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Rheological agent for replacing water reducer in low mass-ratio in cement-based system

A rheological agent, low-quality technology, applied in the field of building materials, can solve the problems of too short molecular main chain of water reducing agent, difficult material air entrainment, unreasonable gradation, etc., to improve rheological properties, optimize encapsulation, The effect of strength development promotion

Inactive Publication Date: 2017-05-17
HUBEI UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In view of this, the technical problem to be solved by the present invention is to solve the application status quo of poor workability of high-fluidity concrete due to factors such as unreasonable gradation of raw materials, difficulty in entraining air in materials, and too short main chain of superplasticizer molecules, and A single conventional polycarboxylate superplasticizer component cannot solve the high fluidity mixture while meeting the cohesion and water retention and other indicators, and builds a combination of lubricants, air-entraining agents, early-strength mineral dispersants-intercalants The rheological agent system that replaces the water reducer with a low mass ratio is the difficulty and key to the matching design of rheological agent multi-components

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] The stearate emulsion is zinc stearate emulsion, and the specific dosage is: zinc stearate emulsion: 35 parts;

[0031] OEP-70 is selected as the alkali-resistant penetrating agent, and the specific dosage is: OEP-70: 10 parts;

[0032] The cationic monomer is acryloyloxyethyltrimethylammonium chloride, and the specific dosage is: acryloyloxyethyltrimethylammonium chloride: 10 parts;

[0033] Alcohol amine compound selects triisopropanolamine for use, and specific consumption is: triisopropanolamine: 10 parts;

[0034] The soap air-entraining agent is selected from triterpene saponins, and the specific dosage is: triterpene saponins: 35 parts.

[0035] Prepare 7 grams of rheological agent solid-solution composition according to the above ratio, add 93 grams of water, replace the water reducer with a solid solute ratio of 7% in a project according to the solid solute ratio of 7%, and replace the low mass ratio n=6.

Embodiment 2

[0037] The stearate emulsion is calcium stearate emulsion, and the specific dosage is: calcium stearate emulsion: 40 parts;

[0038] The alkali-resistant penetrating agent is AEP, and the specific dosage is: AEP: 5 parts;

[0039] N, N-dimethylacetamide is selected as the cationic monomer, and the specific dosage is: N, N-dimethylacetamide: 5 parts;

[0040] The alcohol amine compound is selected from diisopropanolamine and monoisoolamine, and the specific dosage is: diisopropanolamine: 5 parts, monoisoolamine: 5 parts;

[0041] The soap air-entraining agent is sodium oleate, and the specific dosage is: sodium oleate: 40 parts.

[0042] Prepare 15 grams of rheological agent solid-solution composition according to the above ratio, add 85 grams of water, replace a certain engineering water reducer with a solid solute ratio of 15% according to the solid solute ratio of 15%, and replace the low mass ratio n=3.5.

Embodiment 3

[0044] The stearate emulsion is selected from calcium stearate emulsion and zinc stearate emulsion, and the specific dosage is: calcium stearate emulsion: 20 parts, zinc stearate emulsion: 25 parts;

[0045] The alkali-resistant penetrating agent is AEP, and the specific dosage is: AEP: 5 parts;

[0046] The cationic monomer is erucamide, and the specific dosage is: erucamide: 5 parts;

[0047] Alcohol amine compound selects diisopropanolamine for use, and specific dosage is: diisopropanolamine: 5 parts;

[0048] The soap air-entraining agent is sodium oleate, and the specific dosage is: sodium oleate: 40 parts.

[0049] Prepare 11 grams of rheological agent solid-solution composition according to the above ratio, add 89 grams of water, replace a certain engineering water reducing agent with a solid solute ratio of 11% according to the solid solute ratio of 11%, and replace the low mass ratio n=4.5.

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Abstract

The invention provides a rheological agent for replacing a water reducer in a low mass-ratio in a cement-based system. The rheological agent is an aqueous solution of a solid-liquid composition, wherein the solid-liquid composition comprises the following raw materials in parts by weight: 35-45 parts of a stearate emulsion, 5-15 parts of an alkaline-resistant penetrant, 5-10 parts of a cationic monomer, 5-10 parts of an alcohol amine compound and 35-45 parts of a soap air entraining agent; the solid solution content proportion of the solid-liquid composition of the rheological agent in the aqueous solution is 6-20%; the solid solution content proportion of the water reducer thereof is also 6-20%; and the low mass ratio means that 1 part of the rheological agent and (n-1) parts of water can replace n parts of water reducer during replacement of the water reducer by the rheological agent in the same solid solution content proportion and at the same amount of admixture, and n is greater than or equal to 3 but less than or equal to 6. Differentiated from a thickener or a viscosity modifier, the rheological agent can weaken the high water reducing action of the water reducer, improve the rheological property of concrete and optimize the coating property and the stability of the concrete, and the performance advantages of the rheological agent are particularly obvious by using machine-made sand, superfine sand and a non-continuous graded coarse material.

Description

[0001] Technical field: [0002] The invention relates to the field of building materials, in particular to a rheological agent used for replacing water-reducing agents with low mass ratios in cement-based systems. [0003] Background technique: [0004] Concrete mixture is composed of cement, sand, stones, admixtures, mineral admixtures and water reducers, etc. During the process, due to the unreasonable design of particle gradation of different sizes, the inability of the hydrated cementitious material to provide a suitable viscosity, and the fact that the main chain of the water reducing agent is too short to wrap the cement particles, etc., all kinds of problems in the mixture will be caused. The components separate and the mixture becomes inhomogeneous and loses continuity. [0005] Patent CN 1385392 A relates to the application of a powder composition as a rheological additive in a cement-containing or cement-free building material composition, wherein the powder composi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B24/12
CPCC04B40/0039C04B2103/0068C04B24/085C04B24/124C04B24/122C04B2103/304C04B2103/603
Inventor 柯凯秦欢李学锋常鹰严明
Owner HUBEI UNIV OF TECH
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