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Low-damping polyamide negative pressure melt spinning formation method

A melt-spinning, polyamide technology, used in melt-spinning, filament/thread forming, textile and papermaking, etc., can solve the lack of system design of the fiber-air boundary layer, insufficient cooling, uniformity, melt rheology, etc. The lack of necessary consideration of resistance, etc., can improve the surface hardness and friction resistance, improve the transformation, and reduce the rheological resistance.

Active Publication Date: 2017-04-19
DONGHUA UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] In the Chinese patent CN 102206879A, the negative pressure spinning condition (0.01-0.001MPa) is designed in the fiber forming process to improve the spinning speed of the fiber by reducing the air friction resistance, but the rheological resistance of the melt Lack of necessary considerations, and rheological resistance is one of the key factors for the improvement of fiber spinning speed and quality. The structure of the spinneret in the spinning pack has a direct impact on the rheological resistance of the melt, and then regulates the fiber forming process
However, neither the side blowing nor the surrounding blowing cooling method can avoid the disturbance of the fiber air flow, resulting in insufficient and uniform cooling during the cooling process.
Although the surrounding air blowing can ensure the cooling effect of the fiber to a certain extent compared with the side air blowing, and the quality index has been improved in the development of ultra-fine denier and fine-denier fibers, but there is no systematic design for the fiber-air boundary layer during the fiber cooling process.

Method used

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Embodiment 1

[0058] A low-damping polyamide 6 fiber negative-pressure melt-spinning forming method. Firstly, polysiloxane treatment liquid is prepared, and firstly, 10 parts by weight have a pH value of 10.1, a solid content of 30wt%, and an average particle diameter of 30nm. Alkaline silica sol and 10 parts of alkaline silica sol with a pH value of 9.4, a solid content of 20 wt%, and an average particle diameter of 45 nm are mixed, and then 5 parts of formic acid are added as a catalyst to adjust the pH value of the system to maintain the pH value at 2. Then add 10 parts of mixed solvent of ethanol and water, the volume ratio of ethanol and water is 1.25:1, then add 30 parts of methyltrimethoxysilane, and then carry out hydrolysis at room temperature for 15 minutes, and then put the system in 45°C Carry out high-temperature condensation, and keep the reaction for 30 minutes. After the reaction, add 1 part of the mixture additive of leveling agent BYK 310, defoamer BYK 025 and surface harde...

Embodiment 2

[0067] A low-damping polyamide 6 fiber negative-pressure melt-spinning forming method. First, polysiloxane treatment liquid is prepared. First, 20 parts by weight of the polyamide 6 have a pH value of 10.5, a solid content of 45 wt%, and an average particle size of 50nm. Alkaline silica sol mixed with 20 parts of alkaline silica sol with a pH value of 9.8, a solid content of 35 wt %, and an average particle diameter of 65 nm, then adding 8 parts of acetic acid as a catalyst to adjust the pH value of the system to maintain the pH value at 4.5, Then add 20 parts of isopropanol and water mixed solvent, the volume ratio of isopropanol and water is 1.42:1, then add 40 parts of methyltriethoxysilane, then carry out hydrolysis at normal temperature for 20min, and then put Put the system at 80°C for high-temperature condensation, and keep the reaction for 75 minutes. After the reaction, add 3 parts of a mixture of leveling agent BYK 310, defoamer BYK 025 and surface hardening and wear-...

Embodiment 3

[0076] A low-damping polyamide 6 fiber negative-pressure melt-spinning forming method. Firstly, polysiloxane treatment liquid is prepared. First, 15 parts by weight of the polyamide 6 fiber have a pH value of 10.3, a solid content of 35wt%, and an average particle size of 40nm. Alkaline silica sol mixed with 15 parts of alkaline silica sol with a pH value of 9.6, a solid content of 30 wt%, and an average particle diameter of 50 nm, and then adding 6 parts of hydrochloric acid as a catalyst to adjust the pH value of the system to maintain the pH value at 3, Then add 15 parts of butanol and water mixed solvent, the volume ratio of butanol and water is 1.60:1, then add 35 parts of ethyltriethoxysilane, then carry out hydrolysis at room temperature for 18min, and then put the system Put it into 50℃ for high temperature condensation, keep the reaction for 40min, after the reaction is over, add 2 parts of mixture additives of leveling agent BYK 310, defoamer BYK 025 and surface harde...

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Abstract

The invention relates to a low-damping polyamide negative pressure melt spinning formation method. A polyamide melting body squeezed out from a low-damping filament-sprinkling micro-hole is slow-cooled to form nascent fibers; then the nascent fibers are negative-pressure cooled and naturally cooled orderly; the low-damping filament-sprinkling micro-hole has low-surface energy and the surface is processed via polysilaxane processing liquid; the filament-sprinkling micro-hole surface energy En is no more than 35mJ / cm<2>; the surface roughness Ra is no more than 0.2[mu]m; the surface static contact angle WCA is no less than 85 degrees; and the negative pressure cooling is conducted in a sealed air atmosphere environment with constant temperature and isopiestic pressure and constant humidity, pressure of being 0.001 to 0.01 MPa and the temperature of 5 to 10 DEG C. flowing deformation resistance and air friction resistance produced during the flow of the melting body can be effectively reduced and fibers can be evenly and thoroughly cooled; spinning speed and fiber product quality can be obviously improved during the melt spinning; and the method can be applied to production and machining of fibers with rough denier, fine denier, high strength and great modulus.

Description

technical field [0001] The invention belongs to the field of melt spinning and relates to a low-damping polyamide negative pressure melt spinning forming method. Background technique [0002] China is a big country of chemical fiber, and chemical fiber is an important raw material in the textile field. In terms of chemical fiber output, China's chemical fiber output reached 43.9 million tons in 2014, of which polyamide fibers accounted for more than 70% of the total chemical fiber output. The transformation and upgrading of polyamide fiber products directly affects the development of the chemical fiber field, among which the main development trends in the transformation and upgrading of polyamide are production efficiency, energy saving and fiber quality improvement. The improvement of polyamide melt spinning technology has a significant role in promoting the transformation and upgrading of the chemical fiber field. [0003] The problems existing in the application process...

Claims

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Application Information

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IPC IPC(8): D01D5/088D01D5/08D01D4/02D01D5/253
CPCD01D4/022D01D5/08D01D5/088D01D5/253
Inventor 王华平吉鹏王朝生李建武汤廉沈明威
Owner DONGHUA UNIV