Low-damping polyamide negative pressure melt spinning formation method
A melt-spinning, polyamide technology, used in melt-spinning, filament/thread forming, textile and papermaking, etc., can solve the lack of system design of the fiber-air boundary layer, insufficient cooling, uniformity, melt rheology, etc. The lack of necessary consideration of resistance, etc., can improve the surface hardness and friction resistance, improve the transformation, and reduce the rheological resistance.
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Embodiment 1
[0058] A low-damping polyamide 6 fiber negative-pressure melt-spinning forming method. Firstly, polysiloxane treatment liquid is prepared, and firstly, 10 parts by weight have a pH value of 10.1, a solid content of 30wt%, and an average particle diameter of 30nm. Alkaline silica sol and 10 parts of alkaline silica sol with a pH value of 9.4, a solid content of 20 wt%, and an average particle diameter of 45 nm are mixed, and then 5 parts of formic acid are added as a catalyst to adjust the pH value of the system to maintain the pH value at 2. Then add 10 parts of mixed solvent of ethanol and water, the volume ratio of ethanol and water is 1.25:1, then add 30 parts of methyltrimethoxysilane, and then carry out hydrolysis at room temperature for 15 minutes, and then put the system in 45°C Carry out high-temperature condensation, and keep the reaction for 30 minutes. After the reaction, add 1 part of the mixture additive of leveling agent BYK 310, defoamer BYK 025 and surface harde...
Embodiment 2
[0067] A low-damping polyamide 6 fiber negative-pressure melt-spinning forming method. First, polysiloxane treatment liquid is prepared. First, 20 parts by weight of the polyamide 6 have a pH value of 10.5, a solid content of 45 wt%, and an average particle size of 50nm. Alkaline silica sol mixed with 20 parts of alkaline silica sol with a pH value of 9.8, a solid content of 35 wt %, and an average particle diameter of 65 nm, then adding 8 parts of acetic acid as a catalyst to adjust the pH value of the system to maintain the pH value at 4.5, Then add 20 parts of isopropanol and water mixed solvent, the volume ratio of isopropanol and water is 1.42:1, then add 40 parts of methyltriethoxysilane, then carry out hydrolysis at normal temperature for 20min, and then put Put the system at 80°C for high-temperature condensation, and keep the reaction for 75 minutes. After the reaction, add 3 parts of a mixture of leveling agent BYK 310, defoamer BYK 025 and surface hardening and wear-...
Embodiment 3
[0076] A low-damping polyamide 6 fiber negative-pressure melt-spinning forming method. Firstly, polysiloxane treatment liquid is prepared. First, 15 parts by weight of the polyamide 6 fiber have a pH value of 10.3, a solid content of 35wt%, and an average particle size of 40nm. Alkaline silica sol mixed with 15 parts of alkaline silica sol with a pH value of 9.6, a solid content of 30 wt%, and an average particle diameter of 50 nm, and then adding 6 parts of hydrochloric acid as a catalyst to adjust the pH value of the system to maintain the pH value at 3, Then add 15 parts of butanol and water mixed solvent, the volume ratio of butanol and water is 1.60:1, then add 35 parts of ethyltriethoxysilane, then carry out hydrolysis at room temperature for 18min, and then put the system Put it into 50℃ for high temperature condensation, keep the reaction for 40min, after the reaction is over, add 2 parts of mixture additives of leveling agent BYK 310, defoamer BYK 025 and surface harde...
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