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Semi-continuous automatic microwave denitrification device

A semi-continuous, microwave technology, applied in the fields of inorganic chemistry, rare earth metal compounds, chemical instruments and methods, etc., can solve the problems of entering and leaving the denitration container, gas, microwave leakage, and high airtightness requirements, and achieve the composition and particle size of the denitration product. The effect of uniform diameter, low nitrate content and stable operation

Active Publication Date: 2018-06-29
RES INST OF PHYSICAL & CHEM ENG OF NUCLEAR IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Continuous production equipment requires continuous feeding. In order to reduce the droplet splashing during the feeding process, the method of inserting the material guide tube into the container is often used. The widely used microwave equipment adopts the structure of the side door, and there are problems in the denitrification container.
In addition, the airtightness of the side door is often fixed manually by locks, screws, etc. Frequent opening and closing will lead to gas and microwave leakage
A large amount of nitrogen oxide gas will be produced in the process of nitrate denitrification, and radioactive aerosols will also be produced in the denitrification process of uranyl nitrate. The airtightness requirements of the equipment are high. Due to the lack of air convection in the airtight cavity, the steam will condense in the cavity and cannot be discharged, resulting in equipment not functioning properly
Due to the above problems, it is difficult to effectively apply microwave equipment in microwave denitrification production

Method used

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  • Semi-continuous automatic microwave denitrification device

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0063] Embodiment 1: Put the denitrification container 15 into the tray 13 in the operation area, set the parameters such as feeding speed and microwave power, and the equipment will run automatically. The transmission mechanism transmits the denitrification container 15 to the resonant cavity 5, and continuously adds the uranyl nitrate solution into the denitrification container 15 through the metering pump 7, and automatically heats for 150 minutes. After the feeding is completed, continue heating, automatically control the temperature at 250°C for heating and denitrification for 10 minutes, and stop heating. After cooling for 30 minutes, the material is transported to the operation area through the transmission mechanism, and the denitrification product obtained is uranium trioxide, and the ratio of oxygen to uranium is 3.02:1.

Embodiment 2

[0064] Embodiment 2: Put the denitration container 15 into the tray 13 in the operation area, and add a gadolinium nitrate solution containing 150 g of gadolinium in a volume of about 500 mL into the denitration container 15 . Set the feeding speed, microwave power and other parameters, the equipment runs automatically, the transmission mechanism transfers the denitrification container 15 to the resonance cavity 5, starts heating, and stops heating after 60 minutes of heating. After cooling for 30 minutes, the material is transported to the operation area through the transmission mechanism, and the denitrification product is digadolinium trioxide, and the ratio of oxygen to gadolinium is 1.5:1.

[0065] The invention realizes semi-continuous production, automation with remote operation function, and almost no tail gas discharge; the denitrification container enters and exits the resonant cavity vertically, and the translation structure and lifting structure operate smoothly; th...

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PUM

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Abstract

The invention discloses a semicontinuous and automatic microwave denitration device. The device comprises a conveying mechanism of feed liquid, a microwave mechanism, a controlling mechanism of a denitration container and a waste gas treatment mechanism. The conveying mechanism of feed liquid comprises a feed liquid tank. The feed liquid in the tank is extracted by a metering pump and conveyed through a feeding pipe provided with a flowmeter. The microwave mechanism comprises a microwave power supply. The microwave generated by the microwave power supply is transmitted through a waveguide to a resonant cavity. A water load and a circulator are arranged on the waveguide. The opening at the bottom end of the resonant cavity is sealed by a double-sealed door mechanism. The device realizes semicontinuous production and the function of automatically remote operating as well as has almost no exhaust emission. The denitration device vertically moves in and out the resonant cavity, wherein translation structure and lifting structure operate steadily. The resonant cavity with good air tightness is capable of exhausting steam normally so that to ensure no vapour condensation. The denitration product has homogeneous composition, uniform partical and low content of nitrate.

Description

technical field [0001] The invention belongs to a denitration device, in particular to a semi-continuous automatic microwave denitration device. Background technique [0002] Microwave is a clean and efficient new energy source. Microwave heating has the characteristics of uniform heating and high efficiency. It has been widely used in food drying, organic synthesis, sample processing, material sintering, etc. Microwave heating equipment has also been developed and promoted. [0003] The microwave heating denitrification device is a device used to heat the nitrate solution to evaporate, concentrate, and finally denitrify to form oxides. At present, some microwave devices used in research are made by transforming domestic microwave ovens or laboratory microwave ovens, without considering the continuous operation, exhaust gas treatment, personnel protection and other issues. Continuous production equipment requires continuous feeding. In order to reduce the splashing of dropl...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J19/12C01F17/00C01G43/01B01D53/00B01D53/18
CPCB01D53/002B01D53/1456B01D53/18B01J19/126C01F17/206C01G43/01
Inventor 赵刚于震孙亮王筠张晓卫陈晨
Owner RES INST OF PHYSICAL & CHEM ENG OF NUCLEAR IND
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