Production method of rare-earth wide-temperature lithium-ion battery

A technology for lithium-ion batteries and production methods, which can be applied to secondary batteries, battery electrodes, electrochemical generators, etc., and can solve the problems of narrow temperature adaptation range, large volume, and short cycle life

Inactive Publication Date: 2017-03-22
河北绿草地新能源股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the starting power supplies for various automobiles are lead-acid batteries. Compared with lithium-ion batteries, they have disadvantages such as large volume, heavy weight, short cycle life, and narrow temperature adaptation range (currently 0°C-60°C). The market demand for ion batteries

Method used

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] The first embodiment provides a production method of a rare earth wide temperature lithium ion battery.

[0030] Specifically, Embodiment 1 of the present invention provides a 50AH rare earth yttrium-doped lithium manganate aluminum shell square wide temperature lithium battery production method, doping rare earth yttrium element in lithium manganate material, yttrium doped in L i mn 2 o 4 L is formed in i Y 0.02 mn 1.98 o 4 compound.

[0031] Specifically, the method includes the steps of:

[0032] Step S110, dissolving soluble metal manganese salt and rare earth yttrium oxide in a certain amount of deionized water according to a predetermined molar ratio to prepare a mixed salt solution.

[0033] Preferably, the molar ratio in the mixed salt solution is 0.1-0.5%.

[0034] Further, as a possible embodiment, a mixed salt solution with a total metal concentration of 2 mol / L is prepared at a molar ratio of Mn:Y=1:0.005.

[0035] Step S111, NaNO 3 Dissolve ammoni...

Embodiment 2

[0043] Embodiment 2 of the present invention also provides a production method of a rare-earth wide-temperature lithium-ion battery.

[0044] Specifically, Embodiment 2 of the present invention provides a production method of a 10Ah rare earth-doped nickel-cobalt lithium manganate soft-pack wide-temperature lithium-ion power battery. The metal salt used in this method is metal nickel salt, cobalt salt and manganese salt, and the rare earth compound is rare earth neodymium nitrate Nd(NO 3 ) 3 ·6H 2 O.

[0045] The method includes the steps of:

[0046]Step S210, preparing a mixed aqueous solution of nickel nitrate, manganese nitrate, cobalt nitrate, and neodymium nitrate with a total metal concentration of 2 mol / L based on a molar ratio of Ni:Mn:Co:Nd=2:2:1:0.001.

[0047] Step S211, preparing NaNO with a total concentration of 10mol / L 3 Mixed solution with ammonia water, in which NaNO 3 The molar ratio with ammonia water is 1:1.5.

[0048] In step S212, the above two so...

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Abstract

The invention provides a production method of a rare-earth wide-temperature lithium-ion battery. The production method of the rare-earth wide-temperature lithium-ion battery comprises the steps of preparing a mixed saline solution by using dissoluble metal salts and a rare-earth compound according to a certain mole ratio; and carrying out reaction between the mixed saline solution and a mixed alkaline solution under a certain condition, then mixing with lithium salt powder according to a certain proportion, and roasting the mixture to obtain a cathode material of the rare-earth wide-temperature lithium-ion battery. The rare-earth element is added into the cathode material of the lithium-ion battery to keep the crystal structure of the cathode material, and only the lattice constant C is changed, for example, a rare-earth yttrium element is added into the cathode material lithium manganate to enable yttrium to be doped into the cathode material LiMn2O4, thereby forming a LiY0.02Mn1.98O4 compound. The lithium-ion battery added with the rare-earth element is verified to have relatively high reversible capacity, good cycle performance, strong adaptability to high and low temperatures; and the lithium-ion battery added with the rare-earth element can be used at -45 DEG C after being subjected to technical processing.

Description

technical field [0001] The invention relates to the technical field of battery production, and more specifically relates to a production method of a rare-earth wide-temperature lithium-ion battery. Background technique [0002] With the continuous development of social civilization in recent years, especially since human society entered the information age and network age, it is more eager for high-quality electric energy. Therefore, batteries, especially secondary batteries, will inevitably play a pivotal role in the future society based on electric energy. Since the late 1990s, portable electronic devices such as mobile phones and notebook computers have been rapidly popularized around the world at an astonishing speed, and they have entered the homes of ordinary people faster and faster. The result is a rapid increase in the demand for small power supplies. Since portable electronic devices are compact and lightweight, they require small power supplies with the advantag...

Claims

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Application Information

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IPC IPC(8): H01M4/38H01M10/0525H01M10/058H01M10/42
CPCH01M4/38H01M10/0525H01M10/058H01M10/4235Y02E60/10Y02P70/50
Inventor 刘素国
Owner 河北绿草地新能源股份有限公司
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