A quantum dot enhanced film with excellent optical effect and preparation method thereof
A quantum dot enhanced film and optical effect technology, which is applied in chemical instruments and methods, electrical components, circuits, etc., can solve the problems of large optical loss of quantum dot film, short use and storage life, high preparation cost, etc., and achieve luminescence spectrum Symmetry, extended use and storage life, excellent water and oxygen barrier effect
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Embodiment 1
[0048] Embodiment 1 Using ternary quantum dots as quantum dot materials, the quantum dot enhanced film method with excellent optical effect provided by the present invention includes:
[0049] Step 1, preparing ternary quantum dot-PMMA colloid;
[0050] First, 0.5mmol CdO, 5mmol Zn(Ac) 2, 3.5ml of oleic acid and 10ml of octadecene (1-octadecene, ODE for short) were put into a four-neck flask, vacuumed for 40min, heated to 100°C; ventilated three times, heated to 295°C, and 10mmol of high-purity sulfur S Stir and heat with 20ml ODE at 120 degrees Celsius to prepare a mixed solution of S and ODE with a concentration of 0.5mmol / ml, inject 1ml of the mixed solution of S and ODE into the four-necked flask; control the temperature at 315℃, keep it warm for 150min to 20min, inject 1mmolSe and triphosphate Butyl phosphate (Tributyl phosphate, referred to as TBP) mixture; keep warm for 40min, the temperature is controlled at 300°C, add dropwise 1ml of 0.5mmol / ml S and ODE mixed soluti...
Embodiment 2
[0062] Embodiment 2 Using ZnSe quantum dots as the material, the quantum dot enhanced film method with excellent optical effect provided by the present invention includes:
[0063] Step 1, prepare ZnSe quantum dot-PMMA colloid;
[0064] First, weigh 0.1mmol of zinc-containing compounds such as zinc stearate, 0.5mmol of Se powder, and 10ml of ODE solution into a four-neck flask; heat to 100°C, vacuumize for 40min; ventilate three times, heat to 260°C; Temperature, add 0.6ml oleylamine; 2.5mmolZn(Ac) 2 , 3ml oleic acid and 7ml ODE were heated to 120°C and dissolved to prepare Zn(OH) 2 solution, at a temperature of 260°C for 5min, add 0.4ml of the Zn(OH) 2 solution; repeat the previous step three times; keep warm for 30 minutes, cool to room temperature, and complete the preparation of the ZnSe quantum dot material;
[0065] Among them, zinc-containing compounds also include: anhydrous zinc acetate, zinc oxide, zinc chloride, zinc sulfide, zinc sulfate, etc.
[0066] Then, th...
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