-2 parts of fire retardant, 0.6-1 part of foaming agent, 4-6 parts of dimethylsilicone fluid and 12-18 parts of deionized water. The rigid foam polyurethane material with the integration of heat preservation, water resistance and thermal insulation can be applied to multiple fields of water resistance, heat preservation and thermal insulation of high-floor buildings or accessible roofs or roof gardens, repair and transformation of old buildings, and waterproof and heat-preservation engineering of various buildings of pools, swimming pools and the like, has the advantages of high strength, low weight, water resistance, heat preservation, a good thermal insulation effect, good wear resistance and corrosion prevention and the like, and further has an efficient fire retardant ability; moreover, a chlorofluorocarbon (CFC) foaming agent is not used, so that the material saves energy and is environmentally friendly.

Description

technical field [0001] The invention relates to the technical field of materials, in particular to a hard foam polyurethane thermal insulation integrated material. Background technique [0002] Ordinary polyurethane insulation materials generally use polyether polyols with high functionality and high hydroxyl value to react with polyisocyanates to form cross-linked polymers. At present, polyurethane is used as thermal insulation, waterproof, heat insulation and other materials, and its production volume is increasing. As an excellent thermal insulation and energy-saving material, polyurethane rigid foam has great development potential in building energy conservation, and its thermal conductivity is low, only 0.018 -0.024(w / m*k), equivalent to half of EPS, is currently the lowest thermal conductivity of all insulation materials, and has good thermal performance, aging resistance, good chemical stability, excellent moisture and water resistance, and temperature resistance. It...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/76C08G18/66C08G18/48C08G18/32C08K5/521C08J9/08C08J9/14C08G101/00
CPCC08G18/381C08G18/48C08G18/6666C08G18/7657C08G18/7671C08J9/08C08J9/141C08J9/146C08J2203/02C08J2203/14C08J2203/142C08J2203/20C08J2205/10C08J2375/08C08K5/521C08G2110/0025
Inventor 黄永康柳春陈丹谢刚马昭键黎明煌蒙献芳周帆刘建麟
Owner GUANGXI JISHUN ENERGY TECH
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