Anode slurry binding agent used for lithium ion batteries

A lithium-ion battery and negative electrode slurry technology, which is applied in battery electrodes, secondary batteries, secondary battery repair/maintenance, etc., can solve the problem of not being able to apply high energy and high power, can not block the side reaction of heat production, and improve the effect Limited and other problems, to achieve the effect of recycling, repairing and reusing, excellent effect, and improved bonding effect

Inactive Publication Date: 2017-04-19
长兴天晟能源科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since the ceramic-coated diaphragm can only improve the thermal stability of the diaphragm, it cannot block the side reaction of heat generation, so its improvement effect is limited.
At present, it can only solve the safety problem of batteries with an energy density of no more than 200wh / kg; method 2 can partially contain the thermal runaway reaction of the battery, but because the electrodes of lithium-ion batteries are usually porous electrodes, the electrolyte is filled in the abundant electrode gaps; although The conduction of lithium ions between the positive and negative electrodes is blocked, but the reaction between the active material inside the electrode and the electrolyte is still going on, which will further lead to heat accumulation and trigger a thermal runaway reaction. Method 2 cannot be applied to high-energy and high-power lithium Ion battery system

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] A negative electrode slurry binder for lithium-ion batteries, made from the following raw materials in parts by weight:

[0029] 10 parts of polyvinyl alcohol, 2 parts of polyacrylic acid, 4 parts of sodium carboxymethyl cellulose, 1 part of sodium alginate, 3 parts of binder additive;

[0030] Wherein, the binder additive is made from 6 parts by weight of polyvinylidene fluoride, 2 parts by weight of Ketjen black and 1.5 parts by weight of polymethyl acrylate, and Ketjen black is 200 mesh;

[0031] The binder additive is made by the following steps:

[0032] a) Baking PVDF at 180°C for 20 minutes, then quenching in water at 10°C;

[0033] b) Polarize the quenched polyvinylidene fluoride under a polarizing electric field of 0.5MV / cm for 4 minutes, and then crush it to 200 mesh;

[0034] c) Mix the conductive agent and the dispersant and mix evenly, then add the polyvinylidene fluoride treated in the above steps, and continue to mix evenly to obtain a mixture;

[0035...

Embodiment 2

[0037] A negative electrode slurry binder for lithium-ion batteries, made from the following raw materials in parts by weight:

[0038] 12 parts of polyvinyl alcohol, 2 parts of polyacrylic acid, 4 parts of sodium carboxymethyl cellulose, 1 part of sodium alginate, 3.5 parts of binder additive;

[0039] Wherein, the binder additive is made from 7 parts by weight of polyvinylidene fluoride, 3 parts by weight of Ketjen black and 1.5 parts by weight of polymethyl acrylate, and Ketjen black is 250 mesh;

[0040] The binder additive is made by the following steps:

[0041] a) Baking PVDF at 200°C for 30 minutes, then quenching in water at 15°C;

[0042] b) Polarize the quenched polyvinylidene fluoride under a polarizing electric field of 1MV / cm for 6 minutes, and then crush it to 250 mesh;

[0043] c) Mix the conductive agent and the dispersant and mix evenly, then add the polyvinylidene fluoride treated in the above steps, and continue to mix evenly to obtain a mixture;

[0044...

Embodiment 3

[0046] A negative electrode slurry binder for lithium-ion batteries, made from the following raw materials in parts by weight:

[0047] 13 parts of polyvinyl alcohol, 2.5 parts of polyacrylic acid, 4.5 parts of sodium carboxymethyl cellulose, 1.5 parts of sodium alginate, 4 parts of binder additive;

[0048] Wherein, the binder additive is made from 8 parts by weight of polyvinylidene fluoride, 4 parts by weight of Ketjen black and 2 parts by weight of polymethyl acrylate, and Ketjen black is 350 mesh;

[0049] The binder additive is made by the following steps:

[0050] a) Baking PVDF at 220°C for 35 minutes, then quenching in water at 20°C;

[0051] b) Polarize the quenched polyvinylidene fluoride under a polarizing electric field of 1.5MV / cm for 8 minutes, and then crush it to 300 mesh;

[0052] c) Mix the conductive agent and the dispersant and mix evenly, then add the polyvinylidene fluoride treated in the above steps, and continue to mix evenly to obtain a mixture;

[0...

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PUM

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Abstract

The invention belongs to the technical field of lithium ion battery manufacturing, and discloses an anode slurry binding agent used for lithium ion batteries. The anode slurry binding agent is prepared from raw materials including polyvinyl alcohol, polyacrylic acid, sodium carboxymethylcellulose, sodium alginate, and a binding agent additive; the binding agent additive is prepared from polyvinylidene fluoride, Ketjen black, and polymethyl acrylate. The anode slurry binding agent possesses excellent binding performance, is capable of realizing better and more uniform binding of anode active materials, is suitable for batteries with requirements on higher cycling performance, and is capable of improving safety performance of anode slurry, realizing automatic stop of exothermic reaction of assembled lithium ion batteries at high temperature, and ensuring the safety of lithium ion batteries in applications.

Description

technical field [0001] The invention relates to the technical field of manufacturing lithium ion batteries, in particular to a negative electrode slurry binder for lithium ion batteries. Background technique [0002] In recent years, the rapid development of portable electronic products, electric vehicles, energy storage power stations and other fields has put forward higher requirements for energy storage technology. Lithium-ion batteries are the first choice in these fields due to their high energy density, and their energy density is getting higher. As the energy density of lithium-ion batteries is getting higher and higher, the safety problems it faces are becoming more and more severe, which has severely limited the terminal use of high-energy-density lithium-ion batteries. [0003] The safety problem of lithium-ion batteries is mainly due to the thermal runaway of batteries. Due to the abnormal heat generation reaction inside the battery, the internal temperature of ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/62H01M10/0525H01M10/42
CPCH01M4/622H01M4/623H01M10/0525H01M10/4235Y02E60/10
Inventor 佘海中
Owner 长兴天晟能源科技有限公司
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